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Title: Role of sterics in phosphine-ligated gold clusters

Abstract

This study examined the solution-phase exchange reactions of triphenylphosphine (PPh 3 ) ligands on Au 8 L 7 2+ (L = PPh 3 ) gold clusters with three different tolyl ligands using electrospray ionization mass spectrometry to provide insight into how steric differences in the phosphines influence the extent of ligand exchange and the stability of the resulting mixed-phosphine clusters.

Authors:
 [1];  [2]; ORCiD logo [3]; ORCiD logo [3]; ORCiD logo [1]
  1. Department of Chemistry, Grinnell College, Grinnell, USA
  2. Department of Chemistry, University of Texas at Austin, Austin, USA
  3. Physical Sciences Division, Pacific Northwest National Laboratory, Richland, USA
Publication Date:
Sponsoring Org.:
USDOE Office of Science (SC), Workforce Development for Teachers and Scientists (WDTS) (SC-27); USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1474188
Resource Type:
Journal Article: Publisher's Accepted Manuscript
Journal Name:
Physical Chemistry Chemical Physics
Additional Journal Information:
Journal Name: Physical Chemistry Chemical Physics; Journal ID: ISSN 1463-9076
Publisher:
Royal Society of Chemistry (RSC)
Country of Publication:
United Kingdom
Language:
English

Citation Formats

Parrish, Katherine A., King, Mary, Ligare, Marshall R., Johnson, Grant E., and Hernández, Heriberto. Role of sterics in phosphine-ligated gold clusters. United Kingdom: N. p., 2019. Web. doi:10.1039/C8CP04961K.
Parrish, Katherine A., King, Mary, Ligare, Marshall R., Johnson, Grant E., & Hernández, Heriberto. Role of sterics in phosphine-ligated gold clusters. United Kingdom. doi:10.1039/C8CP04961K.
Parrish, Katherine A., King, Mary, Ligare, Marshall R., Johnson, Grant E., and Hernández, Heriberto. Tue . "Role of sterics in phosphine-ligated gold clusters". United Kingdom. doi:10.1039/C8CP04961K.
@article{osti_1474188,
title = {Role of sterics in phosphine-ligated gold clusters},
author = {Parrish, Katherine A. and King, Mary and Ligare, Marshall R. and Johnson, Grant E. and Hernández, Heriberto},
abstractNote = {This study examined the solution-phase exchange reactions of triphenylphosphine (PPh 3 ) ligands on Au 8 L 7 2+ (L = PPh 3 ) gold clusters with three different tolyl ligands using electrospray ionization mass spectrometry to provide insight into how steric differences in the phosphines influence the extent of ligand exchange and the stability of the resulting mixed-phosphine clusters.},
doi = {10.1039/C8CP04961K},
journal = {Physical Chemistry Chemical Physics},
number = ,
volume = ,
place = {United Kingdom},
year = {Tue Jan 01 00:00:00 EST 2019},
month = {Tue Jan 01 00:00:00 EST 2019}
}

Journal Article:
Free Publicly Available Full Text
This content will become publicly available on September 20, 2019
Publisher's Accepted Manuscript

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Works referenced in this record:

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