Salt‐Based Organic–Inorganic Nanocomposites: Towards A Stable Lithium Metal/Li 10 GeP 2 S 12 Solid Electrolyte Interface

Gao, Yue; Wang, Daiwei; Li, Yuguang C.; Yu, Zhaoxin; Mallouk, Thomas E.; Wang, Donghai

doi:10.1002/ange.201807304

Title: Salt‐Based Organic–Inorganic Nanocomposites: Towards A Stable Lithium Metal/Li ₁₀ GeP ₂ S ₁₂ Solid Electrolyte Interface

Journal Article · Mon Sep 17 00:00:00 EDT 2018 · Angewandte Chemie

DOI:https://doi.org/10.1002/ange.201807304· OSTI ID:1472148

Gao, Yue ^[1]; Wang, Daiwei ^[2]; Li, Yuguang C. ^[1]; Yu, Zhaoxin ^[2];

^[1];

^[2]

Department of Chemistry The Pennsylvania State University University Park PA 16802 USA
Department of Mechanical and Nuclear Engineering The Pennsylvania State University University Park PA 16802 USA

Abstract Solid‐state Li metal battery technology is attractive, owing to the high energy density, long lifespans, and better safety. A key obstacle in this technology is the unstable Li/solid‐state electrolyte (SSE) interface involving electrolyte reduction by Li. Herein we report a novel approach based on the use of a nanocomposite consisting of organic elastomeric salts (LiO‐(CH ₂ O) _n ‐Li) and inorganic nanoparticle salts (LiF, ‐NSO ₂ ‐Li, Li ₂ O), which serve as an interphase to protect Li ₁₀ GeP ₂ S ₁₂ (LGPS), a highly conductive but reducible SSE. The nanocomposite is formed in situ on Li via the electrochemical decomposition of a liquid electrolyte, thus having excellent chemical and electrochemical stability, affinity for Li and LGPS, and limited interfacial resistance. XPS depth profiling and SEM show that the nanocomposite effectively restrained the reduction of LGPS. Stable Li electrodeposition over 3000 h and a 200 cycle life for a full cell were achieved.

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Sponsoring Organization:: USDOE

Grant/Contract Number:: EE0008198

OSTI ID:: 1472148

Journal Information:: Angewandte Chemie, Journal Name: Angewandte Chemie Vol. 130 Journal Issue: 41; ISSN 0044-8249

Publisher:: Wiley Blackwell (John Wiley & Sons)Copyright Statement

Country of Publication:: Germany

Language:: English

References (39)

