Suppression of exciton dephasing in sidewall-functionalized carbon nanotubes embedded into metallo-dielectric antennas
Abstract
Covalent functionalization of single-walled carbon nanotubes (SWCNTs) is a promising route to enhance the quantum yield of exciton emission and can lead to single-photon emission at room temperature.
- Authors:
-
- Stevens Inst. of Technology, Hoboken, NJ (United States)
- Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
- National Renewable Energy Lab. (NREL), Golden, CO (United States)
- Publication Date:
- Research Org.:
- National Renewable Energy Laboratory (NREL), Golden, CO (United States); Los Alamos National Laboratory (LANL), Los Alamos, NM (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1461375
- Alternate Identifier(s):
- OSTI ID: 1457200; OSTI ID: 1475343
- Report Number(s):
- NREL/JA-5K00-71992; LA-UR-18-24661
Journal ID: ISSN 2040-3364; NANOHL
- Grant/Contract Number:
- AC36-08GO28308; LDRD program; AC52-06NA25396
- Resource Type:
- Journal Article: Accepted Manuscript
- Journal Name:
- Nanoscale
- Additional Journal Information:
- Journal Volume: 10; Journal Issue: 26; Journal ID: ISSN 2040-3364
- Publisher:
- Royal Society of Chemistry
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSICS; single-walled carbon nanotubes; quantum yield; exciton emission
Citation Formats
Shayan, Kamran, He, Xiaowei, Luo, Yue, Rabut, Claire, Li, Xiangzhi, Hartmann, Nicolai F., Blackburn, Jeffrey L., Doorn, Stephen K., Htoon, Han, and Strauf, Stefan. Suppression of exciton dephasing in sidewall-functionalized carbon nanotubes embedded into metallo-dielectric antennas. United States: N. p., 2018.
Web. doi:10.1039/C8NR03542C.
Shayan, Kamran, He, Xiaowei, Luo, Yue, Rabut, Claire, Li, Xiangzhi, Hartmann, Nicolai F., Blackburn, Jeffrey L., Doorn, Stephen K., Htoon, Han, & Strauf, Stefan. Suppression of exciton dephasing in sidewall-functionalized carbon nanotubes embedded into metallo-dielectric antennas. United States. https://doi.org/10.1039/C8NR03542C
Shayan, Kamran, He, Xiaowei, Luo, Yue, Rabut, Claire, Li, Xiangzhi, Hartmann, Nicolai F., Blackburn, Jeffrey L., Doorn, Stephen K., Htoon, Han, and Strauf, Stefan. 2018.
"Suppression of exciton dephasing in sidewall-functionalized carbon nanotubes embedded into metallo-dielectric antennas". United States. https://doi.org/10.1039/C8NR03542C. https://www.osti.gov/servlets/purl/1461375.
@article{osti_1461375,
title = {Suppression of exciton dephasing in sidewall-functionalized carbon nanotubes embedded into metallo-dielectric antennas},
author = {Shayan, Kamran and He, Xiaowei and Luo, Yue and Rabut, Claire and Li, Xiangzhi and Hartmann, Nicolai F. and Blackburn, Jeffrey L. and Doorn, Stephen K. and Htoon, Han and Strauf, Stefan},
abstractNote = {Covalent functionalization of single-walled carbon nanotubes (SWCNTs) is a promising route to enhance the quantum yield of exciton emission and can lead to single-photon emission at room temperature.},
doi = {10.1039/C8NR03542C},
url = {https://www.osti.gov/biblio/1461375},
journal = {Nanoscale},
issn = {2040-3364},
number = 26,
volume = 10,
place = {United States},
year = {Mon Jun 04 00:00:00 EDT 2018},
month = {Mon Jun 04 00:00:00 EDT 2018}
}
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Cited by: 3 works
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Figures / Tables:
Fig. 1: Low-temperature PL characterization of individual SWCNTs. (a) Schematic representation of a SWCNT with a 3,5-dichlorobenzene aryl group attached to the sidewall shown enlarged for clarity (upper panel). Level scheme for quasi-resonant pumping of excitons into their excited states via one-phonon absorption processes involving the zone-center optical phonons (lowermore »
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Works referenced in this record:
Suppression of Blinking and Enhanced Exciton Emission from Individual Carbon Nanotubes
journal, March 2011
- Ai, Nan; Walden-Newman, William; Song, Qiang
- ACS Nano, Vol. 5, Issue 4
Excitonic Effects and Optical Spectra of Single-Walled Carbon Nanotubes
journal, February 2004
- Spataru, Catalin D.; Ismail-Beigi, Sohrab; Benedict, Lorin X.
