Phosphorus: An Anode of Choice for Sodium-Ion Batteries
Abstract
Phosphorus (P) offers a high theoretical capacity of 2596 mAh g-1 and thus has been intensively pursued as one of the most promising anodes for sodium-ion batteries. However, sodium storage in P anodes is facing significant technical challenges in terms of poor conductivity, large volume swelling, and an unstable solid-electrolyte interphase. These challenges need to be well mitigated before P material can be deployed in full batteries. In this Perspective, we summarize the latest research progress in the development of P anodes. Here, we focus on the design principle and criteria of efficient P anodes and materials strategies that mainly leverage the knowledge accumulated for the lithium anode of silicon. We also highlight the decisive role that theoretical simulation and in situ techniques play in addressing these difficulties associated with P materials.
- Authors:
-
- Soochow Univ., Suzhou (People’s Republic of China). College of Physics, Optoelectronics and Energy, Center for Energy Conversion Materials & Physics (CECMP)
- Argonne National Lab. (ANL), Argonne, IL (United States). Chemical Sciences and Engineering Division
- Publication Date:
- Research Org.:
- Argonne National Lab. (ANL), Argonne, IL (United States)
- Sponsoring Org.:
- USDOE Office of Energy Efficiency and Renewable Energy (EERE), Vehicle Technologies Office (EE-3V); National Natural Science Foundation of China (NSFC)
- OSTI Identifier:
- 1484017
- Grant/Contract Number:
- AC02-06CH11357; 17KJA430013; BK20151219; BK20140009; 51672182; 51772197; 51422206
- Resource Type:
- Journal Article: Accepted Manuscript
- Journal Name:
- ACS Energy Letters
- Additional Journal Information:
- Journal Volume: 3; Journal Issue: 5; Journal ID: ISSN 2380-8195
- Publisher:
- American Chemical Society (ACS)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 25 ENERGY STORAGE
Citation Formats
Ni, Jiangfeng, Li, Liang, and Lu, Jun. Phosphorus: An Anode of Choice for Sodium-Ion Batteries. United States: N. p., 2018.
Web. doi:10.1021/acsenergylett.8b00312.
Ni, Jiangfeng, Li, Liang, & Lu, Jun. Phosphorus: An Anode of Choice for Sodium-Ion Batteries. United States. https://doi.org/10.1021/acsenergylett.8b00312
Ni, Jiangfeng, Li, Liang, and Lu, Jun. 2018.
"Phosphorus: An Anode of Choice for Sodium-Ion Batteries". United States. https://doi.org/10.1021/acsenergylett.8b00312. https://www.osti.gov/servlets/purl/1484017.
@article{osti_1484017,
title = {Phosphorus: An Anode of Choice for Sodium-Ion Batteries},
author = {Ni, Jiangfeng and Li, Liang and Lu, Jun},
abstractNote = {Phosphorus (P) offers a high theoretical capacity of 2596 mAh g-1 and thus has been intensively pursued as one of the most promising anodes for sodium-ion batteries. However, sodium storage in P anodes is facing significant technical challenges in terms of poor conductivity, large volume swelling, and an unstable solid-electrolyte interphase. These challenges need to be well mitigated before P material can be deployed in full batteries. In this Perspective, we summarize the latest research progress in the development of P anodes. Here, we focus on the design principle and criteria of efficient P anodes and materials strategies that mainly leverage the knowledge accumulated for the lithium anode of silicon. We also highlight the decisive role that theoretical simulation and in situ techniques play in addressing these difficulties associated with P materials.},
doi = {10.1021/acsenergylett.8b00312},
url = {https://www.osti.gov/biblio/1484017},
journal = {ACS Energy Letters},
issn = {2380-8195},
number = 5,
volume = 3,
place = {United States},
