Correlation of structural and electrical properties of PrBaCo2O5+δ thin films at high temperature

Mace, Brennan; Harrell, Zach; Xu, Xing; Chen, Chonglin; Enriquez, Erik; Chen, Aiping; Jia, Quanxi

doi:10.1016/j.jmat.2017.12.003

Title: Correlation of structural and electrical properties of PrBaCo2O5+δ thin films at high temperature

Journal Article · Thu Mar 01 00:00:00 EST 2018 · Journal of Materiomics

DOI:https://doi.org/10.1016/j.jmat.2017.12.003· OSTI ID:1633334

Mace, Brennan; Harrell, Zach; Xu, Xing; Chen, Chonglin; Enriquez, Erik; Chen, Aiping; Jia, Quanxi

Epitaxial PrBaCo₂O_5+δ (PBCO, 0 ≤ δ ≤ 1) thin films were deposited by pulsed laser deposition. The structural and electrical properties of the films were characterized at high temperatures in reduced environments. X-ray diffraction scans at high temperature in reduced environment show potential structural transitions of PBCO as evidenced by both a large (Δl = 0.335 nm) expansion of the out-plane (c-axis) lattice, due to thermal and chemical expansion, and a step in the expansion of the c-axis lattice parameter. These transitions indicate the presence of oxygen vacancy ordering as the oxygen content in the films is reduced. Resistivity measurements under the same environments also show evidence of sharp transitions related with the structural transformations. In conclusion, this study helps the understanding of the structure-property relationship of PBCO at high temperature and provides important technological information to utilize these materials for solid oxide fuel cell at intermediate temperatures.

View Journal Article

Cite

Export

Save

Research Organization:: Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

Sponsoring Organization:: USDOE National Nuclear Security Administration (NNSA)

Grant/Contract Number:: G12MD007591; AC52-06NA25396

OSTI ID:: 1633334

Alternate ID(s):: OSTI ID: 1471369

Report Number(s):: LA-UR-18-28581; S2352847817301077; PII: S2352847817301077

Journal Information:: Journal of Materiomics, Journal Name: Journal of Materiomics Vol. 4 Journal Issue: 1; ISSN 2352-8478

Publisher:: ElsevierCopyright Statement

Country of Publication:: China

Language:: English

Citation Metrics:

Cited by: 8 works

Citation information provided by
Web of Science

References (30)

