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Metal oxide-organic hybrid materials for heterogeneous catalysis and methods of making and using thereof

Patent ·
OSTI ID:1484199

Catalysts prepared from abundant, cost effective metals, such as cobalt, nickel, chromium, manganese, iron, and copper, and containing one or more neutrally charged ligands (e.g., monodentate, bidentate, and/or polydentate ligands) and methods of making and using thereof are described herein. Exemplary ligands include, but are not limited to, phosphine ligands, nitrogen-based ligands, sulfur-based ligands, and/or arsenic-based ligands. In some embodiments, the catalyst is a cobalt-based catalyst or a nickel-based catalyst. The catalysts described herein are stable and active at neutral pH and in a wide range of buffers that are both weak and strong proton acceptors. While its activity is slightly lower than state of the art cobalt-based water oxidation catalysts under some conditions, it is capable of sustaining electrolysis at high applied potentials without a significant degradation in catalytic current. This enhanced robustness gives it an advantage in industrial and large-scale water electrolysis schemes.

Research Organization:
Yale University, New Haven, CT (United States)
Sponsoring Organization:
USDOE
DOE Contract Number:
FG02-84ER13297
Assignee:
Yale University (New Haven, CT)
Patent Number(s):
10,081,650
Application Number:
14/322,773
OSTI ID:
1484199
Country of Publication:
United States
Language:
English

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