- Physical Review Letters, Vol. 92, Issue 7
Solid-State Approach for Fabrication of Photostable, Oxygen-Doped Carbon Nanotubes
journal, September 2015
- Ma, Xuedan; Baldwin, Jon K. S.; Hartmann, Nicolai F.
- Advanced Functional Materials, Vol. 25, Issue 39
Electronic Structure and Chemical Nature of Oxygen Dopant States in Carbon Nanotubes
journal, October 2014
- Ma, Xuedan; Adamska, Lyudmyla; Yamaguchi, Hisato
- ACS Nano, Vol. 8, Issue 10
Strong Acoustic Phonon Localization in Copolymer-Wrapped Carbon Nanotubes
journal, May 2015
- Sarpkaya, Ibrahim; Ahmadi, Ehsaneh D.; Shepard, Gabriella D.
- ACS Nano, Vol. 9, Issue 6
Brightening of the Lowest Exciton in Carbon Nanotubes via Chemical Functionalization
journal, April 2012
- Kilina, Svetlana; Ramirez, Jessica; Tretiak, Sergei
- Nano Letters, Vol. 12, Issue 5
Photoluminescence Imaging of Suspended Single-Walled Carbon Nanotubes
journal, August 2006
- Lefebvre, Jacques; Austing, David G.; Bond, Jeffery
- Nano Letters, Vol. 6, Issue 8
Purcell-enhanced quantum yield from carbon nanotube excitons coupled to plasmonic nanocavities
journal, November 2017
- Luo, Yue; Ahmadi, Ehsaneh D.; Shayan, Kamran
- Nature Communications, Vol. 8, Issue 1
Widely Tunable Single-Photon Source from a Carbon Nanotube in the Purcell Regime
journal, June 2016
- Jeantet, A.; Chassagneux, Y.; Raynaud, C.
- Physical Review Letters, Vol. 116, Issue 24
A planar dielectric antenna for directional single-photon emission and near-unity collection efficiency
journal, January 2011
- Lee, K. G.; Chen, X. W.; Eghlidi, H.
- Nature Photonics, Vol. 5, Issue 3
Low-Temperature Single Carbon Nanotube Spectroscopy of sp 3 Quantum Defects
journal, September 2017
- He, Xiaowei; Gifford, Brendan J.; Hartmann, Nicolai F.
- ACS Nano, Vol. 11, Issue 11
Room-temperature single-photon generation from solitary dopants of carbon nanotubes
journal, July 2015
- Ma, Xuedan; Hartmann, Nicolai F.; Baldwin, Jon K. S.
- Nature Nanotechnology, Vol. 10, Issue 8
Confirmation of K-Momentum Dark Exciton Vibronic Sidebands Using 13 C-labeled, Highly Enriched (6,5) Single-walled Carbon Nanotubes
journal, February 2012
- Blackburn, Jeffrey L.; Holt, Josh M.; Irurzun, Veronica M.
- Nano Letters, Vol. 12, Issue 3
Oxygen Doping Modifies Near-Infrared Band Gaps in Fluorescent Single-Walled Carbon Nanotubes
journal, November 2010
- Ghosh, S.; Bachilo, S. M.; Simonette, R. A.
