Lattice Distortion and Phase Stability of Pd-Doped NiCoFeCr Solid-Solution Alloys

Zhang, Fuxiang; Tong, Yang; Jin, Ke; Bei, Hongbin; Weber, William J.; Zhang, Yanwen

doi:10.3390/e20120900

Title: Lattice Distortion and Phase Stability of Pd-Doped NiCoFeCr Solid-Solution Alloys

Journal Article · Sun Nov 25 00:00:00 EST 2018 · Entropy

DOI:https://doi.org/10.3390/e20120900· OSTI ID:1484109

^[1];

^[2];

^[1]

Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Univ. of Tennessee, Knoxville, TN (United States)

In the present study, we have revealed that (NiCoFeCr)_100–xPd_x (x= 1, 3, 5, 20 atom%) high-entropy alloys (HEAs) have both local- and long-range lattice distortions by utilizing X-ray total scattering, X-ray diffraction, and extended X-ray absorption fine structure methods. The local lattice distortion determined by the lattice constant difference between the local and average structures was found to be proportional to the Pd content. A small amount of Pd-doping (1 atom%) yields long-range lattice distortion, which is demonstrated by a larger (200) lattice plane spacing than the expected value from an average structure, however, the degree of long-range lattice distortion is not sensitive to the Pd concentration. Here, the structural stability of these distorted HEAs under high-pressure was also examined. The experimental results indicate that doping with a small amount of Pd significantly enhances the stability of the fcc phase by increasing the fcc-to-hcp transformation pressure from ~13.0 GPa in NiCoFeCr to 20–26 GPa in the Pd-doped HEAs and NiCoFeCrPd maintains its fcc lattice up to 74 GPa, the maximum pressure that the current experiments have reached.

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: Energy Frontier Research Centers (EFRC) (United States). Energy Dissipation to Defect Evolution (EDDE); Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1484109

Journal Information:: Entropy, Vol. 20, Issue 12; ISSN 1099-4300

Publisher:: MDPICopyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 14 works

Citation information provided by
Web of Science

References (38)

