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Title: Effect of overcharge on Li(Ni0.5Mn0.3Co0.2)O2 cathodes: NMP-soluble binder. II — Chemical changes in the anode

Journal Article · · Journal of Power Sources
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  1. Argonne National Lab. (ANL), Argonne, IL (United States). Chemical Sciences and Engineering Division
  2. Argonne National Lab. (ANL), Argonne, IL (United States). Analytical Chemistry Lab. and Nuclear Engineering Division
  3. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Energy and Transportation Science Division
  4. Sandia National Lab. (SNL-NM), Albuquerque, NM (United States). Power Sources Technology Group
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Cells based on nickel manganese cobalt oxide (NMC)/graphite electrodes, which contained polyvinylidene difluoride (PVDF) binders in the electrodes, were systematically charged to 100, 120, 140, 160, 180, and 250% state of charge (SOC). Characterization of the anodes by inductively-coupled-plasma mass spectrometry (ICP-MS), X-ray photoelectron spectroscopy (XPS), and HPLC showed several extent-of-overcharge-dependent trends. The concentrations (by wt) of nickel, manganese, and cobalt in the negative electrode increased with SOC, but the metals remained in the same ratio as that of the positive. Electrolyte reaction products, such as LiF:LiPO3, increased with overcharge, as expected. Three organic products were found by high-performance liquid chromatography (HPLC). The concentrations of two of them tended to reach a constant ratio. The third was seen at 250% SOC only

Research Organization:
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Argonne National Lab. (ANL), Argonne, IL (United States); Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)
Sponsoring Organization:
USDOE Office of Energy Efficiency and Renewable Energy (EERE), Vehicle Technologies Office (EE-3V); USDOE National Nuclear Security Administration (NNSA)
Grant/Contract Number:
AC05-00OR22725; AC02-06CH11357; NA0003525
OSTI ID:
1437886
Alternate ID(s):
OSTI ID: 1474299; OSTI ID: 1548669
Journal Information:
Journal of Power Sources, Vol. 385, Issue C; ISSN 0378-7753
Publisher:
ElsevierCopyright Statement
Country of Publication:
United States
Language:
English
Citation Metrics:
Cited by: 18 works
Citation information provided by
Web of Science

References (48)

