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Title: Selective deoxygenation of nitrate to nitrosyl using trivalent chromium and the Mashima reagent: reductive silylation

Abstract

1,4-Bis(trimethylsilyl)-1,4-diaza-2,5-cyclohexadiene is an effective silyl transfer reagent towards the oxygen of nitrate coordinated to Cr( iii ) in a pincer complex.

Authors:
ORCiD logo [1]; ORCiD logo [1]; ORCiD logo [1]; ORCiD logo [1]
  1. Indiana University, Department of Chemistry, Bloomington, USA
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1478435
Grant/Contract Number:  
AC02-06CH11357
Resource Type:
Journal Article: Published Article
Journal Name:
Chemical Science
Additional Journal Information:
Journal Name: Chemical Science; Journal ID: ISSN 2041-6520
Publisher:
Royal Society of Chemistry (RSC)
Country of Publication:
United Kingdom
Language:
English

Citation Formats

Seo, Junghee, Cabelof, Alyssa C., Chen, Chun-Hsing, and Caulton, Kenneth G.. Selective deoxygenation of nitrate to nitrosyl using trivalent chromium and the Mashima reagent: reductive silylation. United Kingdom: N. p., 2019. Web. doi:10.1039/C8SC02979B.
Seo, Junghee, Cabelof, Alyssa C., Chen, Chun-Hsing, & Caulton, Kenneth G.. Selective deoxygenation of nitrate to nitrosyl using trivalent chromium and the Mashima reagent: reductive silylation. United Kingdom. doi:10.1039/C8SC02979B.
Seo, Junghee, Cabelof, Alyssa C., Chen, Chun-Hsing, and Caulton, Kenneth G.. Tue . "Selective deoxygenation of nitrate to nitrosyl using trivalent chromium and the Mashima reagent: reductive silylation". United Kingdom. doi:10.1039/C8SC02979B.
@article{osti_1478435,
title = {Selective deoxygenation of nitrate to nitrosyl using trivalent chromium and the Mashima reagent: reductive silylation},
author = {Seo, Junghee and Cabelof, Alyssa C. and Chen, Chun-Hsing and Caulton, Kenneth G.},
abstractNote = {1,4-Bis(trimethylsilyl)-1,4-diaza-2,5-cyclohexadiene is an effective silyl transfer reagent towards the oxygen of nitrate coordinated to Cr( iii ) in a pincer complex.},
doi = {10.1039/C8SC02979B},
journal = {Chemical Science},
number = ,
volume = ,
place = {United Kingdom},
year = {Tue Jan 01 00:00:00 EST 2019},
month = {Tue Jan 01 00:00:00 EST 2019}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record at 10.1039/C8SC02979B

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