Investigating the photodissociation of H2O2 using frequency modulation laser absorption spectroscopy to monitor radical products

Lockhart, James P. A.; Gross, Eisen C.; Sears, Trevor J.; Hall, Gregory E.

doi:10.1016/j.cplett.2018.09.004

Title: Investigating the photodissociation of H₂O₂ using frequency modulation laser absorption spectroscopy to monitor radical products

Journal Article · Mon Sep 10 00:00:00 EDT 2018 · Chemical Physics Letters

DOI:https://doi.org/10.1016/j.cplett.2018.09.004· OSTI ID:1473654

Lockhart, James P. A. ^[1]; Gross, Eisen C. ^[2]; Sears, Trevor J. ^[3];

^[1]

Brookhaven National Lab. (BNL), Upton, NY (United States). Division of Chemistry
Stony Brook Univ., NY (United States). Department of Chemistry
Brookhaven National Lab. (BNL), Upton, NY (United States). Division of Chemistry; Stony Brook Univ., NY (United States). Department of Chemistry

In this study, the photodissociation of H₂O₂ dilute in argon at 193 nm has been investigated using near infrared frequency modulation laser absorption spectroscopy on selected rotational lines of the OH vibrational overtone bands between 6500 and 7100 cm^-1 to detect the OH and HO₂ radical products with the same laser. Sequential OH and HO₂ time-dependent profiles have been measured at room temperature and total pressures ranging from 3 to 56 Torr. Kinetic analysis gives the product distribution following H₂O₂ photolysis of (82±1) % OH and (18±1)% HO₂ under the present conditions, in excellent agreement with previously reported measurements.

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Research Organization:: Brookhaven National Lab. (BNL), Upton, NY (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Chemical Sciences, Geosciences, and Biosciences Division

Grant/Contract Number:: SC0012704

OSTI ID:: 1473654

Report Number(s):: BNL-209064-2018-JAAM

Journal Information:: Chemical Physics Letters, Vol. 711, Issue C; ISSN 0009-2614

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 2 works

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References (34)

