Tuning martensitic transitions in (MnNiSi)0.65(Fe2Ge)0.35 through heat treatment and hydrostatic pressure

Chen, Jing-Han; Us Saleheen, Ahmad; Karna, Sunil K.; Young, David P.; Dubenko, Igor; Ali, Naushad; Stadler, Shane

doi:10.1063/1.5051551

Title: Tuning martensitic transitions in (MnNiSi)_0.65(Fe₂Ge)_0.35 through heat treatment and hydrostatic pressure

Journal Article · Wed Nov 28 00:00:00 EST 2018 · Journal of Applied Physics

DOI:https://doi.org/10.1063/1.5051551· OSTI ID:1484787

Chen, Jing-Han ^[1]; Us Saleheen, Ahmad ^[1]; Karna, Sunil K. ^[1]; Young, David P. ^[1]; Dubenko, Igor ^[2]; Ali, Naushad ^[2]; Stadler, Shane ^[1]

Louisiana State Univ., Baton Rouge, LA (United States)
Southern Illinois Univ., Carbondale, IL (United States)

A first-order magneto-structural transition from a ferromagnetic orthorhombic TiNiSi-type martensite phase to a paramagnetic hexagonal Ni2In-type austenite phase was observed in (MnNiSi)_0.65(Fe2Ge)_0.35. In this work, we demonstrate that the first-order magneto-structural transition temperature for a given composition is tunable over a wide temperature range through heat treatment and hydrostatic pressure. The first-order transition temperature was reduced by over 100 K as the annealing temperature went from 600 to 900 °C, and this first-order transition was converted to second order when the sample was annealed at 1000 °C. The maximum magnetic-induced isothermal entropy change with μ0ΔH=7 T reaches -58 J/kg K for the sample annealed at 600 °C, and the relative cooling power reaches 558 J/kg for the sample annealed at 700 °C. Similar to the influence of annealing temperatures, the first-order martensitic transition temperatures were reduced as the application of hydrostatic pressure increased until they were converted to second order. Our results suggest that the (MnNiSi)_0.65(Fe2Ge)_0.35 system is a promising platform for tuning magneto-structural transitions and the associated magnetocaloric effects. Furthermore, a similar heat treatment methodology or application of hydrostatic pressure can be applied to MnNiSi-based shape memory alloys to tailor their working transition temperatures.

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Research Organization:: Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source (APS); Louisiana State Univ., Baton Rouge, LA (United States); Southern Illinois Univ., Carbondale, IL (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC02-06CH11357; FG02-13ER46946; FG02-06ER46291; SC0012432; NSF-DMR- 1306392; SC0010521

OSTI ID:: 1484787

Alternate ID(s):: OSTI ID: 1872463

Journal Information:: Journal of Applied Physics, Vol. 124, Issue 20; ISSN 0021-8979

Publisher:: American Institute of Physics (AIP)Copyright Statement

Country of Publication:: United States

Language:: ENGLISH

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Cited by: 10 works

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Title: Tuning martensitic transitions in (MnNiSi)0.65(Fe2Ge)0.35 through heat treatment and hydrostatic pressure

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Title: Tuning martensitic transitions in (MnNiSi)_0.65(Fe₂Ge)_0.35 through heat treatment and hydrostatic pressure