skip to main content
OSTI.GOV title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Deciphering the Cathode-Electrolyte Interfacial Chemistry in Sodium Layered Cathode Materials

Journal Article · · Advanced Energy Materials
 [1];  [1];  [2];  [3];  [4];  [1];  [2];  [5];  [6];  [7]; ORCiD logo [1]
  1. Virginia Polytechnic Inst. and State Univ. (Virginia Tech), Blacksburg, VA (United States)
  2. Argonne National Lab. (ANL), Argonne, IL (United States)
  3. Tianjin Univ., Tianjin (China); SLAC National Accelerator Lab., Menlo Park, CA (United States)
  4. China Institute of Atomic Energy, Beijing (China)
  5. Tianjin Univ., Tianjin (China)
  6. SLAC National Accelerator Lab., Menlo Park, CA (United States)
  7. Brookhaven National Lab. (BNL), Upton, NY (United States); Univ. of California, Irvine, CA (United States)

Research Organization:
SLAC National Accelerator Laboratory (SLAC), Menlo Park, CA (United States); Argonne National Laboratory (ANL), Argonne, IL (United States)
Sponsoring Organization:
USDOE Office of Science (SC); Canadian Light Source, Inc.
Grant/Contract Number:
AC02-76SF00515; SC0012704; AC02-06CH11357; DE‐AC02‐76SF00515; DE‐SC0012704; DE‐AC02‐06CH11357
OSTI ID:
1490880
Alternate ID(s):
OSTI ID: 1479832; OSTI ID: 1493885
Journal Information:
Advanced Energy Materials, Vol. 8, Issue 34; ISSN 1614-6832
Publisher:
WileyCopyright Statement
Country of Publication:
United States
Language:
English
Citation Metrics:
Cited by: 79 works
Citation information provided by
Web of Science

References (57)

