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Title: Controlling catalytic activity and selectivity for partial hydrogenation by tuning the environment around active sites in iridium complexes bonded to supports

Abstract

Enveloping atomically dispersed supported iridium with the choice of ionic liquid molecular sheaths and supports controls the catalytic performance.

Authors:
ORCiD logo [1];  [2];  [2]; ORCiD logo [3];  [3]; ORCiD logo [2]; ORCiD logo [3]; ORCiD logo [2]; ORCiD logo [1]
  1. Koc Univ., Istanbul (Turkey)
  2. Univ. of California, Davis, CA (United States)
  3. SLAC National Accelerator Lab., Menlo Park, CA (United States)
Publication Date:
Research Org.:
SLAC National Accelerator Lab., Menlo Park, CA (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1491267
Alternate Identifier(s):
OSTI ID: 1505424
Grant/Contract Number:  
AC02-76SF00515; FG02-04ER15513; 113M552; Consortium for Operando and Advanced Catalyst Characterization
Resource Type:
Journal Article: Published Article
Journal Name:
Chemical Science
Additional Journal Information:
Journal Volume: 10; Journal Issue: 9; Journal ID: ISSN 2041-6520
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats

Babucci, Melike, Fang, Chia -Yu, Perez-Aguilar, Jorge E., Hoffman, Adam S., Boubnov, Alexey, Guan, Erjia, Bare, Simon R., Gates, Bruce C., and Uzun, Alper. Controlling catalytic activity and selectivity for partial hydrogenation by tuning the environment around active sites in iridium complexes bonded to supports. United States: N. p., 2019. Web. doi:10.1039/c8sc05287e.
Babucci, Melike, Fang, Chia -Yu, Perez-Aguilar, Jorge E., Hoffman, Adam S., Boubnov, Alexey, Guan, Erjia, Bare, Simon R., Gates, Bruce C., & Uzun, Alper. Controlling catalytic activity and selectivity for partial hydrogenation by tuning the environment around active sites in iridium complexes bonded to supports. United States. doi:10.1039/c8sc05287e.
Babucci, Melike, Fang, Chia -Yu, Perez-Aguilar, Jorge E., Hoffman, Adam S., Boubnov, Alexey, Guan, Erjia, Bare, Simon R., Gates, Bruce C., and Uzun, Alper. Wed . "Controlling catalytic activity and selectivity for partial hydrogenation by tuning the environment around active sites in iridium complexes bonded to supports". United States. doi:10.1039/c8sc05287e.
@article{osti_1491267,
title = {Controlling catalytic activity and selectivity for partial hydrogenation by tuning the environment around active sites in iridium complexes bonded to supports},
author = {Babucci, Melike and Fang, Chia -Yu and Perez-Aguilar, Jorge E. and Hoffman, Adam S. and Boubnov, Alexey and Guan, Erjia and Bare, Simon R. and Gates, Bruce C. and Uzun, Alper},
abstractNote = {Enveloping atomically dispersed supported iridium with the choice of ionic liquid molecular sheaths and supports controls the catalytic performance.},
doi = {10.1039/c8sc05287e},
journal = {Chemical Science},
issn = {2041-6520},
number = 9,
volume = 10,
place = {United States},
year = {2019},
month = {1}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record at 10.1039/c8sc05287e

Citation Metrics:
Cited by: 3 works
Citation information provided by
Web of Science

Figures / Tables:

Table 1 Table 1: Summary of EXAFS fit parameters characterizing samples prepared by adsorption of Ir(CO)2(acac) on metal oxides having various electron-donor characteristics (quantified by the their corresponding PZC values)a

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Figures/Tables have been extracted from DOE-funded journal article accepted manuscripts.