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Title: A core–shell electrode for dynamically and statically stable Li–S battery chemistry

Journal Article · · Energy & Environmental Science
DOI:https://doi.org/10.1039/c6ee01280a· OSTI ID:1430184
 [1];  [1];  [1]
  1. Univ. of Texas, Austin, TX (United States). Materials Science and Engineering Program & Texas Materials Institute

The design of a core–shell sulfur cathode demonstrates superior dynamic and static stability at a high sulfur loading in Li–S batteries.

Research Organization:
Univ. of Texas, Austin, TX (United States)
Sponsoring Organization:
USDOE Office of Energy Efficiency and Renewable Energy (EERE)
Grant/Contract Number:
EE0007218
OSTI ID:
1430184
Alternate ID(s):
OSTI ID: 1487236
Journal Information:
Energy & Environmental Science, Vol. 9, Issue 10; ISSN 1754-5692
Publisher:
Royal Society of ChemistryCopyright Statement
Country of Publication:
United States
Language:
English
Citation Metrics:
Cited by: 111 works
Citation information provided by
Web of Science

References (65)

A high performance lithium-ion sulfur battery based on a Li 2 S cathode using a dual-phase electrolyte journal January 2015
Role of LiNO3 in rechargeable lithium/sulfur battery journal May 2012
High performance lithium–sulfur batteries: advances and challenges journal January 2014
Lithium/Sulfur Cell Discharge Mechanism: An Original Approach for Intermediate Species Identification journal April 2012
Biomass-Derived Heteroatom-Doped Carbon Aerogels from a Salt Melt Sol-Gel Synthesis and their Performance in Li-S Batteries journal August 2015
Effects of sulfur loading on the corrosion behaviors of metal lithium anode in lithium–sulfur batteries journal August 2015
Understanding the Lithium Sulfur Battery System at Relevant Scales journal August 2015
Lithium/sulfur batteries with high specific energy: old challenges and new opportunities journal January 2013
Li-S Battery Analyzed by UV/Vis in Operando Mode journal June 2013
A soft, multilayered lithium–electrolyte interface journal January 2016
New insights into the limiting parameters of the Li/S rechargeable cell journal February 2012
A Polysulfide-Trapping Interface for Electrochemically Stable Sulfur Cathode Development journal February 2016
Prospects and Limits of Energy Storage in Batteries journal February 2015
Robust, Ultra-Tough Flexible Cathodes for High-Energy Li-S Batteries journal December 2015
Electrochemically Stable Rechargeable Lithium-Sulfur Batteries with a Microporous Carbon Nanofiber Filter for Polysulfide journal July 2015
Porous Hollow Carbon@Sulfur Composites for High-Power Lithium-Sulfur Batteries journal May 2011
Bifunctional Separator with a Light-Weight Carbon-Coating for Dynamically and Statically Stable Lithium-Sulfur Batteries journal June 2014
Nanoporous Cathodes for High-Energy Li–S Batteries from Gyroid Block Copolymer Templates journal May 2015
Rechargeable Lithium–Sulfur Batteries journal July 2014
Lithium-Sulfur Cells: The Gap between the State-of-the-Art and the Requirements for High Energy Battery Cells journal April 2015
Functional Mesoporous Carbon-Coated Separator for Long-Life, High-Energy Lithium-Sulfur Batteries journal July 2015
Self-discharge characteristics of lithium/sulfur batteries using TEGDME liquid electrolyte journal December 2006
Porous Carbon Mat as an Electrochemical Testing Platform for Investigating the Polysulfide Retention of Various Cathode Configurations in Li–S Cells journal May 2015
In-Situ Raman Investigation of Polysulfide Formation in Li-S Cells journal January 2013
Porosity Blocking in Highly Porous Carbon Black by PVdF Binder and Its Implications for the Li–S System journal October 2014
Self-Discharge Behavior of Lithium/Sulfur Battery Using Aluminum Current Collector journal June 2005
Improving the self-discharge behavior of sulfur-polypyrrole cathode material by LiNO3 electrolyte additive journal March 2014
On the Surface Chemical Aspects of Very High Energy Density, Rechargeable Li–Sulfur Batteries journal January 2009
Sulfur solubility in pure and mixed organic solvents journal March 1988
