Surface-Engineered Inorganic Nanoporous Membranes for Vapor and Pervaporative Separations of Water–Ethanol Mixtures

Hu, Michael Z.; Engtrakul, Chaiwat; Bischoff, Brian L.; Lu, Mi; Alemseghed, Mussie

doi:10.3390/membranes8040095

Title: Surface-Engineered Inorganic Nanoporous Membranes for Vapor and Pervaporative Separations of Water–Ethanol Mixtures

Journal Article · Fri Oct 12 00:00:00 EDT 2018 · Membranes

DOI:https://doi.org/10.3390/membranes8040095· OSTI ID:1480681

Hu, Michael Z. ^[1]; Engtrakul, Chaiwat ^[2]; Bischoff, Brian L. ^[1];

^[1]; Alemseghed, Mussie ^[1]

Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
National Renewable Energy Lab. (NREL), Golden, CO (United States)

Surface wettability-tailored porous ceramic/metallic membranes (in the tubular and planar disc form) were prepared and studied for both vapor-phase separation and liquid pervaporative separations of water-ethanol mixtures. Superhydrophobic nanoceramic membranes demonstrated more selective permeation of ethanol (relative to water) by cross-flow pervaporation of liquid ethanol–water mixture (10 wt % ethanol feed at 80 °C). In addition, both superhydrophilic and superhydrophobic membranes were tested for the vapor-phase separations of water–ethanol mixtures. Porous inorganic membranes having relatively large nanopores (up to 8-nm) demonstrated good separation selectivity with higher permeation flux through a non-molecular-sieving mechanism. Due to surface-enhanced separation selectivity, larger nanopore-sized membranes (~5–100 nm) can be employed for both pervaporation and vapor phase separations to obtain higher selectivity (e.g., permselectivity for ethanol of 13.9 during pervaporation and a vapor phase separation factor of 1.6), with higher flux due to larger nanopores than the traditional size-exclusion membranes (e.g., inorganic zeolite-based membranes having sub-nanometer pores). The prepared superhydrophobic porous inorganic membranes in this work showed good thermal stability (i.e., the large contact angle remains the same after 300 °C for 4 h) and chemical stability to ethanol, while the silica-textured superhydrophilic surfaced membranes can tolerate even higher temperatures. These surface-engineered metallic/ceramic nanoporous membranes should have better high-temperature tolerance for hot vapor processing than those reported for polymeric membranes.

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Research Organization:: National Renewable Energy Laboratory (NREL), Golden, CO (United States); Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE), Transportation Office. Bioenergy Technologies Office

Grant/Contract Number:: AC36-08GO28308; AC05-00OR22725

OSTI ID:: 1480681

Alternate ID(s):: OSTI ID: 1482451

Report Number(s):: NREL/JA-5900-72700; MBSEB6

Journal Information:: Membranes, Vol. 8, Issue 4; ISSN 2077-0375

Publisher:: MDPICopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 7 works

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Title: Surface-Engineered Inorganic Nanoporous Membranes for Vapor and Pervaporative Separations of Water–Ethanol Mixtures

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