Amine additive reactions induced by the soft Lewis acidity of Pb 2+ in halide perovskites. Part I: evidence for Pb–alkylamide formation

Kerner, Ross A.; Schloemer, Tracy H.; Schulz, Philip; Berry, Joseph J.; Schwartz, Jeffrey; Sellinger, Alan; Rand, Barry P.

doi:10.1039/C8TC04871A

Title: Amine additive reactions induced by the soft Lewis acidity of Pb ²⁺ in halide perovskites. Part I: evidence for Pb–alkylamide formation

Journal Article · Thu Nov 15 00:00:00 EST 2018 · Journal of Materials Chemistry C

DOI:https://doi.org/10.1039/C8TC04871A· OSTI ID:1524327

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^[2]; Schulz, Philip ^[3];

^[4]; Schwartz, Jeffrey ^[1];

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Princeton Univ., NJ (United States)
Colorado School of Mines, Golden, CO (United States)
National Renewable Energy Lab. (NREL), Golden, CO (United States); Centre National de la Recherche Scientifique (CNRS), Palaiseau (France). Inst. Potovoltaique d'lle de France (IPVF)
National Renewable Energy Lab. (NREL), Golden, CO (United States)
Colorado School of Mines, Golden, CO (United States); National Renewable Energy Lab. (NREL), Golden, CO (United States)

Simple aliphatic amine additives are shown to react with PbI ₂ in perovskite inks to form amido Pb and alkylammonium species.

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Research Organization:: National Renewable Energy Laboratory (NREL), Golden, CO (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE), Renewable Power Office. Solar Energy Technologies Office

Grant/Contract Number:: AC36-08GO28308

OSTI ID:: 1524327

Alternate ID(s):: OSTI ID: 1484048

Report Number(s):: NREL/JA-5K00-74034; JMCCCX

Journal Information:: Journal of Materials Chemistry C, Vol. 7, Issue 18; ISSN 2050-7526

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 50 works

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Amine additive reactions induced by the soft Lewis acidity of Pb ²⁺ in halide perovskites. Part II: impacts of amido Pb impurities in methylammonium lead triiodide thin films Kerner, Ross A.; Schloemer, Tracy H.; Schulz, Philip Journal of Materials Chemistry C, Vol. 7, Issue 18 https://doi.org/10.1039/c8tc04872j	journal	January 2019
Acetonitrile based single step slot-die compatible perovskite ink for flexible photovoltaics Burkitt, Daniel; Swartwout, Richard; McGettrick, James RSC Advances, Vol. 9, Issue 64 https://doi.org/10.1039/c9ra06631d	journal	January 2019
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36 MATERIALS SCIENCE
71 CLASSICAL AND QUANTUM MECHANICS
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amines
crystal impurities
inclusions
layered semiconductors
metal halides
molecules
morphology
optoelectronic devices
passivation
perovskites

Title: Amine additive reactions induced by the soft Lewis acidity of Pb 2+ in halide perovskites. Part I: evidence for Pb–alkylamide formation

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Title: Amine additive reactions induced by the soft Lewis acidity of Pb ²⁺ in halide perovskites. Part I: evidence for Pb–alkylamide formation