Hydrogen peroxide and organic hydroperoxide in the troposphere: a review Lee, Meehye; Heikes, Brian G.; O'Sullivan, Daniel W. Atmospheric Environment, Vol. 34, Issue 21 https://doi.org/10.1016/S1352-2310(99)00432-X	journal	January 2000
Hydrogen peroxide, organic hydroperoxide, and formaldehyde as primary pollutants from biomass burning Lee, Meehye; Heikes, Brian G.; Jacob, Daniel J. Journal of Geophysical Research: Atmospheres, Vol. 102, Issue D1 https://doi.org/10.1029/96JD01709	journal	January 1997
Photodissociation of H ₂ O ₂ and CH ₃ OOH at 248 nm and 298 K: Quantum yields for OH, O( ³ P ) and H( ² S ) Vaghjiani, Ghanshyam L.; Ravishankara, A. R. The Journal of Chemical Physics, Vol. 92, Issue 2 https://doi.org/10.1063/1.458081	journal	January 1990
Evaluated Kinetic, Photochemical and Heterogeneous Data for Atmospheric Chemistry: Supplement V. IUPAC Subcommittee on Gas Kinetic Data Evaluation for Atmospheric Chemistry Atkinson, R.; Baulch, D. L.; Cox, R. A. Journal of Physical and Chemical Reference Data, Vol. 26, Issue 3 https://doi.org/10.1063/1.556011	journal	May 1997
Chemical kinetics of hydrocarbon ignition in practical combustion systems Westbrook, Charles K. Proceedings of the Combustion Institute, Vol. 28, Issue 2 https://doi.org/10.1016/S0082-0784(00)80554-8	journal	January 2000
Developments in Laboratory Studies of Gas-Phase Reactions for Atmospheric Chemistry with Applications to Isoprene Oxidation and Carbonyl Chemistry Seakins, Paul W.; Blitz, Mark A. Annual Review of Physical Chemistry, Vol. 62, Issue 1 https://doi.org/10.1146/annurev-physchem-032210-102538	journal	May 2011
The Essential Role for Laboratory Studies in Atmospheric Chemistry Burkholder, James B.; Abbatt, Jonathan P. D.; Barnes, Ian Environmental Science & Technology, Vol. 51, Issue 5 https://doi.org/10.1021/acs.est.6b04947	journal	February 2017
Kinetics of elementary reactions in low-temperature autoignition chemistry Zádor, Judit; Taatjes, Craig A.; Fernandes, Ravi X. Progress in Energy and Combustion Science, Vol. 37, Issue 4 https://doi.org/10.1016/j.pecs.2010.06.006	journal	August 2011
Rate coefficients for the reaction of methylglyoxal (CH₃COCHO) with OH and NO₃ and glyoxal (HCO)₂ with NO₃ Talukdar, R. K.; Zhu, L.; Feierabend, K. J. Atmospheric Chemistry and Physics, Vol. 11, Issue 21 https://doi.org/10.5194/acp-11-10837-2011	journal	January 2011
Gas Phase Oxidation of Monoethanolamine (MEA) with OH Radical and Ozone: Kinetics, Products, and Particles Borduas, Nadine; Abbatt, Jonathan P. D.; Murphy, Jennifer G. Environmental Science & Technology, Vol. 47, Issue 12 https://doi.org/10.1021/es401282j	journal	May 2013
A Shock Tube Study of OH + H ₂ O ₂ → H ₂ O + HO ₂ and H ₂ O ₂ + M → 2OH + M using Laser Absorption of H ₂ O and OH Hong, Zekai; Cook, Robert D.; Davidson, David F. The Journal of Physical Chemistry A, Vol. 114, Issue 18 https://doi.org/10.1021/jp100204z	journal	May 2010
A shock tube study of the rate constants of HO2 and CH3 reactions Hong, Zekai; Davidson, David Frank; Lam, King-Yiu Combustion and Flame, Vol. 159, Issue 10 https://doi.org/10.1016/j.combustflame.2012.04.009	journal	October 2012
Simultaneous, time-resolved measurements of OH and HO2 radicals by coupling of high repetition rate LIF and cw-CRDS techniques to a laser photolysis reactor and its application to the photolysis of H2O2 Parker, A. E.; Jain, C.; Schoemaecker, C. Applied Physics B, Vol. 103, Issue 3 https://doi.org/10.1007/s00340-010-4225-1	journal	September 2010
Direct measurements of OH and other product yields from the HO₂  + CH₃C(O)O₂ reaction Winiberg, Frank A. F.; Dillon, Terry J.; Orr, Stephanie C. Atmospheric Chemistry and Physics, Vol. 16, Issue 6 https://doi.org/10.5194/acp-16-4023-2016	journal	January 2016
Uncovering the Fundamental Chemistry of Alkyl + O ₂ Reactions via Measurements of Product Formation Taatjes, Craig A. The Journal of Physical Chemistry A, Vol. 110, Issue 13 https://doi.org/10.1021/jp056997f	journal	April 2006
Infrared Frequency-Modulation Probing of Product Formation in Alkyl + O ₂ Reactions: I. The Reaction of C ₂ H ₅ with O ₂ between 295 and 698 K Clifford, Eileen P.; Farrell, John T.; DeSain, John D. The Journal of Physical Chemistry A, Vol. 104, Issue 49 https://doi.org/10.1021/jp0024874	journal	December 2000
Formation of HO2 and OH in photolytically initiated oxidation of dimethyl ether Suzaki, Kotaro; Kanno, Nozomu; Tonokura, Kenichi Chemical Physics Letters, Vol. 425, Issue 4-6 https://doi.org/10.1016/j.cplett.2006.04.116	journal	July 2006
