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Title: Encapsulated sulfur cathodes for rechargeable lithium batteries

Abstract

A method of forming a sulfur-based cathode material includes: 1) providing a sulfur-based nanostructure; 2) coating the nanostructure with an encapsulating material to form a shell surrounding the nanostructure; and 3) removing a portion of the nanostructure through the shell to form a void within the shell, with a remaining portion of the nanostructure disposed within the shell.

Inventors:
; ; ; ;
Publication Date:
Research Org.:
SLAC National Accelerator Lab., Menlo Park, CA (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1470723
Patent Number(s):
10,056,618
Application Number:
15/404,058
Assignee:
The Board of Trustees of the Leland Stanford Junior University (Stanford, CA)
DOE Contract Number:  
AC02-76SF00515
Resource Type:
Patent
Resource Relation:
Patent File Date: 2017 Jan 11
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; 25 ENERGY STORAGE

Citation Formats

Li, Weiyang, Cui, Yi, Seh, Zhi Wei, Zheng, Guangyuan, and Yang, Yuan. Encapsulated sulfur cathodes for rechargeable lithium batteries. United States: N. p., 2018. Web.
Li, Weiyang, Cui, Yi, Seh, Zhi Wei, Zheng, Guangyuan, & Yang, Yuan. Encapsulated sulfur cathodes for rechargeable lithium batteries. United States.
Li, Weiyang, Cui, Yi, Seh, Zhi Wei, Zheng, Guangyuan, and Yang, Yuan. Tue . "Encapsulated sulfur cathodes for rechargeable lithium batteries". United States. https://www.osti.gov/servlets/purl/1470723.
@article{osti_1470723,
title = {Encapsulated sulfur cathodes for rechargeable lithium batteries},
author = {Li, Weiyang and Cui, Yi and Seh, Zhi Wei and Zheng, Guangyuan and Yang, Yuan},
abstractNote = {A method of forming a sulfur-based cathode material includes: 1) providing a sulfur-based nanostructure; 2) coating the nanostructure with an encapsulating material to form a shell surrounding the nanostructure; and 3) removing a portion of the nanostructure through the shell to form a void within the shell, with a remaining portion of the nanostructure disposed within the shell.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2018},
month = {8}
}

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Works referenced in this record:

Electrochemical Cell
patent-application, July 2011


Nanostructured materials for advanced energy conversion and storage devices
journal, May 2005

  • Aricò, Antonino Salvatore; Bruce, Peter; Scrosati, Bruno
  • Nature Materials, Vol. 4, Issue 5, p. 366-377
  • DOI: 10.1038/nmat1368

On the Surface Chemical Aspects of Very High Energy Density, Rechargeable Li–Sulfur Batteries
journal, January 2009

  • Aurbach, Doron; Pollak, Elad; Elazari, Ran
  • Journal of The Electrochemical Society, Vol. 156, Issue 8, p. A694-A702
  • DOI: 10.1149/1.3148721

New insights into the limiting parameters of the Li/S rechargeable cell
journal, February 2012


Li–O2 and Li–S batteries with high energy storage
journal, January 2012

  • Bruce, Peter G.; Freunberger, Stefan A.; Hardwick, Laurence J.
  • Nature Materials, Vol. 11, Issue 1, p. 19-29
  • DOI: 10.1038/nmat3191

High-performance lithium battery anodes using silicon nanowires
book, October 2010

  • Chan, Candace K.; Peng, Hailin; Liu, Gao
  • Materials for Sustainable Energy: A Collection of Peer-Reviewed Research and Review Articles from Nature Publishing Group, p. 187-191
  • DOI: 10.1142/9789814317665_0026

Role of surface coating on cathode materials for lithium-ion batteries
journal, January 2010

  • Chen, Zonghai; Qin, Yan; Amine, Khalil
  • Journal of Materials Chemistry, Vol. 20, Issue 36, p. 7606-7612
  • DOI: 10.1039/c0jm00154f

Electronically conductive phospho-olivines as lithium storage electrodes
journal, September 2002

  • Chung, Sung-Yoon; Bloking, Jason T.; Chiang, Yet-Ming
  • Nature Materials, Vol. 1, Issue 2, p. 123-128
  • DOI: 10.1038/nmat732