Self-patterned Nano Structures in Structurally Gradient Epitaxial La0.5Ba0.5CoO3 Films He, Jie; Jiang, Jiechao; Liu, Jian Thin Solid Films, Vol. 519, Issue 13 https://doi.org/10.1016/j.tsf.2011.02.015	journal	April 2011
Ultrafast oxygen exchange kinetics on highly epitaxial PrBaCo ₂ O _5+δ thin films Liu, Jian; Collins, Gregory; Liu, Ming Applied Physics Letters, Vol. 100, Issue 19 https://doi.org/10.1063/1.4712123	journal	May 2012
Effect of oxygen content on properties of the ${HoBaCo}_{2} O_{5 + δ}$ layered cobaltite Diaz-Fernandez, Yuri; Malavasi, Lorenzo; Mozzati, Maria Cristina Physical Review B, Vol. 78, Issue 14 https://doi.org/10.1103/PhysRevB.78.144405	journal	October 2008
Structural and Magnetic Studies of Ordered Oxygen-Deficient PerovskitesLnBaCo2O5+δ, Closely Related to the “112” Structure Maignan, A.; Martin, C.; Pelloquin, D. Journal of Solid State Chemistry, Vol. 142, Issue 2 https://doi.org/10.1006/jssc.1998.7934	journal	February 1999
Thermal analysis of rare earth gallates and aluminates O'Bryan, H. M.; Gallagher, P. K.; Berkstresser, G. W. Journal of Materials Research, Vol. 5, Issue 1 https://doi.org/10.1557/JMR.1990.0183	journal	January 1990
Rapid oxygen ion diffusion and surface exchange kinetics in PrBaCo2O5+x with a perovskite related structure and ordered A cations Kim, G.; Wang, S.; Jacobson, A. J. Journal of Materials Chemistry, Vol. 17, Issue 24 https://doi.org/10.1039/b618345j	journal	January 2007
Epitaxial behavior and transport properties of PrBaCo2O5 thin films on (001) SrTiO3 Yuan, Z.; Liu, J.; Chen, C. L. Applied Physics Letters, Vol. 90, Issue 21 https://doi.org/10.1063/1.2741407	journal	May 2007
Structure and magnetism of HoBaCo2O5+ \delta layered cobaltites with Malavasi, Lorenzo; Diaz-Fernandez, Yuri; Cristina Mozzati, M. Solid State Communications, Vol. 148, Issue 3-4 https://doi.org/10.1016/j.ssc.2008.08.006	journal	October 2008
Thickness effects on the magnetic and electrical transport properties of highly epitaxial LaBaCo ₂ O _5.5+δ thin films on MgO substrates Ma, Chunrui; Liu, Ming; Collins, Gregory Applied Physics Letters, Vol. 101, Issue 2 https://doi.org/10.1063/1.4734386	journal	July 2012
Ordered oxygen deficient ‘112’ perovskites, LnBaCo2O5·50+δ : complex magnetism and transport properties Raveau, B.; Motin Seikh, M. D.; Pralong, V. Bulletin of Materials Science, Vol. 32, Issue 3 https://doi.org/10.1007/s12034-009-0044-6	journal	June 2009
Epitaxial Nature and Transport Properties in (LaBa)Co ₂ O _5+δ Thin Films ^† Liu, Jian; Liu, Ming; Collins, Gregory Chemistry of Materials, Vol. 22, Issue 3 https://doi.org/10.1021/cm901479g	journal	February 2010
VESTA 3 for three-dimensional visualization of crystal, volumetric and morphology data Momma, Koichi; Izumi, Fujio Journal of Applied Crystallography, Vol. 44, Issue 6 https://doi.org/10.1107/S0021889811038970	journal	October 2011
Structural and Magnetic Chemistry of NdBaCo2O5+δ Burley, J. C.; Mitchell, J. F.; Short, S. Journal of Solid State Chemistry, Vol. 170, Issue 2 https://doi.org/10.1016/S0022-4596(02)00101-9	journal	February 2003
Ultrafast chemical dynamic behavior in highly epitaxial LaBaCo ₂ O _5+δ thin films Wang, H. B.; Bao, S. Y.; Liu, J. J. Mater. Chem. C, Vol. 2, Issue 28 https://doi.org/10.1039/C4TC00492B	journal	January 2014
Effect of oxygen content on transport and magnetic properties of PrBaCo2O5.50+δ Zhang, Xue; Wang, Xiao-Ming; Wei, Heng-Wei Materials Research Bulletin, Vol. 65 https://doi.org/10.1016/j.materresbull.2015.01.021	journal	May 2015
High-temperature order-disorder transition and polaronic conductivity in ${PrBaCo}_{2} O_{5.48}$ Streule, S.; Podlesnyak, A.; Sheptyakov, D. Physical Review B, Vol. 73, Issue 9 https://doi.org/10.1103/PhysRevB.73.094203	journal	March 2006
Magnetism and vacancy ordering in PrBaCo2O5+δ (δ⩾0.50) Frontera, C.; García-Muñoz, J. L.; Carrillo, A. E. Journal of Applied Physics, Vol. 97, Issue 10 https://doi.org/10.1063/1.1855017	journal	May 2005
High Temperature Crystal Chemistry and Oxygen Permeation Properties of the Mixed Ionic–Electronic Conductors LnBaCo[sub 2]O[sub 5+δ] (Ln=Lanthanide) Kim, J. -H.; Mogni, L.; Prado, F. Journal of The Electrochemical Society, Vol. 156, Issue 12 https://doi.org/10.1149/1.3231501	journal	January 2009