year = {Fri Apr 06 00:00:00 EDT 2018},
month = {Fri Apr 06 00:00:00 EDT 2018}
}
Web of Science
Works referenced in this record:
Electrode Materials for Rechargeable Sodium-Ion Batteries: Potential Alternatives to Current Lithium-Ion Batteries
journal, May 2012
- Kim, Sung-Wook; Seo, Dong-Hwa; Ma, Xiaohua
- Advanced Energy Materials, Vol. 2, Issue 7, p. 710-721
Sodium-Ion Batteries
journal, May 2012
- Slater, Michael D.; Kim, Donghan; Lee, Eungje
- Advanced Functional Materials, Vol. 23, Issue 8, p. 947-958
Research Development on Sodium-Ion Batteries
journal, October 2014
- Yabuuchi, Naoaki; Kubota, Kei; Dahbi, Mouad
- Chemical Reviews, Vol. 114, Issue 23
Sodium-ion batteries: present and future
journal, January 2017
- Hwang, Jang-Yeon; Myung, Seung-Taek; Sun, Yang-Kook
- Chemical Society Reviews, Vol. 46, Issue 12
Electrochemical Na Insertion and Solid Electrolyte Interphase for Hard-Carbon Electrodes and Application to Na-Ion Batteries
journal, August 2011
- Komaba, Shinichi; Murata, Wataru; Ishikawa, Toru
- Advanced Functional Materials, Vol. 21, Issue 20
Carbon Anode Materials for Advanced Sodium-Ion Batteries
journal, March 2017
- Hou, Hongshuai; Qiu, Xiaoqing; Wei, Weifeng
- Advanced Energy Materials, Vol. 7, Issue 24
Li-alloy based anode materials for Li secondary batteries
journal, January 2010
- Park, Cheol-Min; Kim, Jae-Hun; Kim, Hansu
- Chemical Society Reviews, Vol. 39, Issue 8, p. 3115-3141
Ab Initio Study of Phosphorus Anodes for Lithium- and Sodium-Ion Batteries
journal, March 2016
- Mayo, Martin; Griffith, Kent J.; Pickard, Chris J.
- Chemistry of Materials, Vol. 28, Issue 7
The Atomic Distribution in Red and Black Phosphorus and the Crystal Structure of Black Phosphorus
journal, June 1935
- Hultgren, Ralph; Gingrich, N. S.; Warren, B. E.
- The Journal of Chemical Physics, Vol. 3, Issue 6
Formation of Stable Phosphorus–Carbon Bond for Enhanced Performance in Black Phosphorus Nanoparticle–Graphite Composite Battery Anodes
journal, July 2014
- Sun, Jie; Zheng, Guangyuan; Lee, Hyun-Wook
- Nano Letters, Vol. 14, Issue 8
Black Phosphorus and its Composite for Lithium Rechargeable Batteries
journal, September 2007
- Park, C. -M.; Sohn, H. -J.
- Advanced Materials, Vol. 19, Issue 18
Nano-Structured Phosphorus Composite as High-Capacity Anode Materials for Lithium Batteries
journal, August 2012
- Wang, Li; He, Xiangming; Li, Jianjun
- Angewandte Chemie International Edition, Vol. 51, Issue 36
A comparative first-principles study of the lithiation, sodiation, and magnesiation of black phosphorus for Li-, Na-, and Mg-ion batteries
journal, January 2016
- Hembram, K. P. S. S.; Jung, Hyun; Yeo, Byung Chul
- Physical Chemistry Chemical Physics, Vol. 18, Issue 31
High Capacity and Rate Capability of Amorphous Phosphorus for Sodium Ion Batteries
journal, March 2013
- Qian, Jiangfeng; Wu, Xianyong; Cao, Yuliang
- Angewandte Chemie International Edition, Vol. 52, Issue 17
An Amorphous Red Phosphorus/Carbon Composite as a Promising Anode Material for Sodium Ion Batteries
journal, March 2013
- Kim, Youngjin; Park, Yuwon; Choi, Aram
- Advanced Materials, Vol. 25, Issue 22
Designing nanostructured Si anodes for high energy lithium ion batteries
journal, October 2012
- Wu, Hui; Cui, Yi
- Nano Today, Vol. 7, Issue 5
Phosphorus-Based Materials as the Anode for Sodium-Ion Batteries
journal, October 2017
- Yang, Fuhua; Gao, Hong; Chen, Jun
- Small Methods, Vol. 1, Issue 11
Negative electrodes for Na-ion batteries
journal, January 2014
- Dahbi, Mouad; Yabuuchi, Naoaki; Kubota, Kei
- Physical Chemistry Chemical Physics, Vol. 16, Issue 29
High-Capacity Anode Materials for Sodium-Ion Batteries
journal, August 2014
- Kim, Youngjin; Ha, Kwang-Ho; Oh, Seung M.