Sodium-Deficient O3-Na 0.9 [Ni 0.4 Mn x Ti 0.6− x ]O 2 Layered-Oxide Cathode Materials for Sodium-Ion Batteries journal December 2015
Role of Disproportionation in the Dissolution of Mn from Lithium Manganate Spinel journal September 2017
Sodium and Sodium-Ion Batteries: 50 Years of Research journal February 2018
In Operando XRD and TXM Study on the Metastable Structure Change of NaNi 1/3 Fe 1/3 Mn 1/3 O 2 under Electrochemical Sodium-Ion Intercalation journal September 2016
Surface reconstruction and chemical evolution of stoichiometric layered cathode materials for lithium-ion batteries journal March 2014
Study on the Reversible Electrode Reaction of Na 1– x Ni 0.5 Mn 0.5 O 2 for a Rechargeable Sodium-Ion Battery journal May 2012
Mn(II) deposition on anodes and its effects on capacity fade in spinel lithium manganate–carbon systems journal September 2013
P2-Na0.6[Cr0.6Ti0.4]O2 cation-disordered electrode for high-rate symmetric rechargeable sodium-ion batteries journal April 2015
Propagation topography of redox phase transformations in heterogeneous layered oxide cathode materials journal July 2018
Excellent Comprehensive Performance of Na-Based Layered Oxide Benefiting from the Synergetic Contributions of Multimetal Ions journal April 2017
Measuring Oxygen Release from Delithiated LiNi x Mn y Co 1-x-y O 2 and Its Effects on the Performance of High Voltage Li-Ion Cells journal January 2017
Na-ion batteries, recent advances and present challenges to become low cost energy storage systems journal January 2012
High Voltage Mg-Doped Na 0.67 Ni 0.3– x Mg x Mn 0.7 O 2 ( x = 0.05, 0.1) Na-Ion Cathodes with Enhanced Stability and Rate Capability journal July 2016
In Situ X-Ray Diffraction Study of P2-Na[sub 2/3][Ni[sub 1/3]Mn[sub 2/3]]O[sub 2] journal January 2001
Large-Scale Synthesis of NaNi 1/3 Fe 1/3 Mn 1/3 O 2 as High Performance Cathode Materials for Sodium Ion Batteries journal January 2016
Room-temperature stationary sodium-ion batteries for large-scale electric energy storage journal January 2013
Layered Na[Ni1/3Fe1/3Mn1/3]O2 cathodes for Na-ion battery application journal January 2012
Residual Lithium Carbonate Predominantly Accounts for First Cycle CO 2 and CO Outgassing of Li-Stoichiometric and Li-Rich Layered Transition-Metal Oxides journal November 2017
Dissolution, migration, and deposition of transition metal ions in Li-ion batteries exemplified by Mn-based cathodes – a critical review journal January 2018
Intrinsic Origins of Crack Generation in Ni-rich LiNi0.8Co0.1Mn0.1O2 Layered Oxide Cathode Material journal January 2017
Profiling the nanoscale gradient in stoichiometric layered cathode particles for lithium-ion batteries journal January 2014
Electrochemical intercalation activity of layered NaCrO2 vs. LiCrO2 journal March 2010
New Insights into the Performance Degradation of Fe-Based Layered Oxides in Sodium-Ion Batteries: Instability of Fe 3+ /Fe 4+ Redox in α-NaFeO 2 journal September 2015
Electrochemical Oxidation of Lithium Carbonate Generates Singlet Oxygen journal April 2018
Computational and Experimental Investigation of Ti Substitution in Li 1 (Ni x Mn x Co 1–2 xy Ti y )O 2 for Lithium Ion Batteries journal October 2014
Structure of the high voltage phase of layered P2-Na 2/3−z [Mn 1/2 Fe 1/2 ]O 2 and the positive effect of Ni substitution on its stability journal January 2015
Vacancy Ordering in O 3 -Type Layered Metal Oxide Sodium-Ion Battery Cathodes journal December 2015
Coupling of electrochemically triggered thermal and mechanical effects to aggravate failure in a layered cathode journal June 2018
Suppressing the P2-O2 Phase Transition of Na 0.67 Mn 0.67 Ni 0.33 O 2 by Magnesium Substitution for Improved Sodium-Ion Batteries journal May 2016
Prototype Sodium-Ion Batteries Using an Air-Stable and Co/Ni-Free O3-Layered Metal Oxide Cathode journal October 2015
Orthorhombic Na[sub x]MnO[sub 2] as a Cathode Material for Secondary Sodium and Lithium Polymer Batteries journal January 1994
Transition Metal Dissolution, Ion Migration, Electrocatalytic Reduction and Capacity Loss in Lithium-Ion Full Cells journal December 2016
P2-type Na 2/3 Ni 1/3 Mn 2/3−x Ti x O 2 as a new positive electrode for higher energy Na-ion batteries journal January 2014
A 3.8-V earth-abundant sodium battery electrode journal July 2014
Synthesis and Electrode Performance of O3-Type NaFeO 2 -NaNi 1/2 Mn 1/2 O 2 Solid Solution for Rechargeable Sodium Batteries journal January 2013
Structurally stable Mg-doped P2-Na 2/3 Mn 1−y Mg y O 2 sodium-ion battery cathodes with high rate performance: insights from electrochemical, NMR and diffraction studies journal January 2016
Recent research progress on iron- and manganese-based positive electrode materials for rechargeable sodium batteries journal August 2014
Empowering multicomponent cathode materials for sodium ion batteries by exploring three-dimensional compositional heterogeneities journal January 2018
Environmentally stable interface of layered oxide cathodes for sodium-ion batteries journal July 2017
Exploring Oxygen Activity in the High Energy P2-Type Na 0.78 Ni 0.23 Mn 0.69 O 2 Cathode Material for Na-Ion Batteries journal March 2017
Understanding the Degradation Mechanisms of LiNi 0.5 Co 0.2 Mn 0.3 O 2 Cathode Material in Lithium Ion Batteries journal August 2013
Resolving the degradation pathways of the O3-type layered oxide cathode surface through the nano-scale aluminum oxide coating for high-energy density sodium-ion batteries journal January 2017
Ti-Substituted NaNi 0.5 Mn 0.5- x Ti x O 2 Cathodes with Reversible O3−P3 Phase Transition for High-Performance Sodium-Ion Batteries journal March 2017
Intragranular cracking as a critical barrier for high-voltage usage of layer-structured cathode for lithium-ion batteries journal January 2017
NaCrO 2 cathode for high-rate sodium-ion batteries journal January 2015
Improvement of the Cathode Electrolyte Interphase on P2-Na 2/3 Ni 1/3 Mn 2/3 O 2 by Atomic Layer Deposition journal July 2017
Nucleation of dislocations and their dynamics in layered oxide cathode materials during battery charging journal July 2018
P2-type Nax[Fe1/2Mn1/2]O2 made from earth-abundant elements for rechargeable Na batteries journal April 2012
XPS-Surface Analysis of SEI Layers on Li-Ion Cathodes: Part II. SEI-Composition and Formation inside Composite Electrodes journal January 2018
Electrochemical and Thermal Properties of α-NaFeO 2 Cathode for Na-Ion Batteries journal January 2013
Sodium-ion batteries: present and future journal January 2017
Designing Air-Stable O3-Type Cathode Materials by Combined Structure Modulation for Na-Ion Batteries journal June 2017
Dual Stabilization and Sacrificial Effect of Na 2 CO 3 for Increasing Capacities of Na-Ion Cells Based on P2-Na x MO 2 Electrodes journal July 2017
Structural classification and properties of the layered oxides journal January 1980
Improved stability of Ni-rich cathode by the substitutive cations with stronger bonds journal April 2018
Suppressing the P2-O2 Phase Transition of Na 0.67 Mn 0.67 Ni 0.33 O 2 by Magnesium Substitution for Improved Sodium-Ion Batteries journal May 2016
Nucleation of dislocations and their dynamics in layered oxide cathode materials during battery charging text January 2018

Cited By (3)

Electrolytes and Electrolyte/Electrode Interfaces in Sodium‐Ion Batteries: From Scientific Research to Practical Application journal March 2019
Understanding Challenges of Cathode Materials for Sodium‐Ion Batteries using Synchrotron‐Based X‐Ray Absorption Spectroscopy journal July 2019
Water-Processable P2-Na 0.67 Ni 0.22 Cu 0.11 Mn 0.56 Ti 0.11 O 2 Cathode Material for Sodium Ion Batteries journal January 2019

Similar Records

Effect of Electrolytes on the Cathode-Electrolyte Interfacial Stability of Fe-Based Layered Cathodes for Sodium-Ion Batteries
Journal Article · Mon Mar 21 00:00:00 EDT 2022 · Journal of the Electrochemical Society · OSTI ID:1490880

High-Entropy and Superstructure-Stabilized Layered Oxide Cathodes for Sodium-Ion Batteries
Journal Article · Thu Sep 08 00:00:00 EDT 2022 · Advanced Energy Materials · OSTI ID:1490880

Whole-Voltage-Range Oxygen Redox in P2-Layered Cathode Materials for Sodium-Ion Batteries
Journal Article · Mon Mar 01 00:00:00 EST 2021 · Advanced Materials · OSTI ID:1490880