- Science, Vol. 330, Issue 6011
Brightening of excitons in carbon nanotubes on dimensionality modification
journal, July 2013
- Miyauchi, Yuhei; Iwamura, Munechiyo; Mouri, Shinichiro
- Nature Photonics, Vol. 7, Issue 9
Quantum Light Signatures and Nanosecond Spectral Diffusion from Cavity-Embedded Carbon Nanotubes
journal, January 2012
- Walden-Newman, William; Sarpkaya, Ibrahim; Strauf, Stefan
- Nano Letters, Vol. 12, Issue 4
Role of Surfactants and Salt in Aqueous Two-Phase Separation of Carbon Nanotubes toward Simple Chirality Isolation
journal, January 2014
- Subbaiyan, Navaneetha K.; Cambré, Sofie; Parra-Vasquez, A. Nicholas G.
- ACS Nano, Vol. 8, Issue 2
Elastic Exciton-Exciton Scattering in Photoexcited Carbon Nanotubes
journal, September 2011
- Nguyen, D. T.; Voisin, C.; Roussignol, Ph.
- Physical Review Letters, Vol. 107, Issue 12
Brightening of carbon nanotube photoluminescence through the incorporation of sp3 defects
journal, July 2013
- Piao, Yanmei; Meany, Brendan; Powell, Lyndsey R.
- Nature Chemistry, Vol. 5, Issue 10
Prolonged spontaneous emission and dephasing of localized excitons in air-bridged carbon nanotubes
journal, July 2013
- Sarpkaya, Ibrahim; Zhang, Zhengyi; Walden-Newman, William
- Nature Communications, Vol. 4, Issue 1
Tunable room-temperature single-photon emission at telecom wavelengths from sp3 defects in carbon nanotubes
journal, July 2017
- He, Xiaowei; Hartmann, Nicolai F.; Ma, Xuedan
- Nature Photonics, Vol. 11, Issue 9
Stepwise Quenching of Exciton Fluorescence in Carbon Nanotubes by Single-Molecule Reactions
journal, June 2007
- Cognet, L.; Tsyboulski, D. A.; Rocha, J. -D. R.
- Science, Vol. 316, Issue 5830
Exciton Localization and Optical Emission in Aryl-Functionalized Carbon Nanotubes
journal, November 2017
- Gifford, Brendan J.; Kilina, Svetlana; Htoon, Han
- The Journal of Physical Chemistry C, Vol. 122, Issue 3
Broadband Light Collection Efficiency Enhancement of Carbon Nanotube Excitons Coupled to Metallo-Dielectric Antenna Arrays
journal, November 2017
- Shayan, Kamran; Rabut, Claire; Kong, Xiaoqing
- ACS Photonics, Vol. 5, Issue 2
Trion-Species-Resolved Quantum Beats in MoSe 2
journal, September 2017
- Shepard, Gabriella D.; Ardelean, Jenny V.; Ajayi, Obafunso A.
- ACS Nano, Vol. 11, Issue 11
Time-Resolved Fluorescence of Carbon Nanotubes and Its Implication for Radiative Lifetimes
journal, April 2004
- Wang, Feng; Dukovic, Gordana; Brus, Louis E.
- Physical Review Letters, Vol. 92, Issue 17
Exploiting One-Dimensional Exciton–Phonon Coupling for Tunable and Efficient Single-Photon Generation with a Carbon Nanotube
journal, June 2017
- Jeantet, A.; Chassagneux, Y.; Claude, T.
- Nano Letters, Vol. 17, Issue 7
Photoluminescence Dynamics of Aryl sp 3 Defect States in Single-Walled Carbon Nanotubes
journal, August 2016
- Hartmann, Nicolai F.; Velizhanin, Kirill A.; Haroz, Erik H.
- ACS Nano, Vol. 10, Issue 9
Highly selective dispersion of single-walled carbon nanotubes using aromatic polymers
journal, September 2007
- Nish, Adrian; Hwang, Jeong-Yuan; Doig, James
- Nature Nanotechnology, Vol. 2, Issue 10, p. 640-646
Strong reduction of exciton-phonon coupling in single-wall carbon nanotubes of high crystalline quality: Insight into broadening mechanisms and exciton localization
journal, March 2015
- Ardizzone, V.; Chassagneux, Y.; Vialla, F.
