Molecular Electrocatalysts for Oxidation of Hydrogen Using Earth-Abundant Metals: Shoving Protons Around with Proton Relays
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June 2015 |
Recent advances in hydrogen bonding studies involving metal hydrides
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April 1998 |
Synthesis of the acidic dihydrogen complexes trans-[M(H2)(CN)L2]+ and trans-[M(H2)(CNH)L2]2+ where M = Fe, Ru, Os and L = dppm, dppe, dppp, depe, and dihydrogen substitution by the trifluoromethanesulfonate anion to give trans-[Ru(OTf )(CN)L2] or trans-[Ru(OTf )(CNH)L2]OTf †
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January 1999 |
Spectroscopic Evidence for Intermolecular M−H···H−OR Hydrogen Bonding: Interaction of WH(CO) 2 (NO)L 2 Hydrides with Acidic Alcohols
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January 1996 |
Group 13 Complexes of 5-Methyl-1,3,5-dithiazinane
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February 2004 |
Metals and hydrogen bonds
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January 2003 |
.eta.2-Dihydrogen on the brink of homolytic cleavage: trans-[Os(H.cntdot..cntdot..cntdot.H)H(PEt2CH2CH2PEt2)2]+ has spectroscopic and chemical properties between those of the isoelectronic complexes trans-[OsH(PPh2CH2CH2PPh2)2(.eta.2-H2)]+ and ReH3(PPh2CH2CH2PPh2)2
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April 1991 |
Di-Iron Aza Diphosphido Complexes: Mimics for the Active Site of Fe-Only Hydrogenase, and Effects of Changing the Coordinating Atoms of the Bridging Ligand in [Fe2{μ-(ECH2)2NR}(CO)6]
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November 2004 |
Counteranion-Directed Catalysis in the Tsuji-Trost Reaction: Stereocontrolled Access to 2,5-Disubstituted 3-Hydroxy-Tetrahydrofurans
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September 2012 |
Harnessing non-covalent interactions to exert control over regioselectivity and site-selectivity in catalytic reactions
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January 2017 |
Moving Protons with Pendant Amines: Proton Mobility in a Nickel Catalyst for Oxidation of Hydrogen
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September 2011 |
Synthesis of the First Examples of Transition Metal .eta.2-SiH4 Complexes, cis-Mo(.eta.2-SiH4)(CO)(R2PC2H4PR2)2, and Evidence for an Unprecedented Tautomeric Equilibrium between an .eta.2-SiH4 Complex and a Hydridosilyl Species: A Model for Methane Coordination and Activation
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January 1995 |
Heterolytic Cleavage of Hydrogen by an Iron Hydrogenase Model: An Fe-H⋅⋅⋅H-N Dihydrogen Bond Characterized by Neutron Diffraction
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April 2014 |
Role of the Azadithiolate Cofactor in Models for [FeFe]-Hydrogenase: Novel Structures and Catalytic Implications
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December 2010 |
Dihydrogen Bonding, Proton Transfer and Beyond: What We Can Learn from Kinetics and Thermodynamics
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July 2010 |
Dihydrogen complexes of ruthenium. 2. Kinetic and thermodynamic considerations affecting product distribution
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June 1990 |
Intermolecular Hydrogen Bonding between Neutral Transition Metal Hydrides (η 5 -C 5 H 5 )M(CO) 3 H (M = Mo, W) and Bases
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March 2006 |
Dihydrogen Bonding: Structures, Energetics, and Dynamics
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July 2001 |
Controlling Proton Delivery through Catalyst Structural Dynamics
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September 2016 |
Intramolecular N–H ⋯ X–Ir (X = H, F) hydrogen bonding in metal complexes
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January 1994 |
Flash photolytic generation and study of reactive species: from enols to ynols
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February 1990 |
Dihydrogen, dihydride and in between: NMR and structural properties of iron group complexes
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November 2008 |