The low-temperature macroscopic phase separation in La0.5Ba0.5CoO3 − δ cobaltite Troyanchuk, I. O.; Karpinsky, D. V.; Bushinsky, M. V. JETP Letters, Vol. 93, Issue 3 https://doi.org/10.1134/S0021364011030167	journal	April 2011
Superfast oxygen exchange kinetics on highly epitaxial LaBaCo ₂ O _5+δ thin films for intermediate temperature solid oxide fuel cells Liu, Jian; Collins, Gregory; Liu, Ming APL Materials, Vol. 1, Issue 3 https://doi.org/10.1063/1.4820363	journal	September 2013
Novel layered perovskite oxide PrBaCuCoO5+δ as a potential cathode for intermediate-temperature solid oxide fuel cells Zhao, Ling; Nian, Qiong; He, Beibei Journal of Power Sources, Vol. 195, Issue 2 https://doi.org/10.1016/j.jpowsour.2009.08.009	journal	January 2010
Structural consideration on the ionic conductivity of perovskite-type oxides Hayashi, H. Solid State Ionics, Vol. 122, Issue 1-4 https://doi.org/10.1016/S0167-2738(99)00066-1	journal	July 1999
Effect of Oxygen Content and Oxygen Vacancy Ordering on the Properties of TbBaCo2O6?? Perovskites Kasper, N. V.; Troyanchuk, I. O.; Khalyavin, D. D. physica status solidi (b), Vol. 215, Issue 1 https://doi.org/10.1002/(SICI)1521-3951(199909)215:1<697::AID-PSSB697>3.0.CO;2-H	journal	September 1999
Step Terrace Tuned Anisotropic Transport Properties of Highly Epitaxial LaBaCo ₂ O _5.5+δ Thin Films on Vicinal SrTiO ₃ Substrates Zou, Q.; Liu, M.; Wang, G. Q. ACS Applied Materials & Interfaces, Vol. 6, Issue 9 https://doi.org/10.1021/am500422j	journal	April 2014
Magnetic and Electrical Transport Properties of LaBaCo ₂ O _5.5+δ Thin Films on Vicinal (001) SrTiO ₃ Surfaces Ma, Chunrui; Liu, Ming; Collins, Gregory ACS Applied Materials & Interfaces, Vol. 5, Issue 2 https://doi.org/10.1021/am302553y	journal	December 2012
Oxygen Vacancy Ordering Phenomena in the Mixed-Conducting Hexagonal Perovskite Ba ₇ Y ₂ Mn ₃ Ti ₂ O ₂₀ Kuang, Xiaojun; Allix, Mathieu; Ibberson, Richard M. Chemistry of Materials, Vol. 19, Issue 11 https://doi.org/10.1021/cm0626740	journal	May 2007
Epitaxial Strain-Induced Chemical Ordering in La _0.5 Sr _0.5 CoO _3−δ Films on SrTiO ₃ Donner, Wolfgang; Chen, Chonglin; Liu, Ming Chemistry of Materials, Vol. 23, Issue 4 https://doi.org/10.1021/cm102657v	journal	February 2011
Atomically layer-by-layer diffusion of oxygen/hydrogen in highly epitaxial PrBaCo2O5.5+δ thin films Bao, Shanyong; Xu, Xing; Enriquez, Erik Applied Physics Letters, Vol. 107, Issue 24 https://doi.org/10.1063/1.4937926	journal	December 2015
Electrical Conductivity and Oxygen Nonstoichiometry of La[sub 0.2]Sr[sub 0.8]Fe[sub 0.55]Ti[sub 0.45]O[sub 3-δ] Park, Chan Young; Jacobson, Allan J. Journal of The Electrochemical Society, Vol. 152, Issue 7 https://doi.org/10.1149/1.1931307	journal	January 2005
Material chemistry of perovskite compounds as chemical sensors Post, M. L.; Tunney, J. J.; Yang, D. Sensors and Actuators B: Chemical, Vol. 59, Issue 2-3 https://doi.org/10.1016/S0925-4005(99)00219-1	journal	October 1999

Similar Records

Oxygen content tailored magnetic and electronic properties in cobaltite double perovskite thin films

Journal Article · Mon Feb 27 00:00:00 EST 2017 · Applied Physics Letters · OSTI ID:1633334

Harrell, Zach John; Enriquez, Erik M.; Chen, Aiping; +5 more

Novel Low Temperature Solid State Fuel Cells

Technical Report · Tue Mar 23 00:00:00 EDT 2010 · OSTI ID:1633334

Chen, Chonglin; Nash, Patrick; Liu, Jian; +1 more

Role of temperature and oxygen content on structural and electrical properties of LaBaCo₂O_5+δ thin films

Journal Article · Mon Feb 12 00:00:00 EST 2018 · Applied Physics Letters · OSTI ID:1633334

Mace, Brennan; Harrell, Zach; Chen, Chonglin; +3 more

Related Subjects

36 MATERIALS SCIENCE
High temperature
Physical properties
Complex oxide
Oxygen vacancy
Lattice structures

Title: Correlation of structural and electrical properties of PrBaCo2O5+δ thin films at high temperature

Citation Formats

References (30)

Similar Records

Related Subjects