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Title: Multi-principal element transition metal dichalcogenides via reactive fusion of 3D-heterostructures

Abstract

Transition metal dichalcogenides combining multiple principal elements in their structures are synthesized via mechanochemical exfoliation and spontaneous reassembly of binary precursors into 3D-heterostructures that are converted into single-phase layered materials by high-temperature reactive fusion. As a result, physical and chemical events enabling these transformations are summarized in the form of a conceivable reaction mechanism.

Authors:
 [1];  [1];  [1]; ORCiD logo [1]; ORCiD logo [1]; ORCiD logo [1]; ORCiD logo [1]
  1. Ames Lab. and Iowa State Univ., Ames, IA (United States)
Publication Date:
Research Org.:
Ames Laboratory (AMES), Ames, IA (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1477202
Alternate Identifier(s):
OSTI ID: 1475079
Report Number(s):
IS-J-9760
Journal ID: ISSN 1359-7345; CHCOFS
Grant/Contract Number:  
AC02-07CH11358; Laboratory Directed Research and Development (LDRD) program
Resource Type:
Journal Article: Accepted Manuscript
Journal Name:
ChemComm
Additional Journal Information:
Journal Name: ChemComm; Journal ID: ISSN 1359-7345
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE

Citation Formats

Hlova, Ihor Z., Dolotko, Oleksandr, Boote, Brett W., Pathak, Arjun K., Smith, Emily A., Pecharsky, Vitalij K., and Balema, Viktor P.. Multi-principal element transition metal dichalcogenides via reactive fusion of 3D-heterostructures. United States: N. p., 2018. Web. doi:10.1039/C8CC06766J.
Hlova, Ihor Z., Dolotko, Oleksandr, Boote, Brett W., Pathak, Arjun K., Smith, Emily A., Pecharsky, Vitalij K., & Balema, Viktor P.. Multi-principal element transition metal dichalcogenides via reactive fusion of 3D-heterostructures. United States. doi:10.1039/C8CC06766J.
Hlova, Ihor Z., Dolotko, Oleksandr, Boote, Brett W., Pathak, Arjun K., Smith, Emily A., Pecharsky, Vitalij K., and Balema, Viktor P.. Mon . "Multi-principal element transition metal dichalcogenides via reactive fusion of 3D-heterostructures". United States. doi:10.1039/C8CC06766J.
@article{osti_1477202,
title = {Multi-principal element transition metal dichalcogenides via reactive fusion of 3D-heterostructures},
author = {Hlova, Ihor Z. and Dolotko, Oleksandr and Boote, Brett W. and Pathak, Arjun K. and Smith, Emily A. and Pecharsky, Vitalij K. and Balema, Viktor P.},
abstractNote = {Transition metal dichalcogenides combining multiple principal elements in their structures are synthesized via mechanochemical exfoliation and spontaneous reassembly of binary precursors into 3D-heterostructures that are converted into single-phase layered materials by high-temperature reactive fusion. As a result, physical and chemical events enabling these transformations are summarized in the form of a conceivable reaction mechanism.},
doi = {10.1039/C8CC06766J},
journal = {ChemComm},
number = ,
volume = ,
place = {United States},
year = {Mon Sep 24 00:00:00 EDT 2018},
month = {Mon Sep 24 00:00:00 EDT 2018}
}

Journal Article:
Free Publicly Available Full Text
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Works referenced in this record:

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Van der Waals heterostructures
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Electronics and optoelectronics of two-dimensional transition metal dichalcogenides
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