Poly(phenylene)-based anion exchange polymers and methods thereof

Kim, Yu Seung; Lee, Kwan-Soo; Fujimoto, Cy

Poly(phenylene)-based anion exchange polymers and methods thereof

Patent · 21 August 2018

OSTI ID:1471226

Kim, Yu Seung; Lee, Kwan-Soo; Fujimoto, Cy

The present invention relates to anionic exchange polymers including a poly(phenylene) structure. The structure can include any useful cationic moiety. Methods and uses of such structures and polymers are also described herein. In one instance, such polymers are employed to form a solid membrane.

View Patent

Research Organization:: Los Alamos National Laboratory (LANL), Los Alamos, NM (United States)

Sponsoring Organization:: USDOE

DOE Contract Number:: AC52-06NA25396; AC04-94AL85000

Assignee:: National Technology & Engineering Solutions of Sandia, LLC (Albuquerque, NM); Los Alamos National Security, LLC (Los Alamos, NM)

Patent Number(s):: 10,053,535

Application Number:: 15/398,547

OSTI ID:: 1471226

Country of Publication:: United States

Language:: English

References (20)

Stable Elastomeric Anion Exchange Membranes Based on Quaternary Ammonium-Tethered Polystyrene-b-poly(ethylene-co-butylene)-b-polystyrene Triblock Copolymers Mohanty, Angela D.; Ryu, Chang Y.; Kim, Yu Seung Macromolecules, Vol. 48, Issue 19, p. 7085-7095 https://doi.org/10.1021/acs.macromol.5b01382	journal	September 2015
Polymer Electrolyte Membranes Derived from New Sulfone Monomers with Pendent Sulfonic Acid Groups Li, Nanwen; Shin, Dong Won; Hwang, Doo Sung Macromolecules, Vol. 43, Issue 23, p. 9810-9820 https://doi.org/10.1021/ma102107a	journal	December 2010
An operationally flexible fuel cell based on quaternary ammonium-biphosphate ion pairs Lee, Kwan-Soo; Spendelow, Jacob S.; Choe, Yoong-Kee Nature Energy, Vol. 1, Issue 9, Article No. 16120 https://doi.org/10.1038/nenergy.2016.120	journal	August 2016
Anion exchange membranes for alkaline fuel cells: A review Merle, Géraldine; Wessling, Matthias; Nijmeijer, Kitty Journal of Membrane Science, Vol. 377, Issue 1-2, p. 1-35 https://doi.org/10.1016/j.memsci.2011.04.043	journal	July 2011
Evaluation of Diels–Alder poly(phenylene) anion exchange membranes in all-vanadium redox flow batteries Sun, Che-Nan; Tang, Zhijiang; Belcher, Cami Electrochemistry Communications, Vol. 43, p. 63-66 https://doi.org/10.1016/j.elecom.2014.03.010	journal	June 2014
Resonance Stabilized Perfluorinated Ionomers for Alkaline Membrane Fuel Cells Kim, Dae Sik; Fujimoto, Cy H.; Hibbs, Michael R. Macromolecules, Vol. 46, Issue 19, p. 7826-7833 https://doi.org/10.1021/ma401568f	journal	September 2013
Synthesis and Characterization of Poly(phenylene)-Based Anion Exchange Membranes for Alkaline Fuel Cells Hibbs, Michael R.; Fujimoto, Cy H.; Cornelius, Christopher J. Macromolecules, Vol. 42, Issue 21, p. 8316-8321 https://doi.org/10.1021/ma901538c	journal	November 2009
Transport in sulfonated poly(phenylene)s: Proton conductivity, permeability, and the state of water Hickner, Michael A.; Fujimoto, Cy H.; Cornelius, Chris J. Polymer, Vol. 47, Issue 11, p. 4238-4244 https://doi.org/10.1016/j.polymer.2006.02.034	journal	May 2006
Backbone stability of quaternized polyaromatics for alkaline membrane fuel cells Fujimoto, Cy; Kim, Dae-Sik; Hibbs, Michael Journal of Membrane Science, Vol. 423-424, p. 438-449 https://doi.org/10.1016/j.memsci.2012.08.045	journal	December 2012
