Modeling and simulation of CO2 capture using semipermeable elastic microcapsules

Finn, Justin R.; Galvin, Janine E.

doi:10.1016/j.ijggc.2018.04.022

Title: Modeling and simulation of CO₂ capture using semipermeable elastic microcapsules

Abstract

Very high rates of CO₂ absorption have been demonstrated using semipermeable microcapsules filled with environmentally benign sodium carbonate solutions (Vericella et al., Nature communications 6, 2015). However, such capsules have also exhibited several traits, including water loss/uptake, elastic swelling and buckling, and precipitation of solids, which make them more complicated to engineer as a carbon capture material. To address this, a mechanistic model for mass transfer and chemical reaction has been developed, which accounts for these behaviors, and can be used as a predictive tool to explore capsule performance under different CO₂ capture scenarios. The model uses a modified film theory to describe CO₂ and H₂O mass transfer rates, a concentration based description of vapor-liquid-solid equilibrium inside the capsule, and an elastic description of the capsule shell. Model predictions compare favorably to literature data for precipitating carbonates, as well as recent data for microcapsule CO₂ absorption. The model was used to assess practical issues of capsule water transfer during a temperature swing CO₂ absorption/desorption cycle. Model predictions indicate that capsules filled with high weight percent, precipitating sodium carbonate solution could be significantly or completely dehydrated during CO₂ absorption. Subsequent rehydration of lean capsules at elevated temperature showed strong sensitivity tomore »« less

Authors:

Finn, Justin R. ^[1]; Galvin, Janine E. ^[2]

National Energy Technology Lab. (NETL), Albany, OR (United States); AECOM, Albany, OR (United States)
National Energy Technology Lab. (NETL), Albany, OR (United States)

Publication Date:: Thu May 10 00:00:00 EDT 2018

Research Org.:: National Energy Technology Lab. (NETL), Pittsburgh, PA, and Morgantown, WV (United States). In-house Research

Sponsoring Org.:: USDOE Office of Fossil Energy (FE)

OSTI Identifier:: 1491082

Alternate Identifier(s):: OSTI ID: 1632991

Report Number(s):: NETL-PUB-21633
Journal ID: ISSN 1750-5836

Grant/Contract Number:: FE0004000

Resource Type:: Journal Article: Accepted Manuscript

Journal Name:: International Journal of Greenhouse Gas Control

Additional Journal Information:: Journal Volume: 74; Journal Issue: C; Journal ID: ISSN 1750-5836

Publisher:: Elsevier

Country of Publication:: United States

Language:: English

Subject:: 54 ENVIRONMENTAL SCIENCES; Carbon Capture; Elastic Microcapsule; Sodium Carbonate Solution; Numerical Model

Citation Formats


                    Finn, Justin R., and Galvin, Janine E. Modeling and simulation of CO2 capture using semipermeable elastic microcapsules.  United States: N. p., 2018. 
        Web.  doi:10.1016/j.ijggc.2018.04.022.

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                    Finn, Justin R., & Galvin, Janine E. Modeling and simulation of CO2 capture using semipermeable elastic microcapsules.  United States.  https://doi.org/10.1016/j.ijggc.2018.04.022

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                    Finn, Justin R., and Galvin, Janine E. 2018.  
        "Modeling and simulation of CO2 capture using semipermeable elastic microcapsules".  United States.  https://doi.org/10.1016/j.ijggc.2018.04.022.  https://www.osti.gov/servlets/purl/1491082.

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@article{osti_1491082,

  title        = {Modeling and simulation of CO2 capture using semipermeable elastic microcapsules},