Lithium-Sulfur Batteries: Electrochemistry, Materials, and Prospects journal November 2013
Polysulfide Shuttle Study in the Li/S Battery System journal January 2004
To mitigate self-discharge of lithium–sulfur batteries by optimizing ionic liquid electrolytes journal January 2016
Self-discharge of lithium–sulfur cells using stainless-steel current-collectors journal February 2005
Lithium-Sulfur Batteries: Progress and Prospects journal February 2015
Status and prospects in sulfur–carbon composites as cathode materials for rechargeable lithium–sulfur batteries journal October 2015
Electrochemical Impedance Spectroscopy Study of a Lithium/Sulfur Battery: Modeling and Analysis of Capacity Fading journal January 2013
Recent Advances in Lithium Sulfide Cathode Materials and Their Use in Lithium Sulfur Batteries journal April 2015
Capacity Fading Mechanisms on Cycling a High-Capacity Secondary Sulfur Cathode journal January 2004
Progress Towards Commercially Viable Li-S Battery Cells journal April 2015
Sulfur Speciation in Li–S Batteries Determined by Operando X-ray Absorption Spectroscopy journal September 2013
Effective Stabilization of a High-Loading Sulfur Cathode and a Lithium-Metal Anode in Li-S Batteries Utilizing SWCNT-Modulated Separators journal November 2015
Low-cost, porous carbon current collector with high sulfur loading for lithium–sulfur batteries journal January 2014
Synthesis and characterization of sulfur–carbon–vanadium pentoxide composites for improved electrochemical properties of lithium–sulfur batteries journal January 2016
Lithium sulfur batteries, a mechanistic review journal January 2015
Structure, porosity and conductivity of PVdF films for polymer electrolytes journal July 2001
Recent advances in lithium–sulfur batteries journal December 2014
Pie-like electrode design for high-energy density lithium–sulfur batteries journal November 2015
Lithium–sulfur batteries with activated carbons derived from olive stones journal April 2014
A study of the electrochemical processes in lithium–sulphur cells by impedance spectroscopy journal February 2011
Does the sulfur cathode require good mixing for a liquid electrolyte lithium/sulfur cell? journal June 2013
Reversibility of electrochemical reactions of sulfur supported on inverse opal carbon in glyme–Li salt molten complex electrolytes journal January 2011
A layer-by-layer supramolecular structure for a sulfur cathode journal January 2016
Lithium/Sulfur Batteries Upon Cycling: Structural Modifications and Species Quantification by In Situ and Operando X-Ray Diffraction Spectroscopy journal May 2015
Porous graphene oxide/carbon nanotube hybrid films as interlayer for lithium-sulfur batteries journal April 2016
Li–O2 and Li–S batteries with high energy storage journal January 2012
Bis(2,2,2-trifluoroethyl) Ether As an Electrolyte Co-solvent for Mitigating Self-Discharge in Lithium–Sulfur Batteries journal May 2014
Effects of Liquid Electrolytes on the Charge–Discharge Performance of Rechargeable Lithium/Sulfur Batteries: Electrochemical and in-Situ X-ray Absorption Spectroscopic Studies journal October 2011
Multi-functional separator/interlayer system for high-stable lithium-sulfur batteries: Progress and prospects journal November 2015
Hollow Carbon Nanofibers Filled with MnO 2 Nanosheets as Efficient Sulfur Hosts for Lithium-Sulfur Batteries journal September 2015
High Energy Density Lithium-Sulfur Batteries: Challenges of Thick Sulfur Cathodes journal March 2015
Structural Design of Cathodes for Li-S Batteries journal April 2015
Improved cycling stability of lithium–sulfur batteries using a polypropylene-supported nitrogen-doped mesoporous carbon hybrid separator as polysulfide adsorbent journal January 2016
Lithium–sulfur batteries with superior cycle stability by employing porous current collectors journal September 2013
Porous Hollow Carbon@Sulfur Composites for High-Power Lithium-Sulfur Batteries journal May 2011
Hollow Carbon Nanofibers Filled with MnO 2 Nanosheets as Efficient Sulfur Hosts for Lithium-Sulfur Batteries journal September 2015

Cited By (36)