Ion Pairing in Transition-Metal Organometallic Chemistry
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June 2005 |
Kinetic and thermodynamic acidity of hydrido transition-metal complexes. 3. Thermodynamic acidity of common mononuclear carbonyl hydrides
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April 1986 |
New types of hydrogen bonding in organometallic chemistry
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September 2002 |
An Unusual Type of H.cntdot..cntdot..cntdot.H Interaction: Ir-H.cntdot..cntdot..cntdot.H-O and Ir-H.cntdot..cntdot..cntdot.H-N Hydrogen Bonding and Its Involvement in .sigma.-Bond Metathesis
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November 1994 |
Experimental and Computational Studies of Hydrogen Bonding and Proton Transfer to [Cp*Fe(dppe)H]
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December 2004 |
Iron Complexes Bearing Diphosphine Ligands with Positioned Pendant Amines as Electrocatalysts for the Oxidation of H 2
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May 2015 |
Tricarbonylbis(phosphine)iron(I) cation radicals. A spectroscopic and theoretical study
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June 1986 |
Proton Delivery and Removal in [Ni(P R 2 N R ′ 2 ) 2 ] 2+ Hydrogen Production and Oxidation Catalysts
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November 2012 |
The mechanism of enantioselective ketone reduction with Noyori and Noyori–Ikariya bifunctional catalysts
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January 2016 |
Intermolecular interactions from a natural bond orbital, donor-acceptor viewpoint
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September 1988 |
Hydrogen and Dihydrogen Bonds in the Reactions of Metal Hydrides
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June 2016 |
Fundamentals of H 2 Binding and Reactivity on Transition Metals Underlying Hydrogenase Function and H 2 Production and Storage
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October 2007 |
Crucial Role of Anions on the Deprotonation of the Cationic Dihydrogen Complex trans -[FeH(η 2 -H 2 )(dppe) 2 ] +
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May 2007 |
Solution equilibrium between classical and nonclassical polyhydride tautomers [ReH4(CO)L3]+ and [ReH2(.eta.2-H2)(CO)L3]+ (L = PMe2Ph). Equilibrium isotope effects and an intermediate trihydrogen complex in intramolecular site exchange of dihydrogen and hydride ligands
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September 1990 |
Development of Molecular Electrocatalysts for Energy Storage
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February 2014 |
Interaction between [(η5-C5Me5)2 OsH]+PF6− and nitrogen or oxygen bases. Hydrogen bonds of the type [OsH]+ ⋯ B
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April 1993 |
Elongated dihydrogen complexes: what remains of the H–H Bond?
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January 2004 |
Mechanistic Insights on Cooperative Catalysis through Computational Quantum Chemical Methods
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December 2014 |
A Well-Defined Iron Catalyst for the Reduction of Bicarbonates and Carbon Dioxide to Formates, Alkyl Formates, and Formamides
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November 2010 |
A Nonclassical Dihydrogen Adduct of S = 1 / 2 Fe(I)
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October 2011 |
Experimental and Computational Mechanistic Studies Guiding the Rational Design of Molecular Electrocatalysts for Production and Oxidation of Hydrogen
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November 2015 |
Synthesis, Structure, and Properties of the Stable and Highly Acidic Dihydrogen Complex trans -[Os(η 2 -H 2 )(CH 3 CN)(dppe) 2 ](BF 4 ) 2 . Perspectives on the Influence of the trans Ligand on the Chemistry of the Dihydrogen Ligand
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January 1996 |
Theoretical studies of O2?:(H2O)n clusters
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June 1986 |
Gold( iii ) tetraarylporphyrin amino acid derivatives: ligand or metal centred redox chemistry?