  author       = {Finn, Justin R. and Galvin, Janine E.},

  abstractNote = {Very high rates of CO2 absorption have been demonstrated using semipermeable microcapsules filled with environmentally benign sodium carbonate solutions (Vericella et al., Nature communications 6, 2015). However, such capsules have also exhibited several traits, including water loss/uptake, elastic swelling and buckling, and precipitation of solids, which make them more complicated to engineer as a carbon capture material. To address this, a mechanistic model for mass transfer and chemical reaction has been developed, which accounts for these behaviors, and can be used as a predictive tool to explore capsule performance under different CO2 capture scenarios. The model uses a modified film theory to describe CO2 and H2O mass transfer rates, a concentration based description of vapor-liquid-solid equilibrium inside the capsule, and an elastic description of the capsule shell. Model predictions compare favorably to literature data for precipitating carbonates, as well as recent data for microcapsule CO2 absorption. The model was used to assess practical issues of capsule water transfer during a temperature swing CO2 absorption/desorption cycle. Model predictions indicate that capsules filled with high weight percent, precipitating sodium carbonate solution could be significantly or completely dehydrated during CO2 absorption. Subsequent rehydration of lean capsules at elevated temperature showed strong sensitivity to both gas humidity, and capsule shell elasticity.},

  doi          = {10.1016/j.ijggc.2018.04.022},

  url          = {https://www.osti.gov/biblio/1491082},
  journal      = {International Journal of Greenhouse Gas Control},

  issn         = {1750-5836},

  number       = C,

  volume       = 74,

  place        = {United States},

  year         = {Thu May 10 00:00:00 EDT 2018},

  month        = {Thu May 10 00:00:00 EDT 2018}

}

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Review of liquid nano-absorbents for enhanced CO ₂ capture
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Yu, Wei; Wang, Tao; Park, Ah-Hyung Alissa
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Deformation and water loss from solvent filled microcapsules under compressive loads
journal, January 2020

Finn, Justin R.; Galvin, Janine E.; Panday, Rupen
AIChE Journal, Vol. 66, Issue 5
https://doi.org/10.1002/aic.16905

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Modeling and simulation of CO 2 capture using semipermeable elastic microcapsules

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Title: Modeling and simulation of CO2 capture using semipermeable elastic microcapsules

Abstract

Citation Formats

CO2 capture with potassium carbonate solutions: A state-of-the-art review journal, October 2015

Explorative analysis of advanced solvent processes for energy efficient carbon dioxide capture by gas–liquid absorption journal, June 2016

Carbon dioxide absorption with aqueous potassium carbonate promoted by piperazine journal, September 2004

Vapor-liquid equilibria in multicomponent aqueous solutions of volatile weak electrolytes journal, November 1978

New Method for Prediction of Binary Gas-Phase Diffusion Coefficients journal, May 1966

Solid Phases and Their Solubilities in the System Na 2 CO 3 + NaHCO 3 + Ethylene Glycol + Water from (50 to 90) °C journal, January 2004

Thermodynamic solution model for trona brines journal, July 2003

Corrosion in MEA units for CO2 capture: Pilot plant studies journal, February 2009

Buckling of spherical capsules journal, October 2011

CO2 capture from coal-fired power plants based on sodium carbonate slurry; a systems feasibility and sensitivity study journal, March 2009

Vapor–liquid equilibrium in the sodium carbonate–sodium bicarbonate–water–CO2-system journal, March 2010

Density and N2O solubility of sodium and potassium carbonate solutions in the temperature range 25 to 80 °C journal, March 2010

Kinetics of the reaction of carbon dioxide with aqueous sodium and potassium carbonate solutions journal, December 2010

Kinetics of the Gas−Liquid Reaction between Carbon Dioxide and Hydroxide Ions journal, November 2002

Gaseous Diffusion Coefficients journal, January 1972

Toward transformational carbon capture systems journal, October 2015

Semipermeable Elastic Microcapsules for Gas Capture and Sensing journal, September 2016

Kinetics of reaction between carbon dioxide and hydroxyl ions in aqueous electrolyte solutions journal, January 1988

Numerical deflation of beach balls with various Poisson’s ratios: From sphere to bowl’s shape journal, June 2012

Techno-economic Evaluation of CO 2 Capture from Flue Gases Using Encapsulated Solvent journal, February 2017

Properties of Concentrated Solutions of Sodium Carbonate journal, October 1939

Chemical absorption and desorption of carbon dioxide from hot carbonate solutions journal, January 1980

The estimation of gas solubilities in salt solutions journal, January 1993

Thermodynamic Assessment of Microencapsulated Sodium Carbonate Slurry for Carbon Capture journal, January 2014