Frequency modulation (FM) spectroscopy: Theory of lineshapes and signal-to-noise analysis Bjorklund, G. C.; Levenson, M. D.; Lenth, W. Applied Physics B Photophysics and Laser Chemistry, Vol. 32, Issue 3 https://doi.org/10.1007/BF00688820	journal	November 1983
T RANSIENT L ASER F REQUENCY M ODULATION S PECTROSCOPY Hall, Gregory E.; North, Simon W. Annual Review of Physical Chemistry, Vol. 51, Issue 1 https://doi.org/10.1146/annurev.physchem.51.1.243	journal	October 2000
CN radical reaction rate measurements by time-resolved FM spectroscopy North, Simon W.; Fei, Ruian; Sears, Trevor J. International Journal of Chemical Kinetics, Vol. 29, Issue 2 https://doi.org/10.1002/(SICI)1097-4601(1997)29:2<127::AID-KIN6>3.0.CO;2-W	journal	January 1997
The near-infrared spectrum of ethynyl radical Le, Anh T.; Hall, Gregory E.; Sears, Trevor J. The Journal of Chemical Physics, Vol. 145, Issue 7 https://doi.org/10.1063/1.4961019	journal	August 2016
Quantum yields for OH production from 193 and 248 nm photolysis of HNO ₃ and H ₂ O ₂ Schiffman, A.; Nelson, D. D.; Nesbitt, D. J. The Journal of Chemical Physics, Vol. 98, Issue 9 https://doi.org/10.1063/1.464735	journal	May 1993
Photodissociation of H ₂ O ₂ at 193 and 222 nm: Products and quantum yields Vaghjiani, Ghanshyam L.; Turnipseed, Andrew A.; Warren, Rachel F. The Journal of Chemical Physics, Vol. 96, Issue 8 https://doi.org/10.1063/1.462684	journal	April 1992
Line strengths of rovibrational and rotational transitions in the $X^{2} Π$ ground state of OH Brooke, James S. A.; Bernath, Peter F.; Western, Colin M. Journal of Quantitative Spectroscopy and Radiative Transfer, Vol. 168 https://doi.org/10.1016/j.jqsrt.2015.07.021	journal	January 2016
Measurements of Line Strengths in the 2ν ₁ Band of the HO ₂ Radical Using Laser Photolysis/Continuous Wave Cavity Ring-Down Spectroscopy (cw-CRDS) Thiebaud, Jérôme; Crunaire, Sabine; Fittschen, Christa The Journal of Physical Chemistry A, Vol. 111, Issue 30 https://doi.org/10.1021/jp0703307	journal	August 2007
Absorption spectrum and absorption cross sections of the 2ν 1 band of HO 2 between 20 and 760 Torr air in the range 6636 and 6639 cm −1 Assaf, Emmanuel; Liu, Lu; Schoemaecker, Coralie Journal of Quantitative Spectroscopy and Radiative Transfer, Vol. 211 https://doi.org/10.1016/j.jqsrt.2018.02.035	journal	May 2018
PGOPHER: A program for simulating rotational, vibrational and electronic spectra Western, Colin M. Journal of Quantitative Spectroscopy and Radiative Transfer, Vol. 186 https://doi.org/10.1016/j.jqsrt.2016.04.010	journal	January 2017
The state distribution of OH radicals photodissociated from H2O2 at 193 and 248 nm Ondrey, G.; van Veen, N.; Bersohn, R. The Journal of Chemical Physics, Vol. 78, Issue 6 https://doi.org/10.1063/1.445148	journal	March 1983
Measurements of ground-state OH rotational energy-transfer rates Kliner, Dahv A. V.; Farrow, Roger L. The Journal of Chemical Physics, Vol. 110, Issue 1 https://doi.org/10.1063/1.478073	journal	January 1999
Evaluated Kinetic Data for Combustion Modelling Baulch, D. L.; Cobos, C. J.; Cox, R. A. Journal of Physical and Chemical Reference Data, Vol. 21, Issue 3 https://doi.org/10.1063/1.555908	journal	May 1992
Kinetic study of the hydrogen abstraction reaction H2O2+H→H2+HO2 by ab initio and density functional theory calculations Tarchouna, Y.; Bahri, M.; Jaïdane, N. Journal of Molecular Structure: THEOCHEM, Vol. 758, Issue 1 https://doi.org/10.1016/j.theochem.2005.10.003	journal	January 2006
Absolute rate constant for the reaction of atomic chlorine with hydrogen peroxide vapor over the temperature range 265–400 K Michael, J. V.; Whytock, D. A.; Lee, J. H. The Journal of Chemical Physics, Vol. 67, Issue 8 https://doi.org/10.1063/1.435351	journal	October 1977
Photofragmentation dynamics of H2O2 at 193 nm Grunewald, Axel Ulrich; Gericke, Karl-Heinz; Comes, Franz Josef Chemical Physics Letters, Vol. 132, Issue 2 https://doi.org/10.1016/0009-2614(86)80092-6	journal	December 1986
Mechanism of the Reaction of OH with Alkynes in the Presence of Oxygen Lockhart, James; Blitz, Mark A.; Heard, Dwayne E. The Journal of Physical Chemistry A, Vol. 117, Issue 26 https://doi.org/10.1021/jp404233b	journal	June 2013

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Title: Investigating the photodissociation of H₂O₂ using frequency modulation laser absorption spectroscopy to monitor radical products