Green energy storage materials: Nanostructured TiO2 and Sn-based anodes for lithium-ion batteries
journal, January 2009

  • Deng, Da; Kim, Min Gyu; Lee, Jim Yang
  • Energy & Environmental Science, Vol. 2, Issue 8, p. 818-837
  • DOI: 10.1039/b823474d

Analysis of Polysulfide Dissolved in Electrolyte in Discharge-Charge Process of Li-S Battery
journal, January 2012

  • Diao, Yan; Xie, Kai; Xiong, Shizhao
  • Journal of The Electrochemical Society, Vol. 159, Issue 4, p. A421-A425
  • DOI: 10.1149/2.060204jes

Sulfur-Impregnated Activated Carbon Fiber Cloth as a Binder-Free Cathode for Rechargeable Li-S Batteries
journal, November 2011

  • Elazari, Ran; Salitra, Gregory; Garsuch, Arnd
  • Advanced Materials, Vol. 23, Issue 47, p. 5641-5644
  • DOI: 10.1002/adma.201103274

Core-shell structured sulfur-polypyrrole composite cathodes for lithium-sulfur batteries
journal, January 2012

  • Fu, Yongzhu; Manthiram, Arumugam
  • RSC Advances, Vol. 2, Issue 14, p. 5927-5929
  • DOI: 10.1039/c2ra20393f

Challenges for Rechargeable Li Batteries
journal, February 2010

  • Goodenough, John B.; Kim, Youngsik
  • Chemistry of Materials, Vol. 22, Issue 3, p. 587-603
  • DOI: 10.1021/cm901452z

Sulfur-Impregnated Disordered Carbon Nanotubes Cathode for Lithium–Sulfur Batteries
journal, October 2011

  • Guo, Juchen; Xu, Yunhua; Wang, Chunsheng
  • Nano Letters, Vol. 11, Issue 10, p. 4288-4294
  • DOI: 10.1021/nl202297p

Porous Hollow Carbon@Sulfur Composites for High-Power Lithium-Sulfur Batteries
journal, May 2011

  • Jayaprakash, N.; Shen, J.; Moganty, Surya S.
  • Angewandte Chemie International Edition, Vol. 50, Issue 26, p. 5904-5908
  • DOI: 10.1002/anie.201100637

Porous Hollow Carbon@Sulfur Composites for High-Power Lithium-Sulfur Batteries
journal, May 2011

  • Jayaprakash, N.; Shen, J.; Moganty, Surya S.
  • Angewandte Chemie, Vol. 123, Issue 26, p. 6026-6030
  • DOI: 10.1002/ange.201100637

A highly ordered nanostructured carbon–sulphur cathode for lithium–sulphur batteries
journal, May 2009

  • Ji, Xiulei; Lee, Kyu Tae; Nazar, Linda F.
  • Nature Materials, Vol. 8, Issue 6, p. 500-506
  • DOI: 10.1038/nmat2460

Advances in Li–S batteries
journal, January 2010

  • Ji, Xiulei; Nazar, Linda F.
  • Journal of Materials Chemistry, Vol. 20, Issue 44, p. 9821-9826
  • DOI: 10.1039/b925751a

Graphene Oxide as a Sulfur Immobilizer in High Performance Lithium/Sulfur Cells
journal, November 2011

  • Ji, Liwen; Rao, Mumin; Zheng, Haimei
  • Journal of the American Chemical Society, Vol. 133, Issue 46, p. 18522-18525
  • DOI: 10.1021/ja206955k

Recent developments in nanostructured anode materials for rechargeable lithium-ion batteries
journal, January 2011

  • Ji, Liwen; Lin, Zhan; Alcoutlabi, Mataz
  • Energy & Environmental Science, Vol. 4, Issue 8, p. 2682-2699
  • DOI: 10.1039/c0ee00699h

Stabilizing lithium–sulphur cathodes using polysulphide reservoirs
journal, May 2011

  • Ji, Xiulei; Evers, Scott; Black, Robert
  • Nature Communications, Vol. 2, Article No. 325
  • DOI: 10.1038/ncomms1293

