B 12 (SCN) 12 – : An Ultrastable Weakly Coordinating Dianion
Journal Article
·
· Journal of Physical Chemistry. C
Stable dianions that are weakly coordinating with metal ions are not common. In this work, we show that the thiocyanate SCN– anion, known for its detoxification property of cyanide CN– and antidegradation property of perovskite solar-cell materials, can also be used to produce a new set of weakly coordinating B12(SCN)12– dianion complexes which are potential candidates for the anionic part inside the electrolytes of metal-ion, especially the magnesium-ion-based, batteries.
- Research Organization:
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). National Energy Research Scientific Computing Center (NERSC)
- Sponsoring Organization:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- DOE Contract Number:
- FG02-96ER45579; AC02-05CH11231
- OSTI ID:
- 1480464
- Journal Information:
- Journal of Physical Chemistry. C, Vol. 121, Issue 14; ISSN 1932-7447
- Country of Publication:
- United States
- Language:
- English
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