Structurally-Defined, Sulfo-Phenylated, Oligophenylenes and Polyphenylenes Skalski, Thomas J. G.; Britton, Benjamin; Peckham, Timothy J. Journal of the American Chemical Society, Vol. 137, Issue 38, p. 12223-12226 https://doi.org/10.1021/jacs.5b07865	journal	September 2015
Evaluation of hydrogen and methanol fuel cell performance of sulfonated diels alder poly(phenylene) membranes Stanis, Ronald J.; Yaklin, Melissa A.; Cornelius, Chris J. Journal of Power Sources, Vol. 195, Issue 1, p. 104-110 https://doi.org/10.1016/j.jpowsour.2009.06.082	journal	January 2010
Phosphonated and sulfonated polyhphenylsulfone membranes for fuel cell application Parcero, Ethel; Herrera, Rafael; Nunes, Suzana P. Journal of Membrane Science, Vol. 285, Issue 1-2, p. 206-213 https://doi.org/10.1016/j.memsci.2005.12.065	journal	November 2006
Synthesis and properties of sulfonated poly(phenylene sulfone)s without ether linkage by Diels–Alder reaction for PEMFC application Lim, Youngdon; Lee, Hyunchul; Lee, Soonho Electrochimica Acta, Vol. 119, p. 16-23 https://doi.org/10.1016/j.electacta.2013.11.190	journal	February 2014
Carboxylated and Sulfonated Poly(arylene- co -arylene sulfone)s: Thermostable Polyelectrolytes for Fuel Cell Applications Poppe, D.; Frey, H.; Kreuer, K. D. Macromolecules, Vol. 35, Issue 21, p. 7936-7941 https://doi.org/10.1021/ma012198t	journal	September 2002
Vanadium redox flow battery efficiency and durability studies of sulfonated Diels Alder poly(phenylene)s Fujimoto, Cy; Kim, Soowhan; Stains, Ronald Electrochemistry Communications, Vol. 20, p. 48-51 https://doi.org/10.1016/j.elecom.2012.03.037	journal	July 2012
Ionomeric Poly(phenylene) Prepared by Diels−Alder Polymerization: Synthesis and Physical Properties of a Novel Polyelectrolyte Fujimoto, Cy H.; Hickner, Michael A.; Cornelius, Christopher J. Macromolecules, Vol. 38, Issue 12, p. 5010-5016 https://doi.org/10.1021/ma0482720	journal	June 2005
Alkaline stability of poly(phenylene)-based anion exchange membranes with various cations Hibbs, Michael R.; Hickner, Michael A.; Coughlin, E. Bryan Journal of Polymer Science Part B: Polymer Physics, Vol. 51, Issue 24, p. 1736-1742 https://doi.org/10.1002/polb.23149	journal	August 2012
Factors enabling high mobility of protons and water in perfluorosulfonate membranes under low hydration conditions Maalouf, Manale; Sun, Che-Nan; Pyle, Brandon International Journal of Hydrogen Energy, Vol. 39, Issue 6, p. 2795-2800 https://doi.org/10.1016/j.ijhydene.2013.11.006	journal	February 2014
Rhodium(i) complexes with N-heterocyclic carbenes bearing a 2,3,4,5-tetraphenylphenyl and its higher dendritic frameworks Sato, Hiromichi; Fujihara, Tetsuaki; Obora, Yasushi Chemical Communications, Vol. 0, Issue 3, p. 269-271 https://doi.org/10.1039/B612385F	journal	January 2007
Palladium-Catalyzed Phosphonation of Polyphenylsulfone Jakoby, Kai; Peinemann, K. V.; Nunes, Suzana P. Macromolecular Chemistry and Physics, Vol. 204, Issue 1, p. 61-67 https://doi.org/10.1002/macp.200290066	journal	February 2003

Similar Records

Poly(phenylene)-based anion exchange polymers and methods thereof

Patent · 2019 · OSTI ID:1568691

Halo-containing anion exchange membranes and methods thereof

Patent · 2019 · OSTI ID:1568360

High performance, durable polymers including poly(phenylene)

Patent · 2017 · OSTI ID:1345386

Related Subjects

36 MATERIALS SCIENCE
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Poly(phenylene)-based anion exchange polymers and methods thereof

Citation Formats

References (20)

Similar Records

Related Subjects