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Title: Investigation of Nano-Mechanical and- Tribological Properties of Hydrogenated Diamond Like Carbon (DLC) Coatings

Journal Article · · Journal of Mechanics

Abstract Hydrogenated diamond like Carbon (H-DLC) is a promising lubricious coating that attracted a great deal of interest in recent years mainly because of its outstanding tribological properties. In this study, the nano-mechanical and -tribological properties of a range of H-DLC films were investigated. Specifically, four kinds of H-DLC coatings were produced on Si substrates in pure acetylene, pure methane, 25% methane + 75% hydrogen, 50% methane + 50% hydrogen discharge plasmas using a plasma enhanced chemical vapour deposition (PECVD) system. Nano indentation was performed to measure the mechanical properties such as hardness and young's modulus and nanoscartching was performed to investigate the frictional behavior and wear mechanism of the H-DLC samples in open air. Moreover, Vickers indentation method was utilized to assess the fracture toughness of the samples. The results revealed that there is a strong correlation between the mechanical properties (hardness, young's modulus, fracture toughness) and the friction coefficient of DLC coatings and the source gas chemistry. Lower hydrogen to carbon ratio in source gas leads to higher hardness, young's modulus, fracture toughness and lower friction coefficient. Furthermore, lower wear volume of the coated materials was observed when the friction coefficient was lower. It was also confirmed that lower hydrogen content of the DLC coating leads to higher wear resistance under nanoscratch conditions.

Research Organization:
Argonne National Laboratory (ANL), Argonne, IL (United States)
Sponsoring Organization:
USDOE Office of Energy Efficiency and Renewable Energy (EERE) - Office of Vehicle Technology
DOE Contract Number:
AC02-06CH11357
OSTI ID:
1484028
Journal Information:
Journal of Mechanics, Vol. 33, Issue 06; ISSN 1727-7191
Country of Publication:
United States
Language:
English

References (27)

Tribological characteristics of DLC films and duplex plasma nitriding/DLC coating treatments journal July 1995
Palmqvist indentation toughness in WC-Co composites journal August 1987
Amorphous carbon journal January 1986
Effect of source gas chemistry on tribological performance of diamond-like carbon films journal April 2000
TOF-SIMS and XPS characterization of diamond-like carbon films after tests in inert and oxidizing environments journal June 2008
Fracture mechanisms of thin amorphous carbon films in nanoindentation journal November 1997
Sliding wear characteristics of the diamond-like carbon films on alloy substrates journal September 2007
Synthesis and Tribology of Micro-Carbon Sphere Additives for Enhanced Lubrication journal February 2015
Diamond and Amorphous Carbon MEMS journal April 2001
Investigation of deformation behaviour and abrasive wear mechanism in nanomachining journal January 2011
Friction and wear properties of smooth diamond films grown in fullerene + argon plasmas journal July 1996
The mechanics of single crystal Cu machining at nanoscale journal January 2011
Characterization of diamond films by Raman spectroscopy journal April 1989
Insights into “near-frictionless carbon films” journal June 2004
Diamond-like carbon: state of the art journal March 1999
Mechanism of Abrasive Wear in Nanomachining journal March 2011
Measurement of fracture toughness of ultra-thin amorphous carbon films journal March 1998
The respective role of oxygen and water vapor on the tribology of hydrogenated diamond-like carbon coatings journal January 1998
Mechanical and tribological properties of hard carbon coatings for magnetic recording heads journal November 1995
Environmental effects on the friction of hydrogenated DLC films journal January 2006
Lubrication of DLC Coatings with Two Tris(pentafluoroethyl)trifluorophosphate Anion-Based Ionic Liquids journal July 2013
Synthesis of diamondlike carbon films with superlow friction and wear properties
  • Erdemir, A.; Eryilmaz, O. L.; Fenske, G.
  • Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films, Vol. 18, Issue 4 https://doi.org/10.1116/1.582459
journal July 2000
Characterization of diamondlike carbon films and their application as overcoats on thin‐film media for magnetic recording journal November 1987
Chemical, mechanical and tribological characterization of ultra-thin and hard amorphous carbon coatings as thin as 3.5 nm: recent developments journal November 1999
Characterization of chemical bonding and physical characteristics of diamond-like amorphous carbon and diamond films journal February 1992
Effect of feed gas composition effects on the nanotribological properties of diamond-like carbon films journal February 2013
Mechanical Properties of Carbon Films for Thin Film Disks journal January 1990

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