- Chemistry - A European Journal, Vol. 20, Issue 38
Na-Ion Battery Anodes: Materials and Electrochemistry
journal, January 2016
- Luo, Wei; Shen, Fei; Bommier, Clement
- Accounts of Chemical Research, Vol. 49, Issue 2
Current progress in black phosphorus materials and their applications in electrochemical energy storage
journal, January 2017
- Qiu, M.; Sun, Z. T.; Sang, D. K.
- Nanoscale, Vol. 9, Issue 36
Carbon-coated silicon nanowire array films for high-performance lithium-ion battery anodes
journal, September 2009
- Huang, Rui; Fan, Xing; Shen, Wanci
- Applied Physics Letters, Vol. 95, Issue 13, Article No. 133119
Phosphorus–carbon nanocomposite anodes for lithium-ion and sodium-ion batteries
journal, January 2015
- Ramireddy, Thrinathreddy; Xing, Tan; Rahman, Md Mokhlesur
- Journal of Materials Chemistry A, Vol. 3, Issue 10
Inexpensive Antimony Nanocrystals and Their Composites with Red Phosphorus as High-Performance Anode Materials for Na-ion Batteries
journal, February 2015
- Walter, Marc; Erni, Rolf; Kovalenko, Maksym V.
- Scientific Reports, Vol. 5, Issue 1
High-Performance Red P-Based P–TiP 2 –C Nanocomposite Anode for Lithium-Ion and Sodium-Ion Storage
journal, August 2016
- Kim, Sang-Ok; Manthiram, Arumugam
- Chemistry of Materials, Vol. 28, Issue 16
Activated-phosphorus as new electrode material for Li-ion batteries
journal, April 2011
- Marino, C.; Debenedetti, A.; Fraisse, B.
- Electrochemistry Communications, Vol. 13, Issue 4
Improving the electrochemical properties of the red P anode in Na-ion batteries via the space confinement of carbon nanopores
journal, January 2015
- Wu, Na; Yao, Hu-Rong; Yin, Ya-Xia
- Journal of Materials Chemistry A, Vol. 3, Issue 48
Performance of carbon-fiber-containing LiFePO4 cathodes for high-power applications
journal, November 2006
- Thorat, Indrajeet V.; Mathur, Vipul; Harb, John N.
- Journal of Power Sources, Vol. 162, Issue 1
A review on integrating nano-carbons into polyanion phosphates and silicates for rechargeable lithium batteries
journal, October 2015
- Ni, Jiangfeng; Zhang, Ling; Fu, Shidong
- Carbon, Vol. 92
Carbon Nanomaterials in Different Dimensions for Electrochemical Energy Storage
journal, March 2016
- Ni, Jiangfeng; Li, Yan
- Advanced Energy Materials, Vol. 6, Issue 17
Role of carbon defects in the reversible alloying states of red phosphorus composite anodes for efficient sodium ion batteries
journal, January 2017
- Li, Mengya; Carter, Rachel; Oakes, Landon
- Journal of Materials Chemistry A, Vol. 5, Issue 11
Superior sodium storage in phosphorus@porous multichannel flexible freestanding carbon nanofibers
journal, October 2017
- Sun, Xizhen; Li, Weihan; Zhong, Xiongwu
- Energy Storage Materials, Vol. 9
Red phosphorus nanoparticles embedded in porous N-doped carbon nanofibers as high-performance anode for sodium-ion batteries
journal, October 2017
- Liu, Yongchang; Zhang, Ning; Liu, Xiaobin
- Energy Storage Materials, Vol. 9
Simply Mixed Commercial Red Phosphorus and Carbon Nanotube Composite with Exceptionally Reversible Sodium-Ion Storage
journal, October 2013
- Li, Wei-Jie; Chou, Shu-Lei; Wang, Jia-Zhao
- Nano Letters, Vol. 13, Issue 11
Red Phosphorus–Single-Walled Carbon Nanotube Composite as a Superior Anode for Sodium Ion Batteries
journal, February 2015
- Zhu, Yujie; Wen, Yang; Fan, Xiulin
- ACS Nano, Vol. 9, Issue 3
Strongly coupled inorganic–nano-carbon hybrid materials for energy storage
journal, January 2013
- Wang, Hailiang; Dai, Hongjie
- Chemical Society Reviews, Vol. 42, Issue 7
Advanced Sodium Ion Battery Anode Constructed via Chemical Bonding between Phosphorus, Carbon Nanotube, and Cross-Linked Polymer Binder
journal, October 2015
- Song, Jiangxuan; Yu, Zhaoxin; Gordin, Mikhail L.
