Skip to main content
OSTI.GOVU.S. Department of Energy Office of Scientific and Technical Information
U.S. Department of Energy
Office of Scientific and Technical Information
 

Insight into selectivity: uptake studies of radionuclides 90 Sr 2+ , 137 Cs + , and 233 UO 2 2+ with bis-amidoxime polymers

Journal Article · · Dalton Transactions
DOI:https://doi.org/10.1039/c7dt04935h· OSTI ID:1471584
 [1];  [2];  [2]
  1. Chemical Sciences and Engineering Division; Argonne National Laboratory; Argonne; USA; Department of Chemistry
  2. Chemical Sciences and Engineering Division; Argonne National Laboratory; Argonne; USA
+ Show Author Affiliations

Density functional theory and separation experiments combine to demonstrate the selectivity of bis-amidoxime polymer for uranyl extraction from aqueous solution.

Research Organization:
Argonne National Lab. (ANL), Argonne, IL (United States)
Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
DOE Contract Number:
AC02-06CH11357
OSTI ID:
1471584
Journal Information:
Dalton Transactions, Vol. 47, Issue 15; ISSN 1477-9226
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English

References (53)

Assessment of the “6-31+G** + LANL2DZ” Mixed Basis Set Coupled with Density Functional Theory Methods and the Effective Core Potential: Prediction of Heats of Formation and Ionization Potentials for First-Row-Transition-Metal Complexes September 2009
Tuning Amidoximate to Enhance Uranyl Binding: A Density Functional Theory Study October 2013
Predicting Stability Constants for Uranyl Complexes Using Density Functional Theory March 2015
A theoretical study of uranyl hydroxide monomeric and dimeric complexes October 2001
Functionalized Porous Aromatic Framework for Efficient Uranium Adsorption from Aqueous Solutions March 2017
Metal Salts of 4,5-Dinitro-1,3-imidazole as Colorants in Pyrotechnic Compositions: Metal Salts of 4,5-Dinitro-1,3-imidazole as Colorants in Pyrotechnic Compositions March 2014
Binding Properties of a Polymer Having Amidoxime Groups with Proton and Metal Ions December 1986
A Novel Strontium-Selective Extraction Chromatographic Resin* April 1992
An Amidoximated-UHMEPE Fiber for Selective and High Efficient Removal of Uranyl and Thorium from Acid Aqueous Solution January 2017
Recognition and Extraction of Cesium Hydroxide and Carbonate by Using a Neutral Multitopic Ion-Pair Receptor August 2017
A Planar[15]Metallacrown-5 That Selectively Binds the Uranyl Cation December 1996
A Selectivity Scale for Some Monovalent Cations on Dowex 50 April 1954
Structural clues to UO 2 2+ /VO 2 + competition in seawater extraction using amidoxime-based extractants January 2014
Acidity of the Amidoxime Functional Group in Aqueous Solution: A Combined Experimental and Computational Study February 2015
Highly porous and stable metal–organic frameworks for uranium extraction January 2013
DFT modeling on the suitable crown ether architecture for complexation with Cs+ and Sr2+ metal ions July 2010
Scientific Basis for Efficient Extraction of Uranium from Seawater. I: Understanding the Chemical Speciation of Uranium under Seawater Conditions December 2015
De Novo Structure-Based Design of Bis-amidoxime Uranophiles June 2013
Successful Coupling of a Bis-Amidoxime Uranophile with a Hydrophilic Backbone for Selective Uranium Sequestration August 2017
Materials for the Recovery of Uranium from Seawater June 2017
Examining the Performance of DFT Methods in Uranium Chemistry: Does Core Size Matter for a Pseudopotential? August 2008
Development of Sorbers for the Recovery of Uranium from Seawater. 1. Assessment of Key Parameters and Screening Studies of Sorber Materials August 1982
Quantum Chemistry Study of Uranium(VI), Neptunium(V), and Plutonium(IV,VI) Complexes with Preorganized Tetradentate Phenanthrolineamide Ligands September 2014
