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Title: A cyanide-bridged di-manganese carbonyl complex that photochemically reduces CO 2 to CO

Abstract

A cyanide-bridged di-manganese complex, {[Mn(bpy)(CO) 3 ] 2 (μ-CN)} + , is introduced as an efficient electrocatalyst and photochemically active for proton-assisted of CO 2 reduction to CO.

Authors:
ORCiD logo [1]; ORCiD logo [1]; ORCiD logo [1];  [1]; ORCiD logo [1]; ORCiD logo [1]
  1. Princeton University, Department of Chemistry, Princeton, USA
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1478268
Grant/Contract Number:  
DESC0015429
Resource Type:
Journal Article: Publisher's Accepted Manuscript
Journal Name:
Dalton Transactions
Additional Journal Information:
Journal Name: Dalton Transactions; Journal ID: ISSN 1477-9226
Publisher:
Royal Society of Chemistry (RSC)
Country of Publication:
United Kingdom
Language:
English

Citation Formats

Kuo, Hsin-Ya, Lee, Tia S., Chu, An T., Tignor, Steven E., Scholes, Gregory D., and Bocarsly, Andrew B. A cyanide-bridged di-manganese carbonyl complex that photochemically reduces CO 2 to CO. United Kingdom: N. p., 2019. Web. doi:10.1039/C8DT03358G.
Kuo, Hsin-Ya, Lee, Tia S., Chu, An T., Tignor, Steven E., Scholes, Gregory D., & Bocarsly, Andrew B. A cyanide-bridged di-manganese carbonyl complex that photochemically reduces CO 2 to CO. United Kingdom. doi:10.1039/C8DT03358G.
Kuo, Hsin-Ya, Lee, Tia S., Chu, An T., Tignor, Steven E., Scholes, Gregory D., and Bocarsly, Andrew B. Tue . "A cyanide-bridged di-manganese carbonyl complex that photochemically reduces CO 2 to CO". United Kingdom. doi:10.1039/C8DT03358G.
@article{osti_1478268,
title = {A cyanide-bridged di-manganese carbonyl complex that photochemically reduces CO 2 to CO},
author = {Kuo, Hsin-Ya and Lee, Tia S. and Chu, An T. and Tignor, Steven E. and Scholes, Gregory D. and Bocarsly, Andrew B.},
abstractNote = {A cyanide-bridged di-manganese complex, {[Mn(bpy)(CO) 3 ] 2 (μ-CN)} + , is introduced as an efficient electrocatalyst and photochemically active for proton-assisted of CO 2 reduction to CO.},
doi = {10.1039/C8DT03358G},
journal = {Dalton Transactions},
number = ,
volume = ,
place = {United Kingdom},
year = {Tue Jan 01 00:00:00 EST 2019},
month = {Tue Jan 01 00:00:00 EST 2019}
}

Journal Article:
Free Publicly Available Full Text
This content will become publicly available on October 12, 2019
Publisher's Accepted Manuscript

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Works referenced in this record:

Theory of Stationary Electrode Polarography. Single Scan and Cyclic Methods Applied to Reversible, Irreversible, and Kinetic Systems.
journal, April 1964

  • Nicholson, R. S.; Shain, Irving
  • Analytical Chemistry, Vol. 36, Issue 4, p. 706-723
  • DOI: 10.1021/ac60210a007