Microencapsulation of advanced solvents for carbon capture journal, January 2016

CO2 Absorption Kinetics of Micro-encapsulated Ionic Liquids journal, July 2017

LII. The viscosity of gases and molecular force journal, December 1893

Encapsulated liquid sorbents for carbon dioxide capture journal, February 2015

Solubility and diffusivity of acid gases (carbon dioxide, nitrous oxide) in aqueous alkanolamine solutions journal, January 1988

Loss of stability—a new model for stress relaxation in plant cell walls journal, October 2003

Estimation of gas solubilities in salt solutions at temperatures from 273 K to 363 K journal, January 1996

Estimation of gas solubilities in salt solutions at temperatures from 273 K to 363 K journal, January 1996

Review of liquid nano-absorbents for enhanced CO 2 capture journal, January 2019

Deformation and water loss from solvent filled microcapsules under compressive loads journal, January 2020

Title: Modeling and simulation of CO₂ capture using semipermeable elastic microcapsules

CO2 capture with potassium carbonate solutions: A state-of-the-art review
journal, October 2015

Explorative analysis of advanced solvent processes for energy efficient carbon dioxide capture by gas–liquid absorption
journal, June 2016

Carbon dioxide absorption with aqueous potassium carbonate promoted by piperazine
journal, September 2004

Vapor-liquid equilibria in multicomponent aqueous solutions of volatile weak electrolytes
journal, November 1978

New Method for Prediction of Binary Gas-Phase Diffusion Coefficients
journal, May 1966

Solid Phases and Their Solubilities in the System Na ₂ CO ₃ + NaHCO ₃ + Ethylene Glycol + Water from (50 to 90) °C
journal, January 2004

Thermodynamic solution model for trona brines
journal, July 2003

Corrosion in MEA units for CO2 capture: Pilot plant studies
journal, February 2009

Buckling of spherical capsules
journal, October 2011

CO₂ capture from coal-fired power plants based on sodium carbonate slurry; a systems feasibility and sensitivity study
journal, March 2009

Vapor–liquid equilibrium in the sodium carbonate–sodium bicarbonate–water–CO2-system
journal, March 2010

Density and N2O solubility of sodium and potassium carbonate solutions in the temperature range 25 to 80 °C
journal, March 2010

Kinetics of the reaction of carbon dioxide with aqueous sodium and potassium carbonate solutions
journal, December 2010

Kinetics of the Gas−Liquid Reaction between Carbon Dioxide and Hydroxide Ions
journal, November 2002

Gaseous Diffusion Coefficients
journal, January 1972

Toward transformational carbon capture systems
journal, October 2015

Semipermeable Elastic Microcapsules for Gas Capture and Sensing
journal, September 2016

Kinetics of reaction between carbon dioxide and hydroxyl ions in aqueous electrolyte solutions
journal, January 1988

Numerical deflation of beach balls with various Poisson’s ratios: From sphere to bowl’s shape
journal, June 2012

Techno-economic Evaluation of CO ₂ Capture from Flue Gases Using Encapsulated Solvent
journal, February 2017

Properties of Concentrated Solutions of Sodium Carbonate
journal, October 1939

Chemical absorption and desorption of carbon dioxide from hot carbonate solutions
journal, January 1980

The estimation of gas solubilities in salt solutions
journal, January 1993

Thermodynamic Assessment of Microencapsulated Sodium Carbonate Slurry for Carbon Capture
journal, January 2014

Microencapsulation of advanced solvents for carbon capture
journal, January 2016

CO2 Absorption Kinetics of Micro-encapsulated Ionic Liquids
journal, July 2017

LII. The viscosity of gases and molecular force
journal, December 1893

Encapsulated liquid sorbents for carbon dioxide capture
journal, February 2015

Solubility and diffusivity of acid gases (carbon dioxide, nitrous oxide) in aqueous alkanolamine solutions
journal, January 1988

Loss of stability—a new model for stress relaxation in plant cell walls
journal, October 2003

Estimation of gas solubilities in salt solutions at temperatures from 273 K to 363 K
journal, January 1996

Estimation of gas solubilities in salt solutions at temperatures from 273 K to 363 K
journal, January 1996

Review of liquid nano-absorbents for enhanced CO ₂ capture
journal, January 2019

Deformation and water loss from solvent filled microcapsules under compressive loads
journal, January 2020