Polypropylene Modified with Amidoxime/Carboxyl Groups in Separating Uranium(VI) from Thorium(IV) in Aqueous Solutions December 2016
Complexation of glutarimidedioxime with Fe(iii), Cu(ii), Pb(ii), and Ni(ii), the competing ions for the sequestration of U(vi) from seawater January 2013
Amidoximes as ligand functionalities for braided polymeric materials for the recovery of uranium from seawater April 2016
Chelating polymers and related supports for separation and preconcentration of trace metals May 1990
How Amidoximate Binds the Uranyl Cation February 2012
Advances in Sample Extraction December 2015
Extraction of Lanthanide and Actinide Ions from Aqueous Mixtures Using a Carboxylic Acid-Functionalized Porous Aromatic Framework April 2016
Persistently Folded Circular Aromatic Amide Pentamers Containing Modularly Tunable Cation-Binding Cavities with High Ion Selectivity July 2010
Novel Metal–Organic Framework (MOF) Based Composite Material for the Sequestration of U(VI) and Th(IV) Metal Ions from Aqueous Environment October 2017
Density‐functional thermochemistry. III. The role of exact exchange April 1993
K 2x Sn 4−x S 8−x (x = 0.65–1): a new metal sulfide for rapid and selective removal of Cs + , Sr 2+ and UO 2 2+ ions January 2016
Multiwfn: A multifunctional wavefunction analyzer December 2011
Development of the Colle-Salvetti correlation-energy formula into a functional of the electron density January 1988
A comprehensive study of the complexation of alkali metal cations by lower rim calix[4]arene amide derivatives January 2017
Diphonix® Resin: A Review of Its Properties and Applications January 1997
Highly Porous Acrylonitrile-Based Submicron Particles for UO 2 2+ Absorption in an Immunosensor Assay December 2011
Probing the Nature of Chemical Bonding in Uranyl(VI) Complexes with Quantum Chemical Methods November 2012
Overcoming the crystallization and designability issues in the ultrastable zirconium phosphonate framework system May 2017
Highly Sensitive and Selective Uranium Detection in Natural Water Systems Using a Luminescent Mesoporous Metal–Organic Framework Equipped with Abundant Lewis Basic Sites: A Combined Batch, X-ray Absorption Spectroscopy, and First Principles Simulation Investigation March 2017
Interaction of Cesium Ions with Calix[4]arene-bis( t -octylbenzo-18-crown-6): NMR and Theoretical Study June 2011
Recovery of Uranium from Seawater: A Review of Current Status and Future Research Needs January 2013
Extracting Uranium from Seawater: Promising AI Series Adsorbents November 2015
Acidity of the Poly(acrylamidoxime) Adsorbent in Aqueous Solution: Determination of the Proton Affinity Distribution via Potentiometric Titrations December 2015
Mandelohydroxamic Acid as Ligand for Copper(II) 15-Metallacrown-5 Lanthanide(III) and Copper(II) 15-Metallacrown-5 Uranyl Complexes April 2006
Design and screening of suitable ligand/diluents systems for removal of Sr2+ ion from nuclear waste: Density functional theoretical modelling April 2014
XAFS investigation of polyamidoxime-bound uranyl contests the paradigm from small molecule studies January 2016
Theoretical Investigations of Uranyl−Ligand Bonding:  Four- and Five-Coordinate Uranyl Cyanide, Isocyanide, Carbonyl, and Hydroxide Complexes April 2005
Thorium(IV) and neptunium(V) uptake from carbonate containing aqueous solutions by HDTMA-modified natural zeolites November 2016
From microhydration to bulk hydration of Sr2+ metal ion: DFT, MP2 and molecular dynamics study August 2012
Energies, structures, and electronic properties of molecules in solution with the C-PCM solvation model April 2003

Similar Records

Related Subjects

bis-amidoxime
cooperative binding
radionuclides
separations