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Title: A Highly Active Molybdenum Phosphide Catalyst for Methanol Synthesis from CO and CO 2

Authors:
ORCiD logo [1]; ORCiD logo [1];  [1];  [1];  [1];  [1];  [1]; ORCiD logo [1];  [1]; ORCiD logo [1];  [1];  [1]; ORCiD logo [1]
  1. SUNCAT Center for Interface Science and CatalysisStanford University Stanford CA 94305 USA, SLAC National Accelerator Laboratory Menlo Park CA 94025 USA
Publication Date:
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1478125
Grant/Contract Number:  
AC02-76SF00515; DEAC02-76SF00515
Resource Type:
Journal Article: Publisher's Accepted Manuscript
Journal Name:
Angewandte Chemie
Additional Journal Information:
Journal Name: Angewandte Chemie Journal Volume: 130 Journal Issue: 46; Journal ID: ISSN 0044-8249
Publisher:
Wiley Blackwell (John Wiley & Sons)
Country of Publication:
Germany
Language:
English

Citation Formats

Duyar, Melis S., Tsai, Charlie, Snider, Jonathan L., Singh, Joseph A., Gallo, Alessandro, Yoo, Jong Suk, Medford, Andrew J., Abild‐Pedersen, Frank, Studt, Felix, Kibsgaard, Jakob, Bent, Stacey F., Nørskov, Jens K., and Jaramillo, Thomas F. A Highly Active Molybdenum Phosphide Catalyst for Methanol Synthesis from CO and CO 2. Germany: N. p., 2018. Web. doi:10.1002/ange.201806583.
Duyar, Melis S., Tsai, Charlie, Snider, Jonathan L., Singh, Joseph A., Gallo, Alessandro, Yoo, Jong Suk, Medford, Andrew J., Abild‐Pedersen, Frank, Studt, Felix, Kibsgaard, Jakob, Bent, Stacey F., Nørskov, Jens K., & Jaramillo, Thomas F. A Highly Active Molybdenum Phosphide Catalyst for Methanol Synthesis from CO and CO 2. Germany. doi:10.1002/ange.201806583.
Duyar, Melis S., Tsai, Charlie, Snider, Jonathan L., Singh, Joseph A., Gallo, Alessandro, Yoo, Jong Suk, Medford, Andrew J., Abild‐Pedersen, Frank, Studt, Felix, Kibsgaard, Jakob, Bent, Stacey F., Nørskov, Jens K., and Jaramillo, Thomas F. Thu . "A Highly Active Molybdenum Phosphide Catalyst for Methanol Synthesis from CO and CO 2". Germany. doi:10.1002/ange.201806583.
@article{osti_1478125,
title = {A Highly Active Molybdenum Phosphide Catalyst for Methanol Synthesis from CO and CO 2},
author = {Duyar, Melis S. and Tsai, Charlie and Snider, Jonathan L. and Singh, Joseph A. and Gallo, Alessandro and Yoo, Jong Suk and Medford, Andrew J. and Abild‐Pedersen, Frank and Studt, Felix and Kibsgaard, Jakob and Bent, Stacey F. and Nørskov, Jens K. and Jaramillo, Thomas F.},
abstractNote = {},
doi = {10.1002/ange.201806583},
journal = {Angewandte Chemie},
issn = {0044-8249},
number = 46,
volume = 130,
place = {Germany},
year = {2018},
month = {10}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record at 10.1002/ange.201806583

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Works referenced in this record:

Active Oxygen Vacancy Site for Methanol Synthesis from CO 2 Hydrogenation on In 2 O 3 (110): A DFT Study
journal, April 2013

  • Ye, Jingyun; Liu, Changjun; Mei, Donghai
  • ACS Catalysis, Vol. 3, Issue 6
  • DOI: 10.1021/cs400132a

Activity and Selectivity Trends in Synthesis Gas Conversion to Higher Alcohols
journal, October 2013

  • Medford, Andrew J.; Lausche, Adam C.; Abild-Pedersen, Frank
  • Topics in Catalysis, Vol. 57, Issue 1-4
  • DOI: 10.1007/s11244-013-0169-0

IR study of polycrystalline ceria properties in oxidised and reduced states
journal, April 1999


Next-nearest neighbour contributions to P 2p3/2 X-ray photoelectron binding energy shifts of mixed transition-metal phosphides M1−xM′xP with the MnP-type structure
journal, October 2007

  • Grosvenor, Andrew P.; Cavell, Ronald G.; Mar, Arthur
  • Journal of Solid State Chemistry, Vol. 180, Issue 10
  • DOI: 10.1016/j.jssc.2007.07.027

L-Edge spectroscopy of molybdenum compounds and enzymes
journal, March 1990

  • George, G. N.; Cleland, W. E.; Enemark, J. H.
  • Journal of the American Chemical Society, Vol. 112, Issue 7
  • DOI: 10.1021/ja00163a010

Bridging the Time Gap: A Copper/Zinc Oxide/Aluminum Oxide Catalyst for Methanol Synthesis Studied under Industrially Relevant Conditions and Time Scales
journal, September 2016

  • Lunkenbein, Thomas; Girgsdies, Frank; Kandemir, Timur
  • Angewandte Chemie, Vol. 128, Issue 41
  • DOI: 10.1002/ange.201603368

New and revisited insights into the promotion of methanol synthesis catalysts by CO2
journal, January 2013