Mass Spectrometry Investigations on Electrolyte Degradation Products for the Development of Nanocomposite Electrodes in Lithium Ion Batteries journal June 2006
Surface Film Formation on LiNi[sub 0.8]Co[sub 0.15]Al[sub 0.05]O[sub 2] Cathodes Using Attenuated Total Reflection IR Spectroscopy journal January 2004
Review of selected electrode–solution interactions which determine the performance of Li and Li ion batteries journal August 2000
The Electrochemical Behavior of Alkali and Alkaline Earth Metals in Nonaqueous Battery Systems—The Solid Electrolyte Interphase Model journal January 1979
Impedance of Lithium Electrodes in a Propylene Carbonate Electrolyte journal January 1987
The state of understanding of the lithium-ion-battery graphite solid electrolyte interphase (SEI) and its relationship to formation cycling journal August 2016
Correlation between surface chemistry, morphology, cycling efficiency and interfacial properties of Li electrodes in solutions containing different Li salts journal January 1994
Morphology and chemical compositions of surface films of lithium deposited on a Ni substrate in nonaqueous electrolytes journal September 1995
Effect of overcharge on Li(Ni0.5Mn0.3Co0.2)O2/graphite lithium ion cells with poly(vinylidene fluoride) binder. III — Chemical changes in the cathode journal May 2018
Study of Electrolyte Components in Li Ion Cells Using Liquid-Liquid Extraction and Gas Chromatography Coupled with Mass Spectrometry journal January 2014
A XANES study of LiVPO4F: a factor analysis approach journal January 2014
Mixture analysis using factor analysis. II: Self-modeling curve resolution journal January 1990
Evolving factor analysis journal January 1991
Evolving factor analysis applied to flow injection analysis data journal June 1989
Calculation of equilibrium constants from multiwavelength spectroscopic data—IIIModel-free analysis of spectrophotometric and ESR titrations journal December 1985
Inner-orbital photoelectron spectroscopy of the alkali metal halides, perchlorates, phosphates, and pyrophosphates journal February 1973
ESCA characterization of heparin-like fluoropolymers obtained by functionalization after grafting induced by swift heavy ion irradiation
  • Dapoz, Sylvie; Betz, Natacha; Guittet, Marie-Jo
  • Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms, Vol. 105, Issue 1-4 https://doi.org/10.1016/0168-583X(95)00823-3
journal November 1995
Electrical and structural studies of lithium fluorophosphate glasses journal March 1995
Ion bombardment-induced decomposition of Li and Ba sulfates and carbonates studied by X-ray photoelectron spectroscopy journal January 1985
X-ray photoelectron spectra of methyllithium and dilithiomethane journal March 1985
Surface Characterization of Electrodes from High Power Lithium-Ion Batteries journal January 2002
The Effect of Vinylene Carbonate Additive on Surface Film Formation on Both Electrodes in Li-Ion Batteries journal January 2009
Reactions of Singly-Reduced Ethylene Carbonate in Lithium Battery Electrolytes: A Molecular Dynamics Simulation Study Using the ReaxFF journal December 2011
Theoretical Investigations on Oxidative Stability of Solvents and Oxidative Decomposition Mechanism of Ethylene Carbonate for Lithium Ion Battery Use journal December 2009
Associations of Lithium Alkyl Dicarbonates through O···Li···O Interactions journal October 2002
Theoretical Insights into the Reductive Decompositions of Propylene Carbonate and Vinylene Carbonate:  Density Functional Theory Studies journal May 2002
Theoretical Studies To Understand Surface Chemistry on Carbon Anodes for Lithium-Ion Batteries:  How Does Vinylene Carbonate Play Its Role as an Electrolyte Additive? journal April 2002
Direct visualization of initial SEI morphology and growth kinetics during lithium deposition by in situ electrochemical transmission electron microscopy journal January 2014
Investigating the solid electrolyte interphase using binder-free graphite electrodes journal January 2008
Identification of Li-Based Electrolyte Degradation Products Through DEI and ESI High-Resolution Mass Spectrometry journal January 2004
Composition, depth profiles and lateral distribution of materials in the SEI built on HOPG-TOF SIMS and XPS studies journal July 2001
Effect of Vinylene Carbonate Additive in Li-Ion Batteries: Comparison of LiCoO[sub 2]∕C, LiFePO[sub 4]∕C, and LiCoO[sub 2]∕Li[sub 4]Ti[sub 5]O[sub 12] Systems journal January 2009
Analysis of Vinylene Carbonate Derived SEI Layers on Graphite Anode journal January 2004
Recent studies on the correlation between surface chemistry, morphology, three-dimensional structures and performance of Li and Li-C intercalation anodes in several important electrolyte systems journal September 1997
A Comparative Study of Synthetic Graphite and Li Electrodes in Electrolyte Solutions Based on Ethylene Carbonate-Dimethyl Carbonate Mixtures journal January 1996
A short review of failure mechanisms of lithium metal and lithiated graphite anodes in liquid electrolyte solutions journal June 2002
Electrode–Electrolyte Interface in Li-Ion Batteries: Current Understanding and New Insights journal October 2015
Liquid Chromatography-Quadruple Time of Flight Mass Spectrometry Analysis of Products in Degraded Lithium-Ion Batteries journal January 2015
Identification and formation mechanism of individual degradation products in lithium-ion batteries studied by liquid chromatography/electrospray ionization mass spectrometry and atmospheric solid analysis probe mass spectrometry: Identification of degradation products in LIBs by LC/ESI-MS and ASAP-MS journal July 2016
Qualitative and quantitative investigation of organophosphates in an electrochemically and thermally treated lithium hexafluorophosphate-based lithium ion battery electrolyte by a developed liquid chromatography-tandem quadrupole mass spectrometry method journal January 2016
Qualitative Investigation of the Decomposition of Organic Solvent Based Lithium Ion Battery Electrolytes with LC-IT-TOF-MS journal October 2016
Overcharge failure investigation of lithium-ion batteries journal October 2015
Correlation between dissolution behavior and electrochemical cycling performance for LiNi1/3Co1/3Mn1/3O2-based cells journal June 2012
Distinct Reaction Characteristics of Electrolyte Additives for High-Voltage Lithium-Ion Batteries: Tris(trimethylsilyl) Phosphite, Borate, and Phosphate journal October 2016
Failure mechanism of layered lithium-rich oxide/graphite cell and its solution by using electrolyte additive journal June 2016
Tunable and Robust Phosphite-Derived Surface Film to Protect Lithium-Rich Cathodes in Lithium-Ion Batteries journal April 2015
Why is tris(trimethylsilyl) phosphite effective as an additive for high-voltage lithium-ion batteries? journal January 2015
Surface Modified Pinecone Shaped Hierarchical Structure Fluorinated Mesocarbon Microbeads for Ultrafast Discharge and Improved Electrochemical Performances journal December 2016

Cited By (2)

Overcharge Cycling Effect on the Surface Layers and Crystalline Structure of LiFePO4 Cathodes of Li-Ion Batteries journal December 2019
Chromatographic Techniques in the Research Area of Lithium Ion Batteries: Current State-of-the-Art journal May 2019

Figures / Tables (8)

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Related Subjects

25 ENERGY STORAGE
36 MATERIALS SCIENCE
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Lithium-ion battery
Overcharge
SEI layer
lithium-ion battery
overcharge