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Title: Synthesis and electrochemical properties of Li1.3Nb0.3Cr0.4O2 as a high-capacity cathode material for rechargeable lithium batteries

Abstract

A cation-disordered Li-excess material (Li 1.3 Cr 0.4 Nb 0.3 O 2 ) delivers a high reversible capacity, originating from a Cr 3+ /Cr 6+ three-electron redox reaction.

Authors:
 [1];  [1];  [1];  [1];  [1]; ORCiD logo [1];  [2]; ORCiD logo [2]; ORCiD logo [1]
  1. Fudan Univ., Shanghai (People's Republic of China)
  2. Brookhaven National Lab. (BNL), Upton, NY (United States)
Publication Date:
Research Org.:
Brookhaven National Laboratory (BNL), Upton, NY (United States)
Sponsoring Org.:
USDOE Office of Energy Efficiency and Renewable Energy (EERE), Vehicle Technologies Office (EE-3V); USDOE
OSTI Identifier:
1483754
Alternate Identifier(s):
OSTI ID: 1482851
Report Number(s):
BNL-209508-2018-JAAM
Journal ID: ISSN 1359-7345
Grant/Contract Number:  
SC0012704
Resource Type:
Journal Article: Accepted Manuscript
Journal Name:
ChemComm
Additional Journal Information:
Journal Volume: 54; Journal Issue: 98; Journal ID: ISSN 1359-7345
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English
Subject:
25 ENERGY STORAGE; Li-rich cathode; Li batteries

Citation Formats

Wang, Weiwen, Meng, Jingke, Yue, Xinyang, Wang, Qinchao, Wang, Xinxin, Zhou, Yongning, Yang, Xiaoqing, Shadike, Zulipiya, and Fu, Zhengwen. Synthesis and electrochemical properties of Li1.3Nb0.3Cr0.4O2 as a high-capacity cathode material for rechargeable lithium batteries. United States: N. p., 2018. Web. doi:10.1039/C8CC07660J.
Wang, Weiwen, Meng, Jingke, Yue, Xinyang, Wang, Qinchao, Wang, Xinxin, Zhou, Yongning, Yang, Xiaoqing, Shadike, Zulipiya, & Fu, Zhengwen. Synthesis and electrochemical properties of Li1.3Nb0.3Cr0.4O2 as a high-capacity cathode material for rechargeable lithium batteries. United States. https://doi.org/10.1039/C8CC07660J
Wang, Weiwen, Meng, Jingke, Yue, Xinyang, Wang, Qinchao, Wang, Xinxin, Zhou, Yongning, Yang, Xiaoqing, Shadike, Zulipiya, and Fu, Zhengwen. 2018. "Synthesis and electrochemical properties of Li1.3Nb0.3Cr0.4O2 as a high-capacity cathode material for rechargeable lithium batteries". United States. https://doi.org/10.1039/C8CC07660J. https://www.osti.gov/servlets/purl/1483754.
@article{osti_1483754,
title = {Synthesis and electrochemical properties of Li1.3Nb0.3Cr0.4O2 as a high-capacity cathode material for rechargeable lithium batteries},
author = {Wang, Weiwen and Meng, Jingke and Yue, Xinyang and Wang, Qinchao and Wang, Xinxin and Zhou, Yongning and Yang, Xiaoqing and Shadike, Zulipiya and Fu, Zhengwen},
abstractNote = {A cation-disordered Li-excess material (Li 1.3 Cr 0.4 Nb 0.3 O 2 ) delivers a high reversible capacity, originating from a Cr 3+ /Cr 6+ three-electron redox reaction.},
doi = {10.1039/C8CC07660J},
url = {https://www.osti.gov/biblio/1483754}, journal = {ChemComm},
issn = {1359-7345},
number = 98,
volume = 54,
place = {United States},
year = {Thu Nov 08 00:00:00 EST 2018},
month = {Thu Nov 08 00:00:00 EST 2018}
}

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Free Publicly Available Full Text
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Cited by: 8 works
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Works referenced in this record:

Reversible anionic redox chemistry in high-capacity layered-oxide electrodes
journal, July 2013


In Situ X-Ray Absorption Study of a Layered Manganese-Chromium Oxide-Based Cathode Material
journal, January 2002


High-Capacity Cathode Material with High Voltage for Li-Ion Batteries
journal, January 2018


Structural Changes in Li 2 MnO 3 Cathode Material for Li-Ion Batteries
journal, December 2013


Nanoionics: ion transport and electrochemical storage in confined systems
journal, November 2005


Recent advances in the electrolytes for interfacial stability of high-voltage cathodes in lithium-ion batteries
journal, January 2015


Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides
journal, September 1976


Reversible Three-Electron Redox Reaction of Mo 3+ /Mo 6+ for Rechargeable Lithium Batteries
journal, March 2017


Lithium-free transition metal monoxides for positive electrodes in lithium-ion batteries
journal, January 2017


Structure of the incommensurate composite crystal [Sr 2 Cu 2 O 3 ][CuO 2 ] x ( x = 1.436)
journal, February 1994


Performance and design considerations for lithium excess layered oxide positive electrode materials for lithium ion batteries
journal, January 2016


Electrodes with High Power and High Capacity for Rechargeable Lithium Batteries
journal, February 2006


The origin of electrochemical activity in Li2MnO3
journal, October 2002


The Effect of Cation Disorder on the Average Li Intercalation Voltage of Transition-Metal Oxides
journal, May 2016


Origin of stabilization and destabilization in solid-state redox reaction of oxide ions for lithium-ion batteries
journal, December 2016


Promise and reality of post-lithium-ion batteries with high energy densities
journal, March 2016


High-capacity electrode materials for rechargeable lithium batteries: Li 3 NbO 4 -based system with cation-disordered rocksalt structure
journal, June 2015


Atomic Structure of Li 2 MnO 3 after Partial Delithiation and Re-Lithiation
journal, June 2013


Electrochemical intercalation activity of layered NaCrO2 vs. LiCrO2
journal, March 2010


Approaching the limits of cationic and anionic electrochemical activity with the Li-rich layered rocksalt Li3IrO4
journal, December 2017


In Situ and Ex Situ XRD Investigation of Li[Cr[sub x]Li[sub 1/3−x/3]Mn[sub 2/3−2x/3]]O[sub 2] (x=1/3) Cathode Material
journal, January 2003


The Origin of Electrochemical Activity in Li2MnO3.
journal, March 2003


Electrodes with High Power and High Capacity for Rechargeable Lithium Batteries.
journal, May 2006