Viscosity and real-space molecular motion of water: Observation with inelastic x-ray scattering

Shinohara, Yuya; Dmowski, Wojciech; Iwashita, Takuya; Wu, Bin; Ishikawa, Daisuke; Baron, Alfred Q.  R.; Egami, Takeshi

doi:10.1103/PhysRevE.98.022604

Title: Viscosity and real-space molecular motion of water: Observation with inelastic x-ray scattering

Journal Article · Fri Aug 10 00:00:00 EDT 2018 · Physical Review E

DOI:https://doi.org/10.1103/PhysRevE.98.022604· OSTI ID:1476425

Shinohara, Yuya ^[1]; Dmowski, Wojciech ^[1]; Iwashita, Takuya ^[2]; Wu, Bin ^[3]; Ishikawa, Daisuke ^[4]; Baron, Alfred Q. R. ^[5]; Egami, Takeshi ^[6]

Univ. of Tennessee, Knoxville, TN (United States)
Oita Univ. (Japan)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
RIKEN, Sayo (Japan); Japan Synchrotron Radiation Research Inst., Sayo (Japan)
RIKEN, Sayo (Japan)
Univ. of Tennessee, Knoxville, TN (United States); Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

Even though viscosity is one of the fundamental properties of liquids, its microscopic origin is not fully understood. We determined the spatial and temporal correlation of molecular motions of water near room temperature and its temperature variation on a picosecond timescale and a subnanometer spatial scale, through high-resolution inelastic x-ray scattering measurement. The results, expressed in terms of the time-dependent pair correlation function called the Van Hove function, show that the timescale of the decay of the molecular correlation is directly related to the Maxwell relaxation time near room temperature, which is proportional to viscosity. This conclusion validates our earlier finding that the topological changes in atomic or molecular connectivity are the origin of viscosity in liquids.

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Research Organization:: Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1476425

Alternate ID(s):: OSTI ID: 1463938

Journal Information:: Physical Review E, Vol. 98, Issue 2; ISSN 2470-0045

Publisher:: American Physical Society (APS)Copyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 18 works

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