- ACS Nano, Vol. 9, Issue 12
Chemically Bonded Phosphorus/Graphene Hybrid as a High Performance Anode for Sodium-Ion Batteries
journal, October 2014
- Song, Jiangxuan; Yu, Zhaoxin; Gordin, Mikhail L.
- Nano Letters, Vol. 14, Issue 11
Phosphorus nanoparticles combined with cubic boron nitride and graphene as stable sodium-ion battery anodes
journal, May 2017
- Ding, Xuli; Huang, Yangyang; Li, Guolong
- Electrochimica Acta, Vol. 235
Carbon−Silicon Core−Shell Nanowires as High Capacity Electrode for Lithium Ion Batteries
journal, September 2009
- Cui, Li-Feng; Yang, Yuan; Hsu, Ching-Mei
- Nano Letters, Vol. 9, Issue 9, p. 3370-3374
Amorphous Red Phosphorus Embedded in Highly Ordered Mesoporous Carbon with Superior Lithium and Sodium Storage Capacity
journal, February 2016
- Li, Weihan; Yang, Zhenzhong; Li, Minsi
- Nano Letters, Vol. 16, Issue 3
Wet-Chemical Synthesis of Hollow Red-Phosphorus Nanospheres with Porous Shells as Anodes for High-Performance Lithium-Ion and Sodium-Ion Batteries
journal, May 2017
- Zhou, Jianbin; Liu, Xianyu; Cai, Wenlong
- Advanced Materials, Vol. 29, Issue 29
Amorphous Phosphorus/Nitrogen-Doped Graphene Paper for Ultrastable Sodium-Ion Batteries
journal, February 2016
- Zhang, Chao; Wang, Xi; Liang, Qifeng
- Nano Letters, Vol. 16, Issue 3
Phosphorus Nanoparticles Encapsulated in Graphene Scrolls as a High-Performance Anode for Sodium-Ion Batteries
journal, July 2015
- Pei, Longkai; Zhao, Qing; Chen, Chengcheng
- ChemElectroChem, Vol. 2, Issue 11
Integrated Carbon/Red Phosphorus/Graphene Aerogel 3D Architecture via Advanced Vapor-Redistribution for High-Energy Sodium-Ion Batteries
journal, August 2016
- Gao, Hong; Zhou, Tengfei; Zheng, Yang
- Advanced Energy Materials, Vol. 6, Issue 21
Bio-inspired engineering of Bi2S3-PPy yolk-shell composite for highly durable lithium and sodium storage
journal, March 2017
- Liang, Haichen; Ni, Jiangfeng; Li, Liang
- Nano Energy, Vol. 33
Regulation of Breathing CuO Nanoarray Electrodes for Enhanced Electrochemical Sodium Storage
journal, February 2018
- Ni, Jiangfeng; Jiang, Yu; Wu, Feixiang
- Advanced Functional Materials, Vol. 28, Issue 15
Confined Amorphous Red Phosphorus in MOF-Derived N-Doped Microporous Carbon as a Superior Anode for Sodium-Ion Battery
journal, February 2017
- Li, Weihan; Hu, Shuhe; Luo, Xiangyu
- Advanced Materials, Vol. 29, Issue 16
Nanostructured Black Phosphorus/Ketjenblack–Multiwalled Carbon Nanotubes Composite as High Performance Anode Material for Sodium-Ion Batteries
journal, May 2016
- Xu, Gui-Liang; Chen, Zonghai; Zhong, Gui-Ming
- Nano Letters, Vol. 16, Issue 6
Bridging Covalently Functionalized Black Phosphorus on Graphene for High-Performance Sodium-Ion Battery
journal, October 2017
- Liu, Hanwen; Tao, Li; Zhang, Yiqiong
- ACS Applied Materials & Interfaces, Vol. 9, Issue 42
Functionalized few-layer black phosphorus with super-wettability towards enhanced reaction kinetics for rechargeable batteries
journal, October 2017
- Zhang, Yu; Sun, Wenping; Luo, Zhong-Zhen
- Nano Energy, Vol. 40
Phosphorene as an anode material for Na-ion batteries: a first-principles study
journal, January 2015
- Kulish, Vadym V.; Malyi, Oleksandr I.; Persson, Clas
- Physical Chemistry Chemical Physics, Vol. 17, Issue 21
Capping Black Phosphorene by h-BN Enhances Performances in Anodes for Li and Na Ion Batteries
journal, June 2016