Negating interfacial impedance in garnet-based solid-state Li metal batteries Han, Xiaogang; Gong, Yunhui; Fu, Kun (Kelvin) Nature Materials, Vol. 16, Issue 5 https://doi.org/10.1038/nmat4821	journal	December 2016
Review—Practical Challenges Hindering the Development of Solid State Li Ion Batteries Kerman, Kian; Luntz, Alan; Viswanathan, Venkatasubramanian Journal of The Electrochemical Society, Vol. 164, Issue 7 https://doi.org/10.1149/2.1571707jes	journal	January 2017
Challenges for Rechargeable Li Batteries Goodenough, John B.; Kim, Youngsik Chemistry of Materials, Vol. 22, Issue 3, p. 587-603 https://doi.org/10.1021/cm901452z	journal	February 2010
An insight into intrinsic interfacial properties between Li metals and Li ₁₀ GeP ₂ S ₁₂ solid electrolytes Chen, Bingbing; Ju, Jiangwei; Ma, Jun Physical Chemistry Chemical Physics, Vol. 19, Issue 46 https://doi.org/10.1039/C7CP05253G	journal	January 2017
Review—Advances in Anode and Electrolyte Materials for the Progress of Lithium-Ion and beyond Lithium-Ion Batteries Hassoun, Jusef; Scrosati, Bruno Journal of The Electrochemical Society, Vol. 162, Issue 14 https://doi.org/10.1149/2.0191514jes	journal	January 2015
Solid-State Lithium Metal Batteries Promoted by Nanotechnology: Progress and Prospects Xin, Sen; You, Ya; Wang, Shaofei ACS Energy Letters, Vol. 2, Issue 6 https://doi.org/10.1021/acsenergylett.7b00175	journal	May 2017
Interphase formation on lithium solid electrolytes—An in situ approach to study interfacial reactions by photoelectron spectroscopy Wenzel, Sebastian; Leichtweiss, Thomas; Krüger, Dominik Solid State Ionics, Vol. 278 https://doi.org/10.1016/j.ssi.2015.06.001	journal	October 2015
Interfacial Chemistry Regulation via a Skin-Grafting Strategy Enables High-Performance Lithium-Metal Batteries Gao, Yue; Zhao, Yuming; Li, Yuguang C. Journal of the American Chemical Society, Vol. 139, Issue 43 https://doi.org/10.1021/jacs.7b06437	journal	October 2017
A quaternary sodium superionic conductor - Na10.8Sn1.9PS11.8 Yu, Zhaoxin; Shang, Shun-Li; Gao, Yue Nano Energy, Vol. 47 https://doi.org/10.1016/j.nanoen.2018.01.046	journal	May 2018
Interface Limited Lithium Transport in Solid-State Batteries Santhanagopalan, Dhamodaran; Qian, Danna; McGilvray, Thomas The Journal of Physical Chemistry Letters, Vol. 5, Issue 2 https://doi.org/10.1021/jz402467x	journal	December 2013
Interface Re-Engineering of Li ₁₀ GeP ₂ S ₁₂ Electrolyte and Lithium anode for All-Solid-State Lithium Batteries with Ultralong Cycle Life Zhang, Zhihua; Chen, Shaojie; Yang, Jing ACS Applied Materials & Interfaces, Vol. 10, Issue 3 https://doi.org/10.1021/acsami.7b16176	journal	January 2018
Reviving the lithium metal anode for high-energy batteries Lin, Dingchang; Liu, Yayuan; Cui, Yi Nature Nanotechnology, Vol. 12, Issue 3 https://doi.org/10.1038/nnano.2017.16	journal	March 2017
Review of selected electrode–solution interactions which determine the performance of Li and Li ion batteries Aurbach, Doron Journal of Power Sources, Vol. 89, Issue 2 https://doi.org/10.1016/S0378-7753(00)00431-6	journal	August 2000
A lithium superionic conductor Kamaya, Noriaki; Homma, Kenji; Yamakawa, Yuichiro Nature Materials, Vol. 10, Issue 9, p. 682-686 https://doi.org/10.1038/nmat3066	journal	July 2011
Ceramic and polymeric solid electrolytes for lithium-ion batteries Fergus, Jeffrey W. Journal of Power Sources, Vol. 195, Issue 15, p. 4554-4569 https://doi.org/10.1016/j.jpowsour.2010.01.076	journal	August 2010
Direct Observation of the Interfacial Instability of the Fast Ionic Conductor Li ₁₀ GeP ₂ S ₁₂ at the Lithium Metal Anode Wenzel, Sebastian; Randau, Simon; Leichtweiß, Thomas Chemistry of Materials, Vol. 28, Issue 7 https://doi.org/10.1021/acs.chemmater.6b00610	journal	March 2016
Strategies Based on Nitride Materials Chemistry to Stabilize Li Metal Anode Zhu, Yizhou; He, Xingfeng; Mo, Yifei Advanced Science, Vol. 4, Issue 8 https://doi.org/10.1002/advs.201600517	journal	March 2017
Lithium Superionic Conducting Oxysulfide Solid Electrolyte with Excellent Stability against Lithium Metal for All-Solid-State Cells Tao, Yicheng; Chen, Shaojie; Liu, Deng Journal of The Electrochemical Society, Vol. 163, Issue 2 https://doi.org/10.1149/2.0311602jes	journal	November 2015
Inorganic solid Li ion conductors: An overview Knauth, Philippe Solid State Ionics, Vol. 180, Issue 14-16, p. 911-916 https://doi.org/10.1016/j.ssi.2009.03.022	journal	June 2009
Interfacial Challenges in Solid-State Li Ion Batteries Luntz, Alan C.; Voss, Johannes; Reuter, Karsten The Journal of Physical Chemistry Letters, Vol. 6, Issue 22 https://doi.org/10.1021/acs.jpclett.5b02352	journal	October 2015