Battery materials for ultrafast charging and discharging
journal, March 2009

  • Kang, Byoungwoo; Ceder, Gerbrand
  • Nature, Vol. 458, Issue 7235, p. 190-193
  • DOI: 10.1038/nature07853

Nano- and bulk-silicon-based insertion anodes for lithium-ion secondary cells
journal, January 2007


Microstructural changes of microemulsion-mediated TiO2 particles during calcination
journal, June 2001


Synthesis and Electrochemical Performance of Sulfur/Highly Porous Carbon Composites
journal, February 2009

  • Lai, C.; Gao, X. P.; Zhang, B.
  • The Journal of Physical Chemistry C, Vol. 113, Issue 11, p. 4712-4716
  • DOI: 10.1021/jp809473e

Fabricating Genetically Engineered High-Power Lithium Ion Batteries Using Multiple Virus Genes
journal, April 2009

  • Lee, Yun Jung; Yi, Hyunjung; Kim, Woo-Jae
  • Science, Vol. 324, Issue 5930, p. 1051-1055
  • DOI: 10.1126/science.1171541

Hollow core–shell structured porous Si–C nanocomposites for Li-ion battery anodes
journal, January 2012

  • Li, Xiaolin; Meduri, Praveen; Chen, Xilin
  • Journal of Materials Chemistry, Vol. 22, Issue 22, p. 11014-11017
  • DOI: 10.1039/c2jm31286g

A nano-structured and highly ordered polypyrrole-sulfur cathode for lithium–sulfur batteries
journal, August 2011


Hierarchically Structured Sulfur/Carbon Nanocomposite Material for High-Energy Lithium Battery
journal, October 2009

  • Liang, Chengdu; Dudney, Nancy J.; Howe, Jane Y.
  • Chemistry of Materials, Vol. 21, Issue 19, p. 4724-4730
  • DOI: 10.1021/cm902050j

High-performance lithium-ion anodes using a hierarchical bottom-up approach
journal, March 2010

  • Magasinski, A.; Dixon, P.; Hertzberg, B.
  • Nature Materials, Vol. 9, Issue 4, p. 353-358
  • DOI: 10.1038/nmat2725

Polysulfide Shuttle Study in the Li/S Battery System
journal, January 2004

  • Mikhaylik, Yuriy V.; Akridge, James R.
  • Journal of The Electrochemical Society, Vol. 151, Issue 11, p. A1969-A1976
  • DOI: 10.1149/1.1806394

Template Synthesis of Polypyrrole‐Coated Spinel LiMn2 O 4 Nanotubules and Their Properties as Cathode Active Materials for Lithium Batteries
journal, January 1997

  • Nishizawa, Matsuhiko; Mukai, Kiyoshi; Kuwabata, Susumu
  • Journal of The Electrochemical Society, Vol. 144, Issue 6, p. 1923-1927
  • DOI: 10.1149/1.1837722

Li-alloy based anode materials for Li secondary batteries
journal, January 2010

  • Park, Cheol-Min; Kim, Jae-Hun; Kim, Hansu
  • Chemical Society Reviews, Vol. 39, Issue 8, p. 3115-3141
  • DOI: 10.1039/b919877f

Silicon Nanotube Battery Anodes
journal, November 2009

  • Park, Mi-Hee; Kim, Min Gyu; Joo, Jaebum
  • Nano Letters, Vol. 9, Issue 11, p. 3844-3847
  • DOI: 10.1021/nl902058c

Electrolytes for high-energy lithium batteries
journal, December 2011

  • Schaefer, Jennifer L.; Lu, Yingying; Moganty, Surya S.
  • Applied Nanoscience, Vol. 2, Issue 2, p. 91-109
  • DOI: 10.1007/s13204-011-0044-x

Spherical Ordered Mesoporous Carbon Nanoparticles with High Porosity for Lithium-Sulfur Batteries
journal, March 2012

  • Schuster, Jörg; He, Guang; Mandlmeier, Benjamin
  • Angewandte Chemie International Edition, Vol. 51, Issue 15, p. 3591-3595
  • DOI: 10.1002/anie.201107817

Li ion battery materials with core–shell nanostructures
journal, January 2011

  • Su, Liwei; Jing, Yu; Zhou, Zhen
  • Nanoscale, Vol. 3, Issue 10, p. 3967-3983
  • DOI: 10.1039/c1nr10550g

