Pulsed Laser Deposition and Characterization of Heteroepitaxial LiMn2O4/La0.5Sr0.5CoO3 Bilayer Thin Films as Model Lithium Ion Battery Cathodes

Yu, Xiankai; Chen, Xiao; Buchholz, D. Bruce; Li, Qianqian; Wu, Jinsong; Fenter, Paul A.; Bedzyk, Michael J.; Dravid, Vinayak P.; Barnett, Scott A.

doi:10.1021/acsanm.7b00133

Title: Pulsed Laser Deposition and Characterization of Heteroepitaxial LiMn₂O₄/La_0.5Sr_0.5CoO₃ Bilayer Thin Films as Model Lithium Ion Battery Cathodes

Journal Article · Tue Jan 02 00:00:00 EST 2018 · ACS Applied Nano Materials

DOI:https://doi.org/10.1021/acsanm.7b00133· OSTI ID:1483643

^[1]; Chen, Xiao ^[1]; Buchholz, D. Bruce ^[1]; Li, Qianqian ^[1];

^[1];

^[2];

^[1];

^[1]; Barnett, Scott A. ^[1]

Northwestern Univ., Evanston, IL (United States)
Argonne National Lab. (ANL), Argonne, IL (United States)

Epitaxial LiMn₂O₄ (LMO)/La_0.5Sr_0.5CoO₃ (LSCO) bilayer thin films were grown on single crystalline SrTiO₃ (STO) (111) substrates as model lithium ion battery cathodes. The LSCO layer was used as an electrically conducting buffer layer for electrochemical testing. The LMO and LSCO layers were both epitaxial, with sub-nano flat LMO/LSCO interfaces as seen by X-ray diffraction, synchrotron X-ray scattering, and high-resolution transmission electron microscopy (HRTEM), but with a large LMO surface roughness due to the relatively large lattice mismatch with LSCO. Three-dimensional islands and depressions were formed on the strain-relaxed LMO layer, and misfit dislocations at the LMO/LSCO interface were discerned through HRTEM imaging, suggesting a Stranski–Krastanov (SK) mode thin-film growth. A crystalline structural change from cubic spinel at the LMO surface and interior to tetragonal oxygen-deficient LMO at the LMO/LSCO interface was examined. Furthermore, electrochemical tests along with in situ synchrotron X-ray scattering measurements on the epitaxial LMO/LSCO bilayers showed a significant loss of capacity after the first cycle, which was attributed to an electrical conductivity loss of the LSCO buffer layer due to irreversible lattice oxygen loss.

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Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States); Energy Frontier Research Centers (EFRC) (United States). Center for Electrical Energy Storage (CEES)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1483643

Journal Information:: ACS Applied Nano Materials, Vol. 1, Issue 2; ISSN 2574-0970

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 12 works

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Title: Pulsed Laser Deposition and Characterization of Heteroepitaxial LiMn2O4/La0.5Sr0.5CoO3 Bilayer Thin Films as Model Lithium Ion Battery Cathodes

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