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Title: When ‘smaller is stronger’ no longer holds

Journal Article · · Materials Research Letters
ORCiD logo [1];  [1]
  1. Department of Materials Science and Engineering, Johns Hopkins University, Baltimore, MD, USA

‘Smaller is stronger’ has been a well-established tenet for the mechanical strength of small-volume single crystals. However, emerging evidence suggests that this trend does not always hold in the deep sub-micrometre regime (<~102 nm) when surface-mediated displacive and diffusive processes dominate. Here we present a perspective to highlight typical scenarios in which the single-crystal strength is influenced by surface stresses, diffusion-mediated surface creep, or dislocation-starvation-engendered high-stresses in the crystal interior, leading to ‘smaller is weaker’ or ‘plateau limited by ideal strength’. Such an unusual size dependence/independence of strength has implications for the reliability and stability of nano-structured devices. Due to significant surface effects, single crystals in the deep sub-micron regime (<~102 nm) can be ‘smaller is weaker’ or reach a ‘saturated strength plateau’, defying the well-known ‘smaller is stronger’ trend.

Research Organization:
Johns Hopkins Univ., Baltimore, MD (United States)
Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22). Materials Sciences & Engineering Division
Grant/Contract Number:
FG02-03ER46056
OSTI ID:
1483310
Alternate ID(s):
OSTI ID: 1506651
Journal Information:
Materials Research Letters, Journal Name: Materials Research Letters Vol. 6 Journal Issue: 5; ISSN 2166-3831
Publisher:
Taylor and FrancisCopyright Statement
Country of Publication:
United Kingdom
Language:
English
Citation Metrics:
Cited by: 15 works
Citation information provided by
Web of Science

References (74)

