A Highly Porous Copper Electrocatalyst for Carbon Dioxide Reduction

Lv, Jing-Jing; Jouny, Matthew; Luc, Wesley; Zhu, Wenlei; Zhu, Jun-Jie; Jiao, Feng

doi:10.1002/adma.201803111

Title: A Highly Porous Copper Electrocatalyst for Carbon Dioxide Reduction

Journal Article · Wed Oct 10 00:00:00 EDT 2018 · Advanced Materials

DOI:https://doi.org/10.1002/adma.201803111· OSTI ID:1712663

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^[2]; Zhu, Jun-Jie ^[3];

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Univ. of Delaware, Newark, DE (United States); Nanjing Univ. (China)
Univ. of Delaware, Newark, DE (United States)
Nanjing Univ. (China)

Electrochemical reduction of carbon dioxide (CO₂) is an appealing approach toward tackling climate change associated with atmospheric CO₂ emissions. This approach uses CO₂ as the carbon feedstock to produce value-added chemicals, resulting in a carbon-neutral (or even carbon-negative) process for chemical production. Many efforts have been devoted to the development of CO₂ electrolysis devices that can be operated at industrially relevant rates; however, limited progress has been made, especially for valuable C₂₊ products. Herein, we synthesized a nanoporous copper CO₂ reduction catalyst and integrated it into a microfluidic CO₂ flow cell electrolyzer. The CO₂ electrolyzer exhibited a current density of 653 mA/cm^-2 with a C₂₊ product selectivity of ~62% at an applied potential of -0.67 V (vs. reversible hydrogen electrode). Here, the highly porous electrode structure facilitated rapid gas transport across the electrode-electrolyte interface at high current densities. Further investigations on electrolyte effects revealed that the surface pH value was substantially different from the pH of bulk electrolyte, especially for non-buffering near-neutral electrolytes when operating at high currents.

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Research Organization:: Univ. of Delaware, Newark, DE (United States); Nanjing Univ. (China)

Sponsoring Organization:: USDOE

Grant/Contract Number:: FE0029868; 1350911

OSTI ID:: 1712663

Alternate ID(s):: OSTI ID: 1479518

Journal Information:: Advanced Materials, Vol. 30, Issue 49; ISSN 0935-9648

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 314 works

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
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