Enhanced void swelling in NiCoFeCrPd high-entropy alloy by indentation-induced dislocations Lu, Chenyang; Yang, Taini; Jin, Ke Materials Research Letters, Vol. 6, Issue 10 https://doi.org/10.1080/21663831.2018.1504136	journal	August 2018
ATHENA , ARTEMIS , HEPHAESTUS : data analysis for X-ray absorption spectroscopy using IFEFFIT Ravel, B.; Newville, M. Journal of Synchrotron Radiation, Vol. 12, Issue 4 https://doi.org/10.1107/S0909049505012719	journal	June 2005
A geometric model for intrinsic residual strain and phase stability in high entropy alloys Ye, Y. F.; Liu, C. T.; Yang, Y. Acta Materialia, Vol. 94 https://doi.org/10.1016/j.actamat.2015.04.051	journal	August 2015
Alloy Design Strategies and Future Trends in High-Entropy Alloys Yeh, Jien-Wei JOM, Vol. 65, Issue 12 https://doi.org/10.1007/s11837-013-0761-6	journal	October 2013
An assessment of the lattice strain in the CrMnFeCoNi high-entropy alloy Owen, L. R.; Pickering, E. J.; Playford, H. Y. Acta Materialia, Vol. 122 https://doi.org/10.1016/j.actamat.2016.09.032	journal	January 2017
Local Structure and Short-Range Order in a NiCoCr Solid Solution Alloy Zhang, F. X.; Zhao, Shijun; Jin, Ke Physical Review Letters, Vol. 118, Issue 20 https://doi.org/10.1103/PhysRevLett.118.205501	journal	May 2017
Polymorphism in a high-entropy alloy Zhang, Fei; Wu, Yuan; Lou, Hongbo Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/ncomms15687	journal	June 2017
Recovery, recrystallization, grain growth and phase stability of a family of FCC-structured multi-component equiatomic solid solution alloys Wu, Z.; Bei, H.; Otto, F. Intermetallics, Vol. 46 https://doi.org/10.1016/j.intermet.2013.10.024	journal	March 2014
Enhancing radiation tolerance by controlling defect mobility and migration pathways in multicomponent single-phase alloys Lu, Chenyang; Niu, Liangliang; Chen, Nanjun Nature Communications, Vol. 7, Issue 1 https://doi.org/10.1038/ncomms13564	journal	December 2016
A criterion for the formation of high entropy alloys based on lattice distortion Toda-Caraballo, I.; Rivera-Díaz-del-Castillo, P. E. J. Intermetallics, Vol. 71 https://doi.org/10.1016/j.intermet.2015.12.011	journal	April 2016
Calibration and correction of distortions in two‐dimensional detector systems ^a) Hammersley, A. P.; Svensson, S. O.; Thompson, A. Review of Scientific Instruments, Vol. 66, Issue 3 https://doi.org/10.1063/1.1145618	journal	March 1995
Microstructural development in equiatomic multicomponent alloys Cantor, B.; Chang, I. T. H.; Knight, P. Materials Science and Engineering: A, Vol. 375-377 https://doi.org/10.1016/j.msea.2003.10.257	journal	July 2004
A novel, single phase, non-equiatomic FeMnNiCoCr high-entropy alloy with exceptional phase stability and tensile ductility Yao, M. J.; Pradeep, K. G.; Tasan, C. C. Scripta Materialia, Vol. 72-73 https://doi.org/10.1016/j.scriptamat.2013.09.030	journal	February 2014
Local structure of NiPd solid solution alloys and its response to ion irradiation Zhang, F. X.; Ullah, Mohammad W.; Zhao, Shijun Journal of Alloys and Compounds, Vol. 755 https://doi.org/10.1016/j.jallcom.2018.04.285	journal	July 2018
Sluggish diffusion in Co–Cr–Fe–Mn–Ni high-entropy alloys Tsai, K. -Y.; Tsai, M. -H.; Yeh, J. -W. Acta Materialia, Vol. 61, Issue 13 https://doi.org/10.1016/j.actamat.2013.04.058	journal	August 2013
Evolution of local lattice distortion under irradiation in medium- and high-entropy alloys Tong, Y.; Velisa, G.; Zhao, S. Materialia, Vol. 2 https://doi.org/10.1016/j.mtla.2018.06.008	journal	October 2018
Recent advances in magnetic structure determination by neutron powder diffraction Rodríguez-Carvajal, Juan Physica B: Condensed Matter, Vol. 192, Issue 1-2 https://doi.org/10.1016/0921-4526(93)90108-I	journal	October 1993
Tensile properties of an AlCrCuNiFeCo high-entropy alloy in as-cast and wrought conditions Kuznetsov, A. V.; Shaysultanov, D. G.; Stepanov, N. D. Materials Science and Engineering: A, Vol. 533 https://doi.org/10.1016/j.msea.2011.11.045	journal	January 2012
A critical review of high entropy alloys and related concepts Miracle, D. B.; Senkov, O. N. Acta Materialia, Vol. 122 https://doi.org/10.1016/j.actamat.2016.08.081	journal	January 2017
Microstructures and properties of high-entropy alloys Zhang, Yong; Zuo, Ting Ting; Tang, Zhi Progress in Materials Science, Vol. 61 https://doi.org/10.1016/j.pmatsci.2013.10.001	journal	April 2014
A comparison study of local lattice distortion in Ni 80 Pd 20 binary alloy and FeCoNiCrPd high-entropy alloy Tong, Y.; Zhao, S.; Jin, K. Scripta Materialia, Vol. 156 https://doi.org/10.1016/j.scriptamat.2018.07.002	journal	November 2018
Microstructure and tensile behaviors of FCC Al0.3CoCrFeNi high entropy alloy Shun, Tao-Tsung; Du, Yu-Chin Journal of Alloys and Compounds, Vol. 479, Issue 1-2 https://doi.org/10.1016/j.jallcom.2008.12.088	journal	June 2009
PDFfit2 and PDFgui: computer programs for studying nanostructure in crystals Farrow, C. L.; Juhas, P.; Liu, J. W. Journal of Physics: Condensed Matter, Vol. 19, Issue 33 https://doi.org/10.1088/0953-8984/19/33/335219	journal	July 2007
Microstructures and compressive properties of multicomponent AlCoCrFeNiMox alloys Zhu, J. M.; Fu, H. M.; Zhang, H. F. Materials Science and Engineering: A, Vol. 527, Issue 26 https://doi.org/10.1016/j.msea.2010.07.028	journal	October 2010
Phase stability of non-equiatomic CoCrFeMnNi high entropy alloys Ma, Duancheng; Yao, Mengji; Pradeep, K. G. Acta Materialia, Vol. 98 https://doi.org/10.1016/j.actamat.2015.07.030	journal	October 2015
Influence of chemical disorder on energy dissipation and defect evolution in concentrated solid solution alloys Zhang, Yanwen; Stocks, G. Malcolm; Jin, Ke Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms9736	journal	October 2015
Decomposition of the single-phase high-entropy alloy CrMnFeCoNi after prolonged anneals at intermediate temperatures Otto, F.; Dlouhý, A.; Pradeep, K. G. Acta Materialia, Vol. 112 https://doi.org/10.1016/j.actamat.2016.04.005	journal	June 2016
Pressure-induced fcc to hcp phase transition in Ni-based high entropy solid solution alloys Zhang, F. X.; Zhao, Shijun; Jin, Ke Applied Physics Letters, Vol. 110, Issue 1 https://doi.org/10.1063/1.4973627	journal	January 2017
Exploration and Development of High Entropy Alloys for Structural Applications Miracle, Daniel; Miller, Jonathan; Senkov, Oleg Entropy, Vol. 16, Issue 1 https://doi.org/10.3390/e16010494	journal	January 2014
Metastable high-entropy dual-phase alloys overcome the strength–ductility trade-off Li, Zhiming; Pradeep, Konda Gokuldoss; Deng, Yun Nature, Vol. 534, Issue 7606 https://doi.org/10.1038/nature17981	journal	May 2016
Microstructure, thermophysical and electrical properties in AlxCoCrFeNi (0≤x≤2) high-entropy alloys Chou, Hsuan-Ping; Chang, Yee-Shyi; Chen, Swe-Kai Materials Science and Engineering: B, Vol. 163, Issue 3 https://doi.org/10.1016/j.mseb.2009.05.024	journal	July 2009
High pressure synthesis of a hexagonal close-packed phase of the high-entropy alloy CrMnFeCoNi Tracy, Cameron L.; Park, Sulgiye; Rittman, Dylan R. Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/ncomms15634	journal	May 2017
Formation of simple crystal structures in Cu-Co-Ni-Cr-Al-Fe-Ti-V alloys with multiprincipal metallic elements Yeh, Jien-Wei; Lin, Su-Jien; Chin, Tsung-Shune Metallurgical and Materials Transactions A, Vol. 35, Issue 8 https://doi.org/10.1007/s11661-006-0234-4	journal	August 2004
Chemical complexity induced local structural distortion in NiCoFeMnCr high-entropy alloy Zhang, Fuxiang; Tong, Yang; Jin, Ke Materials Research Letters, Vol. 6, Issue 8 https://doi.org/10.1080/21663831.2018.1478332	journal	June 2018
Local lattice distortion in NiCoCr, FeCoNiCr and FeCoNiCrMn concentrated alloys investigated by synchrotron X-ray diffraction Tong, Y.; Jin, K.; Bei, H. Materials & Design, Vol. 155 https://doi.org/10.1016/j.matdes.2018.05.056	journal	October 2018
An assessment of the lattice strain in the CrMnFeCoNi high-entropy alloy Owen, Lewis; Pickering, Ej; Playford, Hy Apollo - University of Cambridge Repository https://doi.org/10.17863/cam.6293	text	January 2016
PDFgetX3: A rapid and highly automatable program for processing powder diffraction data into total scattering pair distribution functions Juhas, Pavol; Davis, Timur; Farrow, Christopher L. arXiv https://doi.org/10.48550/arxiv.1211.7126	text	January 2012
High pressure synthesis of a hexagonal close-packed phase of the high-entropy alloy CrMnFeCoNi Tracy, Cameron L.; Park, Sulgiye; Rittman, Dylan R. arXiv https://doi.org/10.48550/arxiv.1611.00876	text	January 2016