Size-induced weakening and grain boundary-assisted deformation in 60 nm grained Ni nanopillars journal January 2011
The inverse hall–petch relation in nanocrystalline metals: A discrete dislocation dynamics analysis journal March 2016
Predictive modeling of nanoindentation-induced homogeneous dislocation nucleation in copper journal March 2004
Surface dislocation nucleation controlled deformation of Au nanowires journal November 2014
What is behind the inverse Hall–Petch effect in nanocrystalline materials? journal June 2007
Achieving the ideal strength in annealed molybdenum nanopillars journal September 2010
Liquid-like pseudoelasticity of sub-10-nm crystalline silver particles journal October 2014
Molecular dynamics study of size, temperature and strain rate effects on mechanical properties of gold nanofilms journal November 2008
Sample size effects on the large strain bursts in submicron aluminum pillars journal February 2012
Plasticity of Micrometer-Scale Single Crystals in Compression journal August 2009
Ultrahigh Strength Single Crystalline Nanowhiskers Grown by Physical Vapor Deposition journal August 2009
Electronics using hybrid-molecular and mono-molecular devices journal November 2000
High Strain Rate Tensile Testing of Silver Nanowires: Rate-Dependent Brittle-to-Ductile Transition journal November 2015
Strain Hardening and Size Effect in Five-fold Twinned Ag Nanowires journal May 2015
Nanoscale gold pillars strengthened through dislocation starvation journal June 2006
Reaction pathway analysis for dislocation nucleation from a Ni surface step journal November 2009
Sample-size-dependent surface dislocation nucleation in nanoscale crystals journal February 2018
Demonstration of an inverse Hall–Petch relationship in electrodeposited nanocrystalline Ni–W alloys through tensile testing journal July 2006
Recoverable plasticity in penta-twinned metallic nanowires governed by dislocation nucleation and retraction journal January 2015
Breakdown of Self-Similar Hardening Behavior in Au Nanopillar Microplasticity journal January 2007
Nucleation-Controlled Distributed Plasticity in Penta-twinned Silver Nanowires journal July 2012
Influence of grain size on deformation mechanisms: An extension to nanocrystalline materials journal November 2005
The mechanical behavior and deformation of bicrystalline nanowires journal December 2012
Softening of nanocrystalline metals at very small grain sizes journal February 1998
Real-Time TEM Imaging of the Formation of Crystalline Nanoscale Gaps journal February 2008
Deformation mechanisms in nanotwinned metal nanopillars journal July 2012
Slip-activated surface creep with room-temperature super-elongation in metallic nanocrystals journal November 2016
Size-affected single-slip behavior of pure nickel microcrystals journal September 2005
Compressive strengths of molybdenum alloy micro-pillars prepared using a new technique journal September 2007
Nanostructure and surface effects on yield in Cu nanowires journal April 2013
Growth and Properties of "Whiskers": Further research is needed to show why crystal filaments are many times as strong as large crystals journal September 1958
Superplastic Deformation of Defect-Free Au Nanowires via Coherent Twin Propagation journal August 2011
Near-Ideal Strength in Gold Nanowires Achieved through Microstructural Design journal September 2009
Metal nanoplates: Smaller is weaker due to failure by elastic instability journal November 2017
From “Smaller is Stronger” to “Size-Independent Strength Plateau”: Towards Measuring the Ideal Strength of Iron journal April 2015
Ideal shear strain of metals and ceramics journal September 2004
Grain rotation mediated by grain boundary dislocations in nanocrystalline platinum journal July 2014
Mechanical annealing and source-limited deformation in submicrometre-diameter Ni crystals journal December 2007
Strongly correlated breeding of high-speed dislocations journal October 2016
Inverse Hall–Petch effect and grain boundary sliding controlled flow in nanocrystalline materials journal April 2007
Ideal strengths of bcc metals journal December 2001
A Maximum in the Strength of Nanocrystalline Copper journal September 2003
Liquid-like tribology of gold studied by in situ TEM journal November 2008
Tensile Strength of Whiskers journal December 1956
Grain-size dependent mechanical behavior of nanocrystalline metals journal October 2015
Nanomechanics of Hall–Petch relationship in nanocrystalline materials journal August 2009
Diffusive origins journal June 2015
Sliding of coherent twin boundaries journal October 2017
Contribution to size effect of yield strength from the stochastics of dislocation source lengths in finite samples journal February 2007
Atomistic simulations and continuum modeling of dislocation nucleation and strength in gold nanowires journal January 2012
Crystalline Liquid and Rubber-Like Behavior in Cu Nanowires journal July 2013
Strength differences arising from homogeneous versus heterogeneous dislocation nucleation journal February 2008
Clean Electromigrated Nanogaps Imaged by Transmission Electron Microscopy journal March 2006
Size-Dependent Deformation of Nanocrystalline Pt Nanopillars journal February 2012
Near-ideal theoretical strength in gold nanowires containing angstrom scale twins journal April 2013
Cold welding of ultrathin gold nanowires journal February 2010
The Strength of Gold Nanowires journal December 2004
Conductance of a Molecular Junction journal October 1997
The inherent tensile strength of iron journal March 2002
Surface Rebound of Relativistic Dislocations Directly and Efficiently Initiates Deformation Twinning journal October 2016
Effect of solute segregation on the strength of nanocrystalline alloys: Inverse Hall–Petch relation journal September 2007
Plasticity in small-sized metallic systems: Intrinsic versus extrinsic size effect journal August 2011
Lattice Anharmonicity in Defect-Free Pd Nanowhiskers journal September 2012
The strongest size journal November 2006
Phase-Transition Plasticity Response in Uniaxially Compressed Silicon Nanospheres journal October 2007
Size Dependence of Incipient Dislocation Plasticity in Ni 3 Al journal March 2005
Temperature and Strain-Rate Dependence of Surface Dislocation Nucleation journal January 2008
Plastic Poisson’s Ratio of Nanoporous Metals: A Macroscopic Signature of Tension–Compression Asymmetry at the Nanoscale journal September 2017
Size-dependent melting temperature of individual nanometer-sized metallic clusters journal November 1990
Cyclic deformation leads to defect healing and strengthening of small-volume metal crystals journal October 2015
Inverse Hall–Petch relationship in nanocrystalline tantalum journal September 2013
Visualizing size-dependent deformation mechanism transition in Sn journal July 2013
Molecular dynamics study on compressive yield strength in Ni 3 Al micro-pillars journal June 2006
Measuring surface dislocation nucleation in defect-scarce nanostructures journal May 2015

Cited By (3)

Shattering impact fragmentation of slender nanoprojectiles journal October 2019
Atomistic insights on the influence of pre-oxide shell layer and size on the compressive mechanical properties of nickel nanowires journal April 2019
Microstructure versus size: nano/microscale deformation of solute-strengthening Al alloys via pillar compression tests journal December 2018

Figures / Tables (5)