  • Martin, Oliver; Pérez-Ramírez, Javier
  • Catalysis Science & Technology, Vol. 3, Issue 12
  • DOI: 10.1039/c3cy00573a

Highly active copper-ceria and copper-ceria-titania catalysts for methanol synthesis from CO2
journal, July 2014


Infrared spectroscopy of copper/zinc oxide catalysts for the water-gas shift reaction and methanol synthesis
journal, November 1984

  • Edwards, James F.; Schrader, G. L.
  • The Journal of Physical Chemistry, Vol. 88, Issue 23
  • DOI: 10.1021/j150667a032

Synthesis gas conversion over MoP catalysts
journal, January 2009


Indium Oxide as a Superior Catalyst for Methanol Synthesis by CO 2 Hydrogenation
journal, March 2016

  • Martin, Oliver; Martín, Antonio J.; Mondelli, Cecilia
  • Angewandte Chemie, Vol. 128, Issue 21
  • DOI: 10.1002/ange.201600943

Catalytic reduction of CO 2 by H 2 for synthesis of CO, methanol and hydrocarbons: challenges and opportunities
journal, January 2016

  • Porosoff, Marc D.; Yan, Binhang; Chen, Jingguang G.
  • Energy & Environmental Science, Vol. 9, Issue 1
  • DOI: 10.1039/C5EE02657A

Discovery of a Ni-Ga catalyst for carbon dioxide reduction to methanol
journal, March 2014

  • Studt, Felix; Sharafutdinov, Irek; Abild-Pedersen, Frank
  • Nature Chemistry, Vol. 6, Issue 4
  • DOI: 10.1038/nchem.1873

Stability of formate species on β-Ga2O3
journal, January 2009

  • Calatayud, M.; Collins, S. E.; Baltanás, M. A.
  • Physical Chemistry Chemical Physics, Vol. 11, Issue 9
  • DOI: 10.1039/b800519b

In-situ surface and gas phase analysis for kinetic studies under transient conditions The catalytic hydrogenation of CO2
journal, March 1997


The Mechanism of CO and CO 2 Hydrogenation to Methanol over Cu-Based Catalysts
journal, March 2015


Evidence for a special formate species adsorbed on the Cu–Zn active site for methanol synthesis
journal, May 1998


Novel catalysts for advanced hydroprocessing: transition metal phosphides
journal, May 2003


Scaling Properties of Adsorption Energies for Hydrogen-Containing Molecules on Transition-Metal Surfaces
journal, July 2007


Quantifying the promotion of Cu catalysts by ZnO for methanol synthesis
journal, May 2016


Adsorption and Reactions of Formic Acid on (2×2)-NiO(111)/Ni(111) Surface. 1. TPD and IRAS Studies under Ultrahigh Vacuum Conditions
journal, January 1996

  • Bandara, Athula; Kubota, Jun; Wada, Akihide
  • The Journal of Physical Chemistry, Vol. 100, Issue 36
  • DOI: 10.1021/jp9607834

The Active Site of Methanol Synthesis over Cu/ZnO/Al2O3 Industrial Catalysts
journal, April 2012


Der Weg in die Unabhängigkeit vom Öl mithilfe einer Chemie auf der Basis von erneuerbarem Methanol
journal, December 2012


Bridging the Time Gap: A Copper/Zinc Oxide/Aluminum Oxide Catalyst for Methanol Synthesis Studied under Industrially Relevant Conditions and Time Scales
journal, September 2016

  • Lunkenbein, Thomas; Girgsdies, Frank; Kandemir, Timur
  • Angewandte Chemie International Edition, Vol. 55, Issue 41
  • DOI: 10.1002/anie.201603368

Hydrogenation of CO 2 to Methanol: Importance of Metal–Oxide and Metal–Carbide Interfaces in the Activation of CO 2
journal, October 2015


The P K-near edge absorption spectra of phosphates
journal, December 1995


Catalytic Properties of Molybdenum Carbide, Nitride and Phosphide: A Theoretical Study
journal, December 2003


Designing an improved transition metal phosphide catalyst for hydrogen evolution using experimental and theoretical trends
journal, January 2015

  • Kibsgaard, Jakob; Tsai, Charlie; Chan, Karen
  • Energy & Environmental Science, Vol. 8, Issue 10
  • DOI: 10.1039/C5EE02179K

A study of K-promoted MoP–SiO2 catalysts for synthesis gas conversion
journal, April 2010


Structural stability and mutual transformations of molybdenum carbide, nitride and phosphide
journal, November 2011


Theoretical Analysis of Transition-Metal Catalysts for Formic Acid Decomposition
journal, March 2014

  • Yoo, Jong Suk; Abild-Pedersen, Frank; Nørskov, Jens K.
  • ACS Catalysis, Vol. 4, Issue 4
  • DOI: 10.1021/cs400664z

Indium Oxide as a Superior Catalyst for Methanol Synthesis by CO 2 Hydrogenation
journal, March 2016

  • Martin, Oliver; Martín, Antonio J.; Mondelli, Cecilia
  • Angewandte Chemie International Edition, Vol. 55, Issue 21
  • DOI: 10.1002/anie.201600943

Towards Oil Independence Through Renewable Methanol Chemistry
journal, December 2012


Mechanism of Methanol Synthesis on Cu through CO 2 and CO Hydrogenation
journal, February 2011

  • Grabow, L. C.; Mavrikakis, M.
  • ACS Catalysis, Vol. 1, Issue 4
  • DOI: 10.1021/cs200055d