skip to main content
OSTI.GOV title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Multi-principal element transition metal dichalcogenides via reactive fusion of 3D-heterostructures

Abstract

Transition metal dichalcogenides combining multiple principal elements in their structures are synthesized via mechanochemical exfoliation and spontaneous reassembly of binary precursors into 3D-heterostructures that are converted into single-phase layered materials by high-temperature reactive fusion. As a result, physical and chemical events enabling these transformations are summarized in the form of a conceivable reaction mechanism.

Authors:
 [1];  [1];  [1]; ORCiD logo [1]; ORCiD logo [1]; ORCiD logo [1]; ORCiD logo [1]
  1. Ames Lab. and Iowa State Univ., Ames, IA (United States)
Publication Date:
Research Org.:
Ames Lab., Ames, IA (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1477202
Alternate Identifier(s):
OSTI ID: 1475079
Report Number(s):
IS-J-9760
Journal ID: ISSN 1359-7345
Grant/Contract Number:  
AC02-07CH11358; Laboratory Directed Research and Development (LDRD) program
Resource Type:
Journal Article: Accepted Manuscript
Journal Name:
ChemComm
Additional Journal Information:
Journal Volume: 54; Journal Issue: 89; Journal ID: ISSN 1359-7345
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE

Citation Formats

Hlova, Ihor Z., Dolotko, Oleksandr, Boote, Brett W., Pathak, Arjun K., Smith, Emily A., Pecharsky, Vitalij K., and Balema, Viktor P. Multi-principal element transition metal dichalcogenides via reactive fusion of 3D-heterostructures. United States: N. p., 2018. Web. doi:10.1039/C8CC06766J.
Hlova, Ihor Z., Dolotko, Oleksandr, Boote, Brett W., Pathak, Arjun K., Smith, Emily A., Pecharsky, Vitalij K., & Balema, Viktor P. Multi-principal element transition metal dichalcogenides via reactive fusion of 3D-heterostructures. United States. https://doi.org/10.1039/C8CC06766J
Hlova, Ihor Z., Dolotko, Oleksandr, Boote, Brett W., Pathak, Arjun K., Smith, Emily A., Pecharsky, Vitalij K., and Balema, Viktor P. Mon . "Multi-principal element transition metal dichalcogenides via reactive fusion of 3D-heterostructures". United States. https://doi.org/10.1039/C8CC06766J. https://www.osti.gov/servlets/purl/1477202.
@article{osti_1477202,
title = {Multi-principal element transition metal dichalcogenides via reactive fusion of 3D-heterostructures},
author = {Hlova, Ihor Z. and Dolotko, Oleksandr and Boote, Brett W. and Pathak, Arjun K. and Smith, Emily A. and Pecharsky, Vitalij K. and Balema, Viktor P.},
abstractNote = {Transition metal dichalcogenides combining multiple principal elements in their structures are synthesized via mechanochemical exfoliation and spontaneous reassembly of binary precursors into 3D-heterostructures that are converted into single-phase layered materials by high-temperature reactive fusion. As a result, physical and chemical events enabling these transformations are summarized in the form of a conceivable reaction mechanism.},
doi = {10.1039/C8CC06766J},
url = {https://www.osti.gov/biblio/1477202}, journal = {ChemComm},
issn = {1359-7345},
number = 89,
volume = 54,
place = {United States},
year = {2018},
month = {9}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record

Figures / Tables:

Fig. 1 Fig. 1: (Mo 0.5W 0.5)S 2. (a) XRD patterns and (b) Raman spectra of as-milled and milled then fused equimolar mixtures of MoS 2 and WS 2. Vertical bars in (a) indicate the Bragg peak positions of starting materials. Chart (b) also shows the Raman spectra of MoS 2 andmore » WS 2.« less

Save / Share:

Works referenced in this record:

Mechanical alloying and milling
journal, January 2001


Solid state phase transformations in LiAlH4 during high-energy ball-milling
journal, December 2000


Freestanding van der Waals Heterostructures of Graphene and Transition Metal Dichalcogenides
journal, May 2015


Bandgap-tunable lateral and vertical heterostructures based on monolayer Mo1-x W x S2 alloys
journal, August 2015


Van der Waals heterostructures
journal, July 2013


Electronics and optoelectronics of two-dimensional transition metal dichalcogenides
journal, November 2012


Facile self-assembly of Fe3O4 nanoparticles@WS2 nanosheets: A promising candidate for supercapacitor electrode
journal, October 2016


Facile Synthesis of WS 2 Nanosheets-Carbon Composites Anodes for Sodium and Lithium Ion Batteries
journal, August 2016


Mechanically delaminated few layered MoS2 nanosheets based high performance wire type solid-state symmetric supercapacitors
journal, July 2016


A critical review of high entropy alloys and related concepts
journal, January 2017


Raman study of 2H-Mo1−xWxS2 layered mixed crystals
journal, September 2010


Influence of Milling Media on Mechanically Exfoliated MoS 2
journal, January 2014


Solution-Based Processing of Monodisperse Two-Dimensional Nanomaterials
journal, February 2017


2D materials and van der Waals heterostructures
journal, July 2016


Synthesis and characterization of molybdenum-tungsten mixed sulphoselenide, Mo0.5W0.5S x Se2?x (0 ? x ? 2)
journal, January 1996


Quaternary 2D Transition Metal Dichalcogenides (TMDs) with Tunable Bandgap
journal, July 2017


Distorted MoS2 nanostructures: An efficient catalyst for the electrochemical hydrogen evolution reaction
journal, September 2013


Recent development of two-dimensional transition metal dichalcogenides and their applications
journal, April 2017


Synthetic approaches to two-dimensional transition metal dichalcogenide nanosheets
journal, August 2017


Lateral Built-In Potential of Monolayer MoS 2 -WS 2 In-Plane Heterostructures by a Shortcut Growth Strategy
journal, September 2015


Two Cation Disulfide Layers in the WxMo(1−x)S2 Lamellar Solid Solution
journal, August 2001


Mo x W 1− x S 2 Solid Solutions as 3D Electrodes for Hydrogen Evolution Reaction
journal, April 2015


Centimeter Scale Patterned Growth of Vertically Stacked Few Layer Only 2D MoS2/WS2 van der Waals Heterostructure
journal, May 2016


Electrochemistry of Nanostructured Layered Transition-Metal Dichalcogenides
journal, October 2015


Monolayers of W x Mo 1−x S 2 alloy heterostructure with in-plane composition variations
journal, February 2015


    Figures/Tables have been extracted from DOE-funded journal article accepted manuscripts.