- Chowdhury, Chandra; Karmakar, Sharmistha; Datta, Ayan
- ACS Energy Letters, Vol. 1, Issue 1
Layer-Tunable Phosphorene Modulated by the Cation Insertion Rate as a Sodium-Storage Anode
journal, July 2017
- Huang, Zhaodong; Hou, Hongshuai; Zhang, Yan
- Advanced Materials, Vol. 29, Issue 34
A phosphorene–graphene hybrid material as a high-capacity anode for sodium-ion batteries
journal, September 2015
- Sun, Jie; Lee, Hyun-Wook; Pasta, Mauro
- Nature Nanotechnology, Vol. 10, Issue 11
Stable cycling of double-walled silicon nanotube battery anodes through solid–electrolyte interphase control
journal, March 2012
- Wu, Hui; Chan, Gerentt; Choi, Jang Wook
- Nature Nanotechnology, Vol. 7, Issue 5
Challenges and Recent Progress in the Development of Si Anodes for Lithium-Ion Battery
journal, September 2017
- Jin, Yan; Zhu, Bin; Lu, Zhenda
- Advanced Energy Materials, Vol. 7, Issue 23
Phosphorus Electrodes in Sodium Cells: Small Volume Expansion by Sodiation and the Surface-Stabilization Mechanism in Aprotic Solvent
journal, January 2014
- Yabuuchi, Naoaki; Matsuura, Yuta; Ishikawa, Toru
- ChemElectroChem, Vol. 1, Issue 3
Black Phosphorus as a High-Capacity, High-Capability Negative Electrode for Sodium-Ion Batteries: Investigation of the Electrode/Electrolyte Interface
journal, February 2016
- Dahbi, Mouad; Yabuuchi, Naoaki; Fukunishi, Mika
- Chemistry of Materials, Vol. 28, Issue 6
A Major Constituent of Brown Algae for Use in High-Capacity Li-Ion Batteries
journal, September 2011
- Kovalenko, I.; Zdyrko, B.; Magasinski, A.
- Science, Vol. 334, Issue 6052
The role of nanotechnology in the development of battery materials for electric vehicles
journal, December 2016
- Lu, Jun; Chen, Zonghai; Ma, Zifeng
- Nature Nanotechnology, Vol. 11, Issue 12
Self-Supported 3D Array Electrodes for Sodium Microbatteries
journal, November 2017
- Ni, Jiangfeng; Li, Liang
- Advanced Functional Materials, Vol. 28, Issue 3
Highly Reversible and Durable Na Storage in Niobium Pentoxide through Optimizing Structure, Composition, and Nanoarchitecture
journal, December 2016
- Ni, Jiangfeng; Wang, Wencong; Wu, Chao
- Advanced Materials, Vol. 29, Issue 9
Boosting Sodium Storage in TiO 2 Nanotube Arrays through Surface Phosphorylation
journal, January 2018
- Ni, Jiangfeng; Fu, Shidong; Yuan, Yifei
- Advanced Materials, Vol. 30, Issue 6
State-of-the-art characterization techniques for advanced lithium-ion batteries
journal, March 2017
- Lu, Jun; Wu, Tianpin; Amine, Khalil
- Nature Energy, Vol. 2, Issue 3
Unraveling the Atomistic Sodiation Mechanism of Black Phosphorus for Sodium Ion Batteries by First-Principles Calculations
journal, June 2015
- Hembram, K. P. S. S.; Jung, Hyun; Yeo, Byung Chul
- The Journal of Physical Chemistry C, Vol. 119, Issue 27
First-principles study of fast Na diffusion in Na 3 P
journal, September 2014
- Yu, Xue-fang; Giorgi, Giacomo; Ushiyama, Hiroshi
- Chemical Physics Letters, Vol. 612
Works referencing / citing this record:
Red Phosphorus/Onion‐like Mesoporous Carbon Composite as High‐Performance Anode for Sodium‐Ion Battery
journal, October 2019
- Liang, Xiaoqiang; Chang, Caiyun; Guo, Wenbin
- ChemElectroChem, Vol. 6, Issue 22
A black phosphorus-based cathode for aqueous Na-ion batteries operating under ambient conditions
journal, January 2020
- Fonsaca, Jéssica E. S.; Domingues, Sergio H.; Orth, Elisa S.