A Novel Conductive Polymer-Sulfur Composite Cathode Material for Rechargeable Lithium Batteries
journal, July 2002


Graphene-Wrapped Sulfur Particles as a Rechargeable Lithium–Sulfur Battery Cathode Material with High Capacity and Cycling Stability
journal, July 2011

  • Wang, Hailiang; Yang, Yuan; Liang, Yongye
  • Nano Letters, Vol. 11, Issue 7, p. 2644-2647
  • DOI: 10.1021/nl200658a

Lithium Batteries and Cathode Materials
journal, October 2004

  • Whittingham, M. Stanley
  • Chemical Reviews, Vol. 104, Issue 10, p. 4271-4302
  • DOI: 10.1021/cr020731c

Sulfur/Polythiophene with a Core/Shell Structure: Synthesis and Electrochemical Properties of the Cathode for Rechargeable Lithium Batteries
journal, March 2011

  • Wu, Feng; Chen, Junzheng; Chen, Renjie
  • The Journal of Physical Chemistry C, Vol. 115, Issue 13, p. 6057-6063
  • DOI: 10.1021/jp1114724

A Soft Approach to Encapsulate Sulfur: Polyaniline Nanotubes for Lithium-Sulfur Batteries with Long Cycle Life
journal, January 2012

  • Xiao, Lifen; Cao, Yuliang; Xiao, Jie
  • Advanced Materials, Vol. 24, Issue 9, p. 1176-1181
  • DOI: 10.1002/adma.201103392

Lithium Sulfur Battery: Oxidation/Reduction Mechanisms of Polysulfides in THF Solutions
journal, January 1988

  • Yamin, H.; Gorenshtein, A.; Penciner, J.
  • Journal of The Electrochemical Society, Vol. 135, Issue 5, p. 1045-1048
  • DOI: 10.1149/1.2095868

Improving the Performance of Lithium–Sulfur Batteries by Conductive Polymer Coating
journal, October 2011

  • Yang, Yuan; Yu, Guihua; Cha, Judy J.
  • ACS Nano, Vol. 5, Issue 11, p. 9187-9193
  • DOI: 10.1021/nn203436j

Nanostructures and lithium electrochemical reactivity of lithium titanites and titanium oxides: A review
journal, July 2009


New Nanostructured Li2S/Silicon Rechargeable Battery with High Specific Energy
journal, April 2010

  • Yang, Yuan; McDowell, Matthew T.; Jackson, Ariel
  • Nano Letters, Vol. 10, Issue 4, p. 1486-1491
  • DOI: 10.1021/nl100504q

Towards systems materials engineering
journal, July 2012

  • Yang, Peidong; Tarascon, Jean-Marie
  • Nature Materials, Vol. 11, Issue 7, p. 560-563
  • DOI: 10.1038/nmat3367

Interconnected Silicon Hollow Nanospheres for Lithium-Ion Battery Anodes with Long Cycle Life
journal, July 2011

  • Yao, Yan; McDowell, Matthew T.; Ryu, Ill
  • Nano Letters, Vol. 11, Issue 7, p. 2949-2954
  • DOI: 10.1021/nl201470j

Improvement of cycle property of sulfur-coated multi-walled carbon nanotubes composite cathode for lithium/sulfur batteries
journal, April 2009


Amorphous Microporous Titania Modified with Platinum(IV) ChlorideA New Type of Hybrid Photocatalyst for Visible Light Detoxification
journal, December 1998

  • Zang, Ling; Lange, Christian; Abraham, Ingo
  • The Journal of Physical Chemistry B, Vol. 102, Issue 52, p. 10765-10771
  • DOI: 10.1021/jp981755j

Hollow Carbon Nanofiber-Encapsulated Sulfur Cathodes for High Specific Capacity Rechargeable Lithium Batteries
journal, October 2011

  • Zheng, Guangyuan; Yang, Yuan; Cha, Judy J.
  • Nano Letters, Vol. 11, Issue 10, p. 4462-4467
  • DOI: 10.1021/nl2027684

Novel nanosized adsorbing sulfur composite cathode materials for the advanced secondary lithium batteries
journal, January 2006