Rational Design of MXene/1T-2H MoS 2 -C Nanohybrids for High-Performance Lithium-Sulfur Batteries journal March 2018
Creating Effective Nanoreactors on Carbon Nanotubes with Mechanochemical Treatments for High-Areal-Capacity Sulfur Cathodes and Lithium Anodes journal June 2018
Progress on the Critical Parameters for Lithium-Sulfur Batteries to be Practically Viable journal May 2018
Phenyl Selenosulfides as Cathode Materials for Rechargeable Lithium Batteries journal June 2018
More Reliable Lithium-Sulfur Batteries: Status, Solutions and Prospects journal April 2017
Yolk-Shelled C@Fe 3 O 4 Nanoboxes as Efficient Sulfur Hosts for High-Performance Lithium-Sulfur Batteries journal July 2017
Rational Design of Statically and Dynamically Stable Lithium-Sulfur Batteries with High Sulfur Loading and Low Electrolyte/Sulfur Ratio journal December 2017
Long-Life Lithium-Sulfur Batteries with a Bifunctional Cathode Substrate Configured with Boron Carbide Nanowires journal August 2018
A Facile, Low-Cost Hot-Pressing Process for Fabricating Lithium-Sulfur Cells with Stable Dynamic and Static Electrochemistry journal October 2018
Current Status and Future Prospects of Metal–Sulfur Batteries journal May 2019
Simultaneous Suppression of the Dendrite Formation and Shuttle Effect in a Lithium-Sulfur Battery by Bilateral Solid Electrolyte Interface journal July 2018
Review on High-Loading and High-Energy Lithium-Sulfur Batteries journal May 2017
A High-Volumetric-Capacity Cathode Based on Interconnected Close-Packed N-Doped Porous Carbon Nanospheres for Long-Life Lithium-Sulfur Batteries journal August 2017
High-Performance and Low-Temperature Lithium-Sulfur Batteries: Synergism of Thermodynamic and Kinetic Regulation journal March 2018
In Situ Assembly of 2D Conductive Vanadium Disulfide with Graphene as a High-Sulfur-Loading Host for Lithium-Sulfur Batteries journal April 2018
Nitrogen-Doped Graphene-Supported Mixed Transition-Metal Oxide Porous Particles to Confine Polysulfides for Lithium-Sulfur Batteries journal May 2018
Highly Stable Lithium-Sulfur Batteries Based on Laponite Nanosheet-Coated Celgard Separators journal July 2018
Solid-State Lithium/Selenium-Sulfur Chemistry Enabled via a Robust Solid-Electrolyte Interphase journal November 2018
Interfacial Charge Field in Hierarchical Yolk–Shell Nanocapsule Enables Efficient Immobilization and Catalysis of Polysulfides Conversion journal July 2019
Polysulfide Confinement and Highly Efficient Conversion on Hierarchical Mesoporous Carbon Nanosheets for Li–S Batteries journal September 2019
High‐Sulfur‐Content Graphene‐Based Composite through Ethanol Evaporation for High‐Energy Lithium‐Sulfur Battery journal March 2020
Sulfur Loaded by Nanometric Tin as a New Electrode for High‐Performance Lithium/Sulfur Batteries journal May 2019
Functional Differentiation of Three Pores for Effective Sulfur Confinement in Li-S Battery journal January 2018
Greatly Improved Conductivity of Double-Chain Polymer Network Binder for High Sulfur Loading Lithium-Sulfur Batteries with a Low Electrolyte/Sulfur Ratio journal July 2018
Nanostructured Host Materials for Trapping Sulfur in Rechargeable Li-S Batteries: Structure Design and Interfacial Chemistry journal November 2017
Layered Electrodes Based on 3D Hierarchical Porous Carbon and Conducting Polymers for High‐Performance Lithium‐Sulfur Batteries journal January 2019
Sulfur nanoparticles encapsulated in reduced graphene oxide nanotubes for flexible lithium-sulfur batteries journal February 2018
Structural Design of Lithium–Sulfur Batteries: From Fundamental Research to Practical Application journal June 2018
Recent innovative configurations in high-energy lithium–sulfur batteries journal January 2017
Electrostatic trapping of polysulfides enabled by imidazolium-based ionic polymers for high-energy-density lithium–sulfur batteries journal January 2018
Current-density dependence of Li 2 S/Li 2 S 2 growth in lithium–sulfur batteries journal January 2019
Self-Discharge Behavior of Lithium-Sulfur Batteries at Different Electrolyte/Sulfur Ratios journal January 2019
Flow Battery Molecular Reactant Stability Determined by Symmetric Cell Cycling Methods journal January 2018
Low-Temperature Conductivity Study of Multiorganic Solvent Electrolyte for Lithium-Sulfur Rechargeable Battery Application journal November 2019
Stabilizing the Performance of High-Capacity Sulfur Composite Electrodes by a New Gel Polymer Electrolyte Configuration journal August 2017
Chemisorption of polysulfides through redox reactions with organic molecules for lithium–sulfur batteries journal February 2018

Figures / Tables (8)