Comparative Study of TiS 2 /Li-In All-Solid-State Lithium Batteries Using Glass-Ceramic Li 3 PS 4 and Li 10 GeP 2 S 12 Solid Electrolytes Shin, Bum Ryong; Nam, Young Jin; Oh, Dae Yang Electrochimica Acta, Vol. 146 https://doi.org/10.1016/j.electacta.2014.08.139	journal	November 2014
Building better batteries Armand, M.; Tarascon, J.-M. Nature, Vol. 451, Issue 7179, p. 652-657 https://doi.org/10.1038/451652a	journal	February 2008
High-power all-solid-state batteries using sulfide superionic conductors Kato, Yuki; Hori, Satoshi; Saito, Toshiya Nature Energy, Vol. 1, Issue 4 https://doi.org/10.1038/nenergy.2016.30	journal	March 2016
Interfacial reactivity and interphase growth of argyrodite solid electrolytes at lithium metal electrodes Wenzel, Sebastian; Sedlmaier, Stefan J.; Dietrich, Christian Solid State Ionics, Vol. 318 https://doi.org/10.1016/j.ssi.2017.07.005	journal	May 2018
Garnet Electrolyte with an Ultralow Interfacial Resistance for Li-Metal Batteries Li, Yutao; Chen, Xi; Dolocan, Andrei Journal of the American Chemical Society, Vol. 140, Issue 20 https://doi.org/10.1021/jacs.8b03106	journal	April 2018
High-Performance All-Solid-State Lithium-Sulfur Batteries Enabled by Amorphous Sulfur-Coated Reduced Graphene Oxide Cathodes Yao, Xiayin; Huang, Ning; Han, Fudong Advanced Energy Materials, Vol. 7, Issue 17 https://doi.org/10.1002/aenm.201602923	journal	May 2017
Degradation of NASICON-Type Materials in Contact with Lithium Metal: Formation of Mixed Conducting Interphases (MCI) on Solid Electrolytes Hartmann, Pascal; Leichtweiss, Thomas; Busche, Martin R. The Journal of Physical Chemistry C, Vol. 117, Issue 41 https://doi.org/10.1021/jp4051275	journal	October 2013
Interface reactions between LiPON and lithium studied by in-situ X-ray photoemission Schwöbel, André; Hausbrand, René; Jaegermann, Wolfram Solid State Ionics, Vol. 273 https://doi.org/10.1016/j.ssi.2014.10.017	journal	May 2015
Interface Stability in Solid-State Batteries Richards, William D.; Miara, Lincoln J.; Wang, Yan Chemistry of Materials, Vol. 28, Issue 1 https://doi.org/10.1021/acs.chemmater.5b04082	journal	December 2015
Interfacial instability of amorphous LiPON against lithium: A combined Density Functional Theory and spectroscopic study Sicolo, Sabrina; Fingerle, Mathias; Hausbrand, René Journal of Power Sources, Vol. 354 https://doi.org/10.1016/j.jpowsour.2017.04.005	journal	June 2017
Lithium metal anodes for rechargeable batteries Xu, Wu; Wang, Jiulin; Ding, Fei Energy Environ. Sci., Vol. 7, Issue 2 https://doi.org/10.1039/C3EE40795K	journal	January 2014
Electrochemical Stability of Li ₁₀ GeP ₂ S ₁₂ and Li ₇ La ₃ Zr ₂ O ₁₂ Solid Electrolytes Han, Fudong; Zhu, Yizhou; He, Xingfeng Advanced Energy Materials, Vol. 6, Issue 8 https://doi.org/10.1002/aenm.201501590	journal	January 2016
Interfacial Chemistry in Solid-State Batteries: Formation of Interphase and Its Consequences Wang, Shaofei; Xu, Henghui; Li, Wangda Journal of the American Chemical Society, Vol. 140, Issue 1 https://doi.org/10.1021/jacs.7b09531	journal	December 2017
High-capacity thin film lithium batteries with sulfide solid electrolytes Ogawa, Mitsuyasu; Kanda, Ryoko; Yoshida, Kentaro Journal of Power Sources, Vol. 205 https://doi.org/10.1016/j.jpowsour.2012.01.086	journal	May 2012
Mechanism of Lithium Metal Penetration through Inorganic Solid Electrolytes Porz, Lukas; Swamy, Tushar; Sheldon, Brian W. Advanced Energy Materials, Vol. 7, Issue 20 https://doi.org/10.1002/aenm.201701003	journal	July 2017
Inorganic Solid-State Electrolytes for Lithium Batteries: Mechanisms and Properties Governing Ion Conduction Bachman, John Christopher; Muy, Sokseiha; Grimaud, Alexis Chemical Reviews, Vol. 116, Issue 1 https://doi.org/10.1021/acs.chemrev.5b00563	journal	December 2015
Anomalous High Ionic Conductivity of Nanoporous β-Li₃PS₄ Liu, Zengcai; Fu, Wujun; Payzant, E. Andrew Journal of the American Chemical Society, Vol. 135, Issue 3, p. 975-978 https://doi.org/10.1021/ja3110895	journal	January 2013
Plating a Dendrite-Free Lithium Anode with a Polymer/Ceramic/Polymer Sandwich Electrolyte Zhou, Weidong; Wang, Shaofei; Li, Yutao Journal of the American Chemical Society, Vol. 138, Issue 30 https://doi.org/10.1021/jacs.6b05341	journal	July 2016
Germanium Thin Film Protected Lithium Aluminum Germanium Phosphate for Solid-State Li Batteries Liu, Yijie; Li, Chao; Li, Bojie Advanced Energy Materials, Vol. 8, Issue 16 https://doi.org/10.1002/aenm.201702374	journal	February 2018

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