Confined Ultrathin Pd-Ce Nanowires with Outstanding Moisture and SO2 Tolerance in Methane Combustion
Abstract
Abstract An efficient strategy (enhanced metal oxide interaction and core–shell confinement to inhibit the sintering of noble metal) is presented confined ultrathin Pd‐CeO x nanowire (2.4 nm) catalysts for methane combustion, which enable CH 4 total oxidation at a low temperature of 350 °C, much lower than that of a commercial Pd/Al 2 O 3 catalyst (425 °C). Importantly, unexpected stability was observed even under harsh conditions (800 °C, water vapor, and SO 2 ), owing to the confinement and shielding effect of the porous silica shell together with the promotion of CeO 2 . Pd‐CeO x solid solution nanowires (Pd‐Ce NW) as cores and porous silica as shells (Pd‐CeNW@SiO 2 ) were rationally prepared by a facile and direct self‐assembly strategy for the first time. This strategy is expected to inspire more active and stable catalysts for use under severe conditions (vehicle emissions control, reforming, and water–gas shift reaction).
- Authors:
-
- Nanchang Univ. (China). Inst. of Applied Chemistry; Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Nanchang Univ. (China). Inst. of Applied Chemistry
- Shanghai Jiao Tong Univ. (China)
- Shanghai Jiao Tong Univ. (China); Univ. of Tennessee, Knoxville, TN (United States)
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Univ. of Tennessee, Knoxville, TN (United States)
- Publication Date:
- Research Org.:
- Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States); Univ. of Tennessee, Knoxville, TN (United States); Nanchang Univ. (China); Shanghai Jiao Tong Univ. (China)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES); National Key Research and Development Program of China; National Natural Science Foundation of China (NSFC); Natural Science Foundation of Jiangxi Province; Foundation of State Key Lab. of Coal Clean Utilization and Ecological Chemical Engineering, China
- OSTI Identifier:
- 1479715
- Alternate Identifier(s):
- OSTI ID: 1459724
- Grant/Contract Number:
- AC05-00OR22725; 2016YFC0205900; 21503106; 21567016; 21773106; 20171BCB23016; 20171BAB203024; 2016-15
- Resource Type:
- Journal Article: Accepted Manuscript
- Journal Name:
- Angewandte Chemie (International Edition)
- Additional Journal Information:
- Journal Volume: 57; Journal Issue: 29; Journal ID: ISSN 1433-7851
- Publisher:
- Wiley
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; cerium; core-shell materials; methane oxidation; palladium; solid solutions
Citation Formats
Peng, Honggen, Rao, Cheng, Zhang, Ning, Wang, Xiang, Liu, Wenming, Mao, Wenting, Han, Lu, Zhang, Pengfei, and Dai, Sheng. Confined Ultrathin Pd-Ce Nanowires with Outstanding Moisture and SO2 Tolerance in Methane Combustion. United States: N. p., 2018.
Web. doi:10.1002/anie.201803393.
Peng, Honggen, Rao, Cheng, Zhang, Ning, Wang, Xiang, Liu, Wenming, Mao, Wenting, Han, Lu, Zhang, Pengfei, & Dai, Sheng. Confined Ultrathin Pd-Ce Nanowires with Outstanding Moisture and SO2 Tolerance in Methane Combustion. United States. https://doi.org/10.1002/anie.201803393
Peng, Honggen, Rao, Cheng, Zhang, Ning, Wang, Xiang, Liu, Wenming, Mao, Wenting, Han, Lu, Zhang, Pengfei, and Dai, Sheng. 2018.
"Confined Ultrathin Pd-Ce Nanowires with Outstanding Moisture and SO2 Tolerance in Methane Combustion". United States. https://doi.org/10.1002/anie.201803393. https://www.osti.gov/servlets/purl/1479715.
@article{osti_1479715,
title = {Confined Ultrathin Pd-Ce Nanowires with Outstanding Moisture and SO2 Tolerance in Methane Combustion},
author = {Peng, Honggen and Rao, Cheng and Zhang, Ning and Wang, Xiang and Liu, Wenming and Mao, Wenting and Han, Lu and Zhang, Pengfei and Dai, Sheng},
abstractNote = {Abstract An efficient strategy (enhanced metal oxide interaction and core–shell confinement to inhibit the sintering of noble metal) is presented confined ultrathin Pd‐CeO x nanowire (2.4 nm) catalysts for methane combustion, which enable CH 4 total oxidation at a low temperature of 350 °C, much lower than that of a commercial Pd/Al 2 O 3 catalyst (425 °C). Importantly, unexpected stability was observed even under harsh conditions (800 °C, water vapor, and SO 2 ), owing to the confinement and shielding effect of the porous silica shell together with the promotion of CeO 2 . Pd‐CeO x solid solution nanowires (Pd‐Ce NW) as cores and porous silica as shells (Pd‐CeNW@SiO 2 ) were rationally prepared by a facile and direct self‐assembly strategy for the first time. This strategy is expected to inspire more active and stable catalysts for use under severe conditions (vehicle emissions control, reforming, and water–gas shift reaction).},
doi = {10.1002/anie.201803393},
url = {https://www.osti.gov/biblio/1479715},
journal = {Angewandte Chemie (International Edition)},
issn = {1433-7851},
number = 29,
volume = 57,
place = {United States},
year = {Tue May 22 00:00:00 EDT 2018},
month = {Tue May 22 00:00:00 EDT 2018}
}
Web of Science
Figures / Tables:
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