Broadband surface-enhanced coherent anti-Stokes Raman spectroscopy with high spectral resolution

Yan, Zhongbo; Liu, Zirui; Xia, Ming; Efimov, Anatoly; Xie, Ya-Hong

doi:10.1002/jrs.5165

Title: Broadband surface-enhanced coherent anti-Stokes Raman spectroscopy with high spectral resolution

Journal Article · Wed May 31 00:00:00 EDT 2017 · Journal of Raman Spectroscopy

DOI:https://doi.org/10.1002/jrs.5165· OSTI ID:1483528

^[1]; Liu, Zirui ^[2];

^[2]; Efimov, Anatoly ^[3]; Xie, Ya-Hong ^[2]

Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Univ. of California, Los Angeles, CA (United States). Dept. of Materials Science and Engineering
Univ. of California, Los Angeles, CA (United States). Dept. of Materials Science and Engineering
Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

Both the surface-enhanced Raman spectroscopy (SERS) and coherent anti-Stokes Raman spectroscopy (CARS) are widely used methods in the bio-sensing field for improving the intensity of Raman scattering process. By combining the mechanisms of CARS (coherence and nonlinear process) and SERS (plasmon resonance), a multiplicative enhancement can be achieved through surface-enhanced CARS (SECARS). Besides sensitivity, high specificity with wide spectral bandwidth is also preferred for bio-sensing techniques but not well developed in SECARS setups reported in the literature. A broadband SECARS setup with high sensitivity and high spectral resolution is presented. Rhodamine 6G dye molecules and several biomolecules are used as the model system to benchmark the functionality of the SECARS system in terms of its sensitivity, the lowest detectable concentration, and the spectral resolution. Our setup rendered single-molecule sensitivity with spectral resolution of <35 cm^-1. More than 10² times stronger signal-to-noise ratio compared with that of SERS is observed with the detection limit being 10^-9 m. Different from the SECARS systems in the literature, our setup employs a unique graphene-Au pyramids hybrid platform. The graphene in this structure provides additional SERS enhancement and a bio-compatible surface. Finally, this powerful technique could be instrumental in furthering the understanding of various chemical and biological processes.

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Research Organization:: Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Univ. of California, Los Angeles, CA (United States)

Sponsoring Organization:: USDOE

Grant/Contract Number:: AC52-06NA25396

OSTI ID:: 1483528

Report Number(s):: LA-UR-18-23396

Journal Information:: Journal of Raman Spectroscopy, Vol. 48, Issue 7; ISSN 0377-0486

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 8 works

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Title: Broadband surface-enhanced coherent anti-Stokes Raman spectroscopy with high spectral resolution

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