Cited By (1)

Critical Review of Chemical Complexity Effect on Local Structure of Multi-principal-Element Alloys Tong, Yang; Zhang, Fuxiang JOM, Vol. 71, Issue 10 https://doi.org/10.1007/s11837-019-03705-3	journal	August 2019

Similar Records

Nb-H system at high pressures and temperatures

Journal Article · Fri Mar 24 00:00:00 EDT 2017 · Physical Review B · OSTI ID:1484109

Liu, Guangtao; Besedin, Stanislav; Irodova, Alla; +5 more

Local lattice distortion mediated formation of stacking faults in Mg alloys

Journal Article · Sun Mar 24 00:00:00 EDT 2019 · Acta Materialia · OSTI ID:1484109

Wang, William Yi; Tang, Bin; Shang, Shun-Li; +14 more

First-principles calculation of lattice distortions in four single phase high entropy alloys with experimental validation

Journal Article · Wed Aug 25 00:00:00 EDT 2021 · Materials & Design · OSTI ID:1484109

San, Saro; Tong, Yang; Bei, Hongbin; +3 more

Related Subjects

36 MATERIALS SCIENCE
solid-solution alloys
lattice distortion
phase transformation

Title: Lattice Distortion and Phase Stability of Pd-Doped NiCoFeCr Solid-Solution Alloys

Citation Formats

References (38)

Cited By (1)

Similar Records

Related Subjects