skip to main content
OSTI.GOV title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Sensitized photon upconversion in anthracene-based zirconium metal–organic frameworks

Abstract

Sensitized upconversion is explored in three metal–organic frameworks (MOFs) constructed from the anthracene dicarboxylate (ADC) derivatives and zirconium nodes, 9,10-ADC (9,10-MOF), 2,6-ADC (2,6-MOF) and 1,4-ADC (1,4-MOF). Selective excitation of surface-bound Pd(II) mesoporphyrin IX (PdMP) gives rise to delayed fluorescence (τ = 370 ± 30 ns) from anthracene in the 9,10-MOF. The overall upconversion efficiency of the Pd@9,10-MOF is 0.46 ± 0.05% with a threshold intensity of 104 ± 26 mW cm -2.

Authors:
 [1];  [1];  [1]; ORCiD logo [2];  [2]; ORCiD logo [1]
  1. Virginia Polytechnic Inst. and State Univ. (Virginia Tech), Blacksburg, VA (United States). Dept. of Chemistry and Macromolecules Innovation Inst.
  2. Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source (APS), X-ray Science Division
Publication Date:
Research Org.:
Argonne National Lab. (ANL), Argonne, IL (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1473675
Alternate Identifier(s):
OSTI ID: 1457465
Grant/Contract Number:  
AC02-06CH11357; SC0012446
Resource Type:
Journal Article: Accepted Manuscript
Journal Name:
ChemComm
Additional Journal Information:
Journal Volume: 54; Journal Issue: 56; Journal ID: ISSN 1359-7345
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE

Citation Formats

Rowe, Jennifer M., Zhu, Jie, Soderstrom, Erin M., Xu, Wenqian, Yakovenko, Andrey, and Morris, Amanda J. Sensitized photon upconversion in anthracene-based zirconium metal–organic frameworks. United States: N. p., 2018. Web. doi:10.1039/c8cc01893f.
Rowe, Jennifer M., Zhu, Jie, Soderstrom, Erin M., Xu, Wenqian, Yakovenko, Andrey, & Morris, Amanda J. Sensitized photon upconversion in anthracene-based zirconium metal–organic frameworks. United States. doi:10.1039/c8cc01893f.
Rowe, Jennifer M., Zhu, Jie, Soderstrom, Erin M., Xu, Wenqian, Yakovenko, Andrey, and Morris, Amanda J. Tue . "Sensitized photon upconversion in anthracene-based zirconium metal–organic frameworks". United States. doi:10.1039/c8cc01893f.
@article{osti_1473675,
title = {Sensitized photon upconversion in anthracene-based zirconium metal–organic frameworks},
author = {Rowe, Jennifer M. and Zhu, Jie and Soderstrom, Erin M. and Xu, Wenqian and Yakovenko, Andrey and Morris, Amanda J.},
abstractNote = {Sensitized upconversion is explored in three metal–organic frameworks (MOFs) constructed from the anthracene dicarboxylate (ADC) derivatives and zirconium nodes, 9,10-ADC (9,10-MOF), 2,6-ADC (2,6-MOF) and 1,4-ADC (1,4-MOF). Selective excitation of surface-bound Pd(II) mesoporphyrin IX (PdMP) gives rise to delayed fluorescence (τ = 370 ± 30 ns) from anthracene in the 9,10-MOF. The overall upconversion efficiency of the Pd@9,10-MOF is 0.46 ± 0.05% with a threshold intensity of 104 ± 26 mW cm-2.},
doi = {10.1039/c8cc01893f},
journal = {ChemComm},
number = 56,
volume = 54,
place = {United States},
year = {Tue Jun 19 00:00:00 EDT 2018},
month = {Tue Jun 19 00:00:00 EDT 2018}
}

Journal Article:
Free Publicly Available Full Text
This content will become publicly available on June 19, 2019
Publisher's Version of Record

Save / Share:

Works referenced in this record:

Light-Harvesting Metal�Organic Frameworks (MOFs) Efficient Strut-to-Strut Energy Transfer in Bodipy and Porphyrin-Based MOFs
journal, October 2011

  • Lee, Chang Yeon; Farha, Omar K.; Hong, Bong Jin
  • Journal of the American Chemical Society, Vol. 133, Issue 40, p. 15858-15861
  • DOI: 10.1021/ja206029a

Measurement of photoluminescence quantum yields. Review
journal, April 1971

  • Crosby, Glenn A.; Demas, James N.
  • The Journal of Physical Chemistry, Vol. 75, Issue 8, p. 991-1024
  • DOI: 10.1021/j100678a001