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January 2016 |
An iron complex with pendent amines as a molecular electrocatalyst for oxidation of hydrogen
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February 2013 |
Diverse World of Unconventional Hydrogen Bonds
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August 2005 |
Solvent-Dependent Dihydrogen/Dihydride Stability for [Mo(CO)(Cp*)H 2 (PMe 3 ) 2 ] + [BF 4 ] â Determined by Multiple Solventâ
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Cation Non-Covalent Interactions
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January 2010 |
The pKa and keto-enol equilibrium constant of acetone in aqueous solution
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January 1984 |
Brønsted–Lowry Acid Strength of Metal Hydride and Dihydrogen Complexes
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March 2016 |
Mild Redox Complementation Enables H 2 Activation by [FeFe]-Hydrogenase Models
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June 2011 |
Synthesis and Spectroscopic Properties of Elongated Ruthenium Dihydrogen Complexes: Temperature and Isotope Dependence of H−H Distances
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February 2002 |
Switching On and Off a New Intramolecular Hydrogen-Hydrogen Interaction and the Heterolytic Splitting of Dihydrogen. Crystal and Molecular Structure of [Ir{H(.eta.1-SC5H4NH)}2(PCy3)2]BF4.cntdot.2.7CH2Cl2
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September 1994 |
Kinetic and thermodynamic acidity of hydrido transition-metal complexes. 4. Kinetic acidities toward aniline and their use in identifying proton-transfer mechanisms
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June 1987 |
Kinetics and Mechanism of the Proton Transfer to Cp*Fe(dppe)H: Absence of a Direct Protonation at the Metal Site
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September 2003 |
Redox Induced Configurational Isomerization of Bisphosphine–Tricarbonyliron(I) Complexes and the Difference a Ferrocene Makes
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June 2017 |
Intramolecular N−H···H−Ru Proton−Hydride Interaction in Ruthenium Complexes with (2-(Dimethylamino)ethyl)cyclopentadienyl and (3-(Dimethylamino)propyl)cyclopentadienyl Ligands. Hydrogenation of CO 2 to Formic Acid via the N−H···H−Ru Hydrogen-Bonded Complexes
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June 1998 |
Trimethylammonium tetrafluoroborate at 100 K
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November 2005 |
Infrared detection of M–H ⋯ OPPh 3 hydrogen bonds
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January 1995 |
Molecular hydrogen complexes of the transition metals. 4. Preparation and characterization of M(CO)3(PR3)2(.eta.2-H2) (M = molybdenum, tungsten) and evidence for equilibrium dissociation of the H-H bond to give MH2(CO)3(PR3)2
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October 1986 |
Explicitly Unraveling the Roles of Counterions, Solvent Molecules, and Electron Correlation in Solution Phase Reaction Pathways
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October 2016 |
H−H Distances in Elongated Transition Metal Dihydrogen Complexes: Effects of Temperature and Isotopic Substitution
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March 2001 |
Investigation of the [Cp*Mo(PMe 3 ) 3 H] n + ( n = 0, 1) Redox Pair: Dynamic Processes on Very Different Time Scales
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January 2009 |
Dihydrogen to Dihydride Isomerization Mechanism in [(C 5 Me 5 )FeH 2 (Ph 2 PCH 2 CH 2 PPh 2 )] + through the Experimental and Theoretical Analysis of Kinetic Isotope Effects
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December 2006 |
Electrostatic Control of Regioselectivity in Au(I)-Catalyzed Hydroarylation
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March 2017 |
Hydrogen Activation by Biomimetic [NiFe]-Hydrogenase Model Containing Protected Cyanide Cofactors
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July 2013 |
Sterically crowded stable simple enols
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December 1988 |
Molecular hydrogen complexes of the transition metals. 3. Evidence for a new complex, Mo(CO)(dppe)2(H2), and for solution equilibrium between dihydrogen and dihydride forms, M-.eta.2-H2 .dblarw. H-M-H, in M(CO)3(PR3)2(H2)
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March 1986 |
Synthesis and properties of a series of ruthenium dihydrogen complexes
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September 1987 |
Synthetic Models for the Active Site of the [FeFe]-Hydrogenase: Catalytic Proton Reduction and the Structure of the Doubly Protonated Intermediate
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November 2012 |
Counteranion-Directed Catalysis in the Tsuji-Trost Reaction: Stereocontrolled Access to 2,5-Disubstituted 3-Hydroxy-Tetrahydrofurans
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journal
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September 2012 |
Heterolytic Cleavage of Hydrogen by an Iron Hydrogenase Model: An Fe-H⋅⋅⋅H-N Dihydrogen Bond Characterized by Neutron Diffraction
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April 2014 |