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Title: Increasing spin crossover cooperativity in 2D Hofmann-type materials with guest molecule removal

Abstract

Ambient temperature spin crossover with wide hysteresis has been achieved in 2D Hofmann-type materials, where removal of guest molecules optimises ligand–ligand interactions, resulting in increased cooperativity.

Authors:
ORCiD logo [1];  [1];  [2];  [2]; ORCiD logo [3]; ORCiD logo [1];  [1];  [4]
  1. School of Chemistry; The University of Sydney; Sydney; Australia
  2. Univ Rennes; CNRS; IPR (Institut de Physique de Rennes) – UMR 6251; F-35000 Rennes; France
  3. Graduate School of Engineering; Nagasaki University; Nagasaki-shi Nagasaki 852-8521; Japan
  4. School of Chemistry; The University of Sydney; Sydney; Australia; School of Chemistry
Publication Date:
Research Org.:
Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source (APS)
Sponsoring Org.:
FOREIGN
OSTI Identifier:
1485677
Resource Type:
Journal Article
Journal Name:
Chemical Science
Additional Journal Information:
Journal Volume: 9; Journal Issue: 25; Journal ID: ISSN 2041-6520
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
ENGLISH

Citation Formats

Zenere, Katrina A., Duyker, Samuel G., Trzop, Elzbieta, Collet, Eric, Chan, Bun, Doheny, Patrick W., Kepert, Cameron J., and Neville, Suzanne M. Increasing spin crossover cooperativity in 2D Hofmann-type materials with guest molecule removal. United States: N. p., 2018. Web. doi:10.1039/C8SC01040D.
Zenere, Katrina A., Duyker, Samuel G., Trzop, Elzbieta, Collet, Eric, Chan, Bun, Doheny, Patrick W., Kepert, Cameron J., & Neville, Suzanne M. Increasing spin crossover cooperativity in 2D Hofmann-type materials with guest molecule removal. United States. doi:10.1039/C8SC01040D.
Zenere, Katrina A., Duyker, Samuel G., Trzop, Elzbieta, Collet, Eric, Chan, Bun, Doheny, Patrick W., Kepert, Cameron J., and Neville, Suzanne M. Mon . "Increasing spin crossover cooperativity in 2D Hofmann-type materials with guest molecule removal". United States. doi:10.1039/C8SC01040D.
@article{osti_1485677,
title = {Increasing spin crossover cooperativity in 2D Hofmann-type materials with guest molecule removal},
author = {Zenere, Katrina A. and Duyker, Samuel G. and Trzop, Elzbieta and Collet, Eric and Chan, Bun and Doheny, Patrick W. and Kepert, Cameron J. and Neville, Suzanne M.},
abstractNote = {Ambient temperature spin crossover with wide hysteresis has been achieved in 2D Hofmann-type materials, where removal of guest molecules optimises ligand–ligand interactions, resulting in increased cooperativity.},
doi = {10.1039/C8SC01040D},
journal = {Chemical Science},
issn = {2041-6520},
number = 25,
volume = 9,
place = {United States},
year = {2018},
month = {1}
}