- Physical Review B, Vol. 91, Issue 12
Unconventional motional narrowing in the optical spectrum of a semiconductor quantum dot
journal, October 2006
- Berthelot, A.; Favero, I.; Cassabois, G.
- Nature Physics, Vol. 2, Issue 11
Spectral diffusion and its influence on the emission linewidths of site-controlled GaN nanowire quantum dots
journal, September 2015
- Holmes, M.; Kako, S.; Choi, K.
- Physical Review B, Vol. 92, Issue 11
Fluorescence Imaging In Vivo at Wavelengths beyond 1500 nm
journal, October 2015
- Diao, Shuo; Blackburn, Jeffrey L.; Hong, Guosong
- Angewandte Chemie, Vol. 127, Issue 49
Unifying the Low-Temperature Photoluminescence Spectra of Carbon Nanotubes: The Role of Acoustic Phonon Confinement
journal, July 2014
- Vialla, F.; Chassagneux, Y.; Ferreira, R.
- Physical Review Letters, Vol. 113, Issue 5
Tuning the driving force for exciton dissociation in single-walled carbon nanotube heterojunctions
journal, April 2016
- Ihly, Rachelle; Mistry, Kevin S.; Ferguson, Andrew J.
- Nature Chemistry, Vol. 8, Issue 6
Photoluminescence imaging of solitary dopant sites in covalently doped single-wall carbon nanotubes
journal, January 2015
- Hartmann, Nicolai F.; Yalcin, Sibel Ebru; Adamska, Lyudmyla
- Nanoscale, Vol. 7, Issue 48
High-Yield Dispersions of Large-Diameter Semiconducting Single-Walled Carbon Nanotubes with Tunable Narrow Chirality Distributions
journal, February 2013
- Mistry, Kevin S.; Larsen, Brian A.; Blackburn, Jeffrey L.
- ACS Nano, Vol. 7, Issue 3, p. 2231-2239
High energetic excitons in carbon nanotubes directly probe charge-carriers
journal, May 2015
- Soavi, Giancarlo; Scotognella, Francesco; Viola, Daniele
- Scientific Reports, Vol. 5, Issue 1
Fluorescence Imaging In Vivo at Wavelengths beyond 1500 nm
journal, October 2015
- Diao, Shuo; Blackburn, Jeffrey L.; Hong, Guosong
- Angewandte Chemie International Edition, Vol. 54, Issue 49
Quantized electronic transitions in electrodeposited copper indium selenide nanocrystalline homojunctions
journal, February 2021
- Menezes, Shalini; Samantilleke, Anura P.; Larson, Bryon W.
- Scientific Reports, Vol. 11, Issue 1
Prolonged spontaneous emission and dephasing of localized excitons in air-bridged carbon nanotubes
text, January 2013
- Sarpkaya, Ibrahim; Zhang, Zhengyi; Walden-Newman, William
- arXiv
Unifying the low-temperature photoluminescence spectra of carbon nanotubes: the role of acoustic phonon confinement
text, January 2014
- Vialla, Fabien; Chassagneux, Yannick; Ferreira, Robson
- arXiv
High energetic excitons in carbon nanotubes directly probe charge-carriers
text, January 2014
- Soavi, Giancarlo; Scotognella, Francesco; Viola, Daniele
- arXiv
Exploiting one-dimensional exciton-phonon coupling for tunable and efficient single-photon generation with a carbon nanotube
text, January 2017
- Jeantet, Adrien; Chassagneux, Yannick; Claude, Théo
- arXiv
Unconventional motional narrowing in the optical spectrum of a semiconductor quantum dot
text, January 2006
- Berthelot, Alice; Favero, Ivan; Cassabois, Guillaume
- arXiv
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Figures/Tables have been extracted from DOE-funded journal article accepted manuscripts.