Construction of Hierarchically Porous Nanoparticles@Metal-Organic Frameworks Composites by Inherent Defects for the Enhancement of Catalytic Efficiency

Meng, Fanchen; Zhang, Suoying; Ma, Lu; Zhang, Weina; Li, Matthew; Wu, Tianpin; Li, Hang; Zhang, Tao; Lu, Xiaohua; Huo, Fengwei; Lu, Jun

doi:10.1002/adma.201803263

Title: Construction of Hierarchically Porous Nanoparticles@Metal-Organic Frameworks Composites by Inherent Defects for the Enhancement of Catalytic Efficiency

Journal Article · Wed Oct 10 00:00:00 EDT 2018 · Advanced Materials

DOI:https://doi.org/10.1002/adma.201803263· OSTI ID:1504256

Meng, Fanchen ^[1]; Zhang, Suoying ^[2]; Ma, Lu ^[3]; Zhang, Weina ^[1]; Li, Matthew ^[4]; Wu, Tianpin ^[3]; Li, Hang ^[5]; Zhang, Tao ^[2]; Lu, Xiaohua ^[5]; Huo, Fengwei ^[1];

^[3]

Nanjing Tech Univ. (Nanjing Tech), Nanjing (People's Republic of China)
Nanjing Tech Univ. (Nanjing Tech), Nanjing (People's Republic of China); Argonne National Lab. (ANL), Argonne, IL (United States)
Argonne National Lab. (ANL), Argonne, IL (United States)
Univ. of Waterloo, Waterloo, ON (Canada); Argonne National Lab. (ANL), Argonne, IL (United States)
Nanjing Tech Univ., Nanjing (People's Republic of China)

Abstract Nanoparticles@metal–organic frameworks (MOFs) composites have attracted considerable attention in recent years due to the prominent selective catalytic activity. However, it is highly desirable to develop a simple and universal way to settle the trade‐off between the catalytic efficiency and selectivity. Herein, by employing the thermal instability of inherent defects, hierarchically porous Pt@UiO‐66‐NH ₂ , Pt@UiO‐66, Pt@ZIF‐8, and Au@ZIF‐8 are successfully constructed after annealing at an appropriate temperature, respectively. The generated mesopores in the MOFs can be located around the external nanoparticle to retain the MOF shell for catalytic selectivity. Finally, when tested in olefin hydrogenation, Pt@UiO‐66‐NH ₂ shows significantly improved catalytic rate and enhanced dynamic selectivity.

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Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE), Vehicle Technologies Office (EE-3V); National Natural Science Foundation of China (NSFC); National Natural Science Foundation of Jiangsu Province; China Scholarship Council; USDOE Office of Science (SC), Basic Energy Sciences (BES); National Key Research and Development Program of China

Grant/Contract Number:: AC02-06CH11357; DE‐AC02‐06CH11357

OSTI ID:: 1504256

Alternate ID(s):: OSTI ID: 1479567

Journal Information:: Advanced Materials, Vol. 30, Issue 49; ISSN 0935-9648

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 82 works

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Rising Up: Hierarchical Metal–Organic Frameworks in Experiments and Simulations Luo, Yi; Ahmad, Momin; Schug, Alexander Advanced Materials, Vol. 31, Issue 26 https://doi.org/10.1002/adma.201901744	journal	May 2019
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