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Title: Synthesis and electrochemical properties of Li1.3Nb0.3Cr0.4O2 as a high-capacity cathode material for rechargeable lithium batteries

Journal Article · · ChemComm
DOI:https://doi.org/10.1039/C8CC07660J· OSTI ID:1483754
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  1. Fudan Univ., Shanghai (People's Republic of China)
  2. Brookhaven National Lab. (BNL), Upton, NY (United States)
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A cation-disordered Li-excess material (Li 1.3 Cr 0.4 Nb 0.3 O 2 ) delivers a high reversible capacity, originating from a Cr 3+ /Cr 6+ three-electron redox reaction.

Research Organization:
Brookhaven National Laboratory (BNL), Upton, NY (United States)
Sponsoring Organization:
USDOE Office of Energy Efficiency and Renewable Energy (EERE), Vehicle Technologies Office (EE-3V); USDOE
Grant/Contract Number:
SC0012704
OSTI ID:
1483754
Alternate ID(s):
OSTI ID: 1482851
Report Number(s):
BNL-209508-2018-JAAM
Journal Information:
ChemComm, Vol. 54, Issue 98; ISSN 1359-7345
Publisher:
Royal Society of ChemistryCopyright Statement
Country of Publication:
United States
Language:
English
Citation Metrics:
Cited by: 8 works
Citation information provided by
Web of Science

References (29)

Reversible anionic redox chemistry in high-capacity layered-oxide electrodes journal July 2013
In Situ X-Ray Absorption Study of a Layered Manganese-Chromium Oxide-Based Cathode Material journal January 2002
High-Capacity Cathode Material with High Voltage for Li-Ion Batteries journal January 2018
Structural Changes in Li 2 MnO 3 Cathode Material for Li-Ion Batteries journal December 2013
Nanoionics: ion transport and electrochemical storage in confined systems journal November 2005
Recent advances in the electrolytes for interfacial stability of high-voltage cathodes in lithium-ion batteries journal January 2015
Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides journal September 1976
Reversible Three-Electron Redox Reaction of Mo 3+ /Mo 6+ for Rechargeable Lithium Batteries journal March 2017
Assignment of pre-edge peaks in K-edge x-ray absorption spectra of 3d transition metal compounds: electric dipole or quadrupole? journal November 2008
Lithium-free transition metal monoxides for positive electrodes in lithium-ion batteries journal January 2017
Structure of the incommensurate composite crystal [Sr 2 Cu 2 O 3 ][CuO 2 ] x ( x = 1.436) journal February 1994
Performance and design considerations for lithium excess layered oxide positive electrode materials for lithium ion batteries journal January 2016
Electrodes with High Power and High Capacity for Rechargeable Lithium Batteries journal February 2006
The origin of electrochemical activity in Li2MnO3 journal October 2002
Unlocking the Potential of Cation-Disordered Oxides for Rechargeable Lithium Batteries journal January 2014
The Effect of Cation Disorder on the Average Li Intercalation Voltage of Transition-Metal Oxides journal May 2016
Crystal Habit-Tuned Nanoplate Material of Li[Li1/3-2x/3NixMn2/3-x/3]O2 for High-Rate Performance Lithium-Ion Batteries journal August 2010
Chemical and electrochemical deintercalations of the layered compounds LiMO2 (M = Cr, Co) and NaM′O2 (M′ Cr, Fe, Co, Ni) journal January 1983
Probing Reversible Multielectron Transfer and Structure Evolution of Li 1.2 Cr 0.4 Mn 0.4 O 2 Cathode Material for Li-Ion Batteries in a Voltage Range of 1.0–4.8 V journal July 2015
Origin of stabilization and destabilization in solid-state redox reaction of oxide ions for lithium-ion batteries journal December 2016
Promise and reality of post-lithium-ion batteries with high energy densities journal March 2016
Structure and electrochemistry of LiMO2 (M=Ti, Mn, Fe, Co, Ni) prepared by mechanochemical synthesis journal September 1998
High-capacity electrode materials for rechargeable lithium batteries: Li 3 NbO 4 -based system with cation-disordered rocksalt structure journal June 2015
Atomic Structure of Li 2 MnO 3 after Partial Delithiation and Re-Lithiation journal June 2013
Electrochemical intercalation activity of layered NaCrO2 vs. LiCrO2 journal March 2010
Approaching the limits of cationic and anionic electrochemical activity with the Li-rich layered rocksalt Li3IrO4 journal December 2017
In Situ and Ex Situ XRD Investigation of Li[Cr[sub x]Li[sub 1/3−x/3]Mn[sub 2/3−2x/3]]O[sub 2] (x=1/3) Cathode Material journal January 2003
The Origin of Electrochemical Activity in Li2MnO3. journal March 2003
Electrodes with High Power and High Capacity for Rechargeable Lithium Batteries. journal May 2006

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