- Chemical Communications, Vol. 56, Issue 5
A new family of cation-disordered Zn(Cu)–Si–P compounds as high-performance anodes for next-generation Li-ion batteries
journal, January 2019
- Li, Wenwu; Li, Xinwei; Liao, Jun
- Energy & Environmental Science, Vol. 12, Issue 7
Materials Based on Antimony and Bismuth for Sodium Storage
journal, July 2018
- Li, Xinyan; Ni, Jiangfeng; Savilov, S. V.
- Chemistry - A European Journal, Vol. 24, Issue 52
Scalable and controlled synthesis of 2D nanoporous Co 3 O 4 from bulk alloy for potassium ion batteries
journal, January 2020
- Jiang, Huiyu; An, Yongling; Tian, Yuan
- Materials Technology, Vol. 35, Issue 9-10
Polymer Binders Constructed through Dynamic Noncovalent Bonds for High‐Capacity Silicon‐Based Anodes
journal, September 2009
- Pan, Yiyang; Gao, Shilun; Sun, Feiyuan
- Chemistry – A European Journal, Vol. 25, Issue 47
Hierarchical Porous Activated Carbon Obtained by a Novel Heating‐Rate‐Induced Method for Lithium‐Ion Capacitor
journal, May 2019
- Sun, Jing; Yang, Shuhua; Ai, Jingui
- ChemistrySelect, Vol. 4, Issue 18
Materials based on group IVA elements for alloying-type sodium storage
journal, November 2018
- Zhu, Xiaocui; Sun, Menglei; Ni, Jiangfeng
- Science China Chemistry, Vol. 61, Issue 12
Organic Carbonyl Compounds for Sodium‐Ion Batteries: Recent Progress and Future Perspectives
journal, June 2018
- Wang, Heng‐guo; Zhang, Xin‐bo
- Chemistry – A European Journal, Vol. 24, Issue 69
Highly Elastic Binders Incorporated with Helical Molecules to Improve the Electrochemical Stability of Black Phosphorous Anodes for Sodium‐Ion Batteries
journal, November 2019
- Zhang, Hongwei; Lv, Zhisheng; Liang, Qinghua
- Batteries & Supercaps, Vol. 3, Issue 1
Computational Screening of Anode Materials for Sodium-Ion Batteries
journal, January 2019
- Yu, Seungho; Kim, Sang-Ok; Kim, Hyung-Seok
- Journal of The Electrochemical Society, Vol. 166, Issue 10
Toward dendrite-free alkaline zinc-based rechargeable batteries: A minireview
journal, September 2019
- Cao, Xin; Xia, Huan; Zhao, Xiangyu
- Functional Materials Letters, Vol. 12, Issue 05
Dual‐Doped Hematite Nanorod Arrays on Carbon Cloth as a Robust and Flexible Sodium Anode
journal, January 2020
- Sun, Menglei; Wang, Zhenzhu; Ni, Jiangfeng
- Advanced Functional Materials, Vol. 30, Issue 11
Pulverization‐Tolerance and Capacity Recovery of Copper Sulfide for High‐Performance Sodium Storage
journal, April 2019
- Park, Jae Yeol; Kim, Sung Joo; Yim, Kanghoon
- Advanced Science, Vol. 6, Issue 12
Recent development and prospect of potassium-ion batteries with high energy and high safety for post-lithium batteries
journal, August 2019
- An, Yongling; Liu, Yining; Tian, Yuan
- Functional Materials Letters, Vol. 12, Issue 04
Band alignment in multilayered semiconductor homojunctions supported on metals
journal, January 2020
- Wang, Qian; Dou, Kunpeng; Shi, Xingqiang
- Journal of Materials Chemistry C, Vol. 8, Issue 3