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Title: The capricious nature of iodine catenation in I 2 excess, perovskite-derived hybrid Pt( iv ) compounds

Abstract

Perovskite-derived hybrid platinum iodides with the general formula A 2 Pt IV I 6 (A = formamidinium FA and guanidinium GUA) accommodate excess I 2 to yield hydrogen-bond-stabilized compounds where the I 2 forms catenates with I anions on the PtI 6 octahedra.

Authors:
ORCiD logo [1];  [2]; ORCiD logo [3];  [1];  [2]; ORCiD logo [4];  [5]; ORCiD logo [1]
  1. Department of Chemistry and Biochemistry, University of California Santa Barbara, USA, Materials Research Laboratory, University of California Santa Barbara
  2. Department of Chemistry and Biochemistry, University of California Santa Barbara, USA
  3. Materials Research Laboratory, University of California Santa Barbara, USA, Materials Department, University of California Santa Barbara
  4. Materials Research Laboratory, University of California Santa Barbara, USA, Department of Materials Science and Engineering, National University of Singapore
  5. Materials Department, University of California Santa Barbara, USA
Publication Date:
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1483443
Grant/Contract Number:  
DE SC 0012541
Resource Type:
Journal Article: Publisher's Accepted Manuscript
Journal Name:
Chemical Communications
Additional Journal Information:
Journal Name: Chemical Communications Journal Volume: 55 Journal Issue: 5; Journal ID: ISSN 1359-7345
Publisher:
Royal Society of Chemistry (RSC)
Country of Publication:
United Kingdom
Language:
English

Citation Formats

Evans, Hayden A., Andrews, Jessica L., Fabini, Douglas H., Preefer, Molleigh B., Wu, Guang, Cheetham, Anthony K., Wudl, Fred, and Seshadri, Ram. The capricious nature of iodine catenation in I 2 excess, perovskite-derived hybrid Pt( iv ) compounds. United Kingdom: N. p., 2019. Web. doi:10.1039/C8CC07536K.
Evans, Hayden A., Andrews, Jessica L., Fabini, Douglas H., Preefer, Molleigh B., Wu, Guang, Cheetham, Anthony K., Wudl, Fred, & Seshadri, Ram. The capricious nature of iodine catenation in I 2 excess, perovskite-derived hybrid Pt( iv ) compounds. United Kingdom. doi:10.1039/C8CC07536K.
Evans, Hayden A., Andrews, Jessica L., Fabini, Douglas H., Preefer, Molleigh B., Wu, Guang, Cheetham, Anthony K., Wudl, Fred, and Seshadri, Ram. Thu . "The capricious nature of iodine catenation in I 2 excess, perovskite-derived hybrid Pt( iv ) compounds". United Kingdom. doi:10.1039/C8CC07536K.
@article{osti_1483443,
title = {The capricious nature of iodine catenation in I 2 excess, perovskite-derived hybrid Pt( iv ) compounds},
author = {Evans, Hayden A. and Andrews, Jessica L. and Fabini, Douglas H. and Preefer, Molleigh B. and Wu, Guang and Cheetham, Anthony K. and Wudl, Fred and Seshadri, Ram},
abstractNote = {Perovskite-derived hybrid platinum iodides with the general formula A 2 Pt IV I 6 (A = formamidinium FA and guanidinium GUA) accommodate excess I 2 to yield hydrogen-bond-stabilized compounds where the I 2 forms catenates with I − anions on the PtI 6 octahedra.},
doi = {10.1039/C8CC07536K},
journal = {Chemical Communications},
number = 5,
volume = 55,
place = {United Kingdom},
year = {Thu Jan 10 00:00:00 EST 2019},
month = {Thu Jan 10 00:00:00 EST 2019}
}

Journal Article:
Free Publicly Available Full Text
This content will become publicly available on November 27, 2019
Publisher's Accepted Manuscript

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Works referenced in this record:

Dynamic disorder in methylammoniumtrihalogenoplumbates (II) observed by millimeter?wave spectroscopy
journal, December 1987

  • Poglitsch, A.; Weber, D.
  • The Journal of Chemical Physics, Vol. 87, Issue 11, p. 6373-6378
  • DOI: 10.1063/1.453467