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KVOPO4: A New High Capacity Multielectron Na-Ion Battery Cathode

Journal Article · · Advanced Energy Materials
 [1];  [2];  [3];  [1];  [1];  [1];  [2];  [4];  [1];  [1];  [4];  [1];  [2];  [1]
  1. NECCES, Binghamton University, Binghamton NY 13902 USA
  2. Department of NanoEngineering, University of California San Diego, 9500 Gilman Drive # 0448 La Jolla CA 92093 USA
  3. Spallation Neutron Source, Oak Ridge National Laboratory, Oak Ridge TN 37831 USA
  4. X-ray Science Division, Advanced Photon Source, Argonne National Laboratory, Argonne IL 60439 USA

Research Organization:
Energy Frontier Research Centers (EFRC) (United States). Northeastern Center for Chemical Energy Storage (NECCES)
Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
DOE Contract Number:
SC0001294
OSTI ID:
1470548
Journal Information:
Advanced Energy Materials, Vol. 8, Issue 21; Related Information: NECCES partners with Stony Brook University (lead); Argonne National Laboratory; Binghamton University; Brookhaven National University; University of California, San Diego; University of Cambridge, UK; Lawrence Berkeley National Laboratory; Massachusetts Institute of Technology; University of Michigan; Rutgers University; ISSN 1614-6832
Publisher:
Wiley
Country of Publication:
United States
Language:
English

References (54)

Electrochemical investigation of the P2–NaxCoO2 phase diagram journal December 2010
Fast Na+-ion transport in skeleton structures journal February 1976
Lithium Batteries and Cathode Materials journal October 2004
Carbon-Coated Na 3 V 2 (PO 4 ) 3 Embedded in Porous Carbon Matrix: An Ultrafast Na-Storage Cathode with the Potential of Outperforming Li Cathodes journal March 2014
β-NaMnO 2 : A High-Performance Cathode for Sodium-Ion Batteries journal November 2014
The solution of lithium in hexagonal potassium tungsten bronze journal May 1968
Comparison of the polymorphs of VOPO 4 as multi-electron cathodes for rechargeable alkali-ion batteries journal January 2017
Addressing Challenges of Identifying Geometrically Diverse Sets of Crystalline Porous Materials journal December 2011
An Advanced Sodium-Ion Battery Composed of Carbon Coated Na 3 V 2 (PO 4 ) 3 in a Porous Graphene Network journal September 2015
Na 2 FeP 2 O 7 : A Safe Cathode for Rechargeable Sodium-ion Batteries journal August 2013
Voltage, stability and diffusion barrier differences between sodium-ion and lithium-ion intercalation materials journal January 2011
Synthesis, Structure and Electrochemistry of Lithium Vanadium Phosphate Cathode Materials journal January 2011
Study of the Insertion/Deinsertion Mechanism of Sodium into Na 0.44 MnO 2 journal April 2007
A structural study of the hexagonal potassium tungsten bronze, K0.26WO3 journal November 1979
Reversible Sodium Ion Insertion in Single Crystalline Manganese Oxide Nanowires with Long Cycle Life journal June 2011
ε-VOPO[sub 4]: Electrochemical Synthesis and Enhanced Cathode Behavior journal January 2005
Exceptional energy and new insight with a sodium–selenium battery based on a carbon nanosheet cathode and a pseudographite anode journal January 2017
A New High-Energy Cathode for a Na-Ion Battery with Ultrahigh Stability journal September 2013
Electrochemical Behavior of Nanostructured ɛ-VOPO4 over Two Redox Plateaus journal January 2013
Algorithms and tools for high-throughput geometry-based analysis of crystalline porous materials journal February 2012
Electrode Materials for Rechargeable Sodium-Ion Batteries: Potential Alternatives to Current Lithium-Ion Batteries journal May 2012
Ultimate Limits to Intercalation Reactions for Lithium Batteries journal October 2014
Structure of the high voltage phase of layered P2-Na 2/3−z [Mn 1/2 Fe 1/2 ]O 2 and the positive effect of Ni substitution on its stability journal January 2015
Understanding the Structural Evolution and Redox Mechanism of a NaFeO 2 -NaCoO 2 Solid Solution for Sodium-Ion Batteries journal June 2016
A comprehensive review of sodium layered oxides: powerful cathodes for Na-ion batteries journal January 2015
The vanadium monophosphates AVOPO4: Synthesis of a second form β-KVOPO4 and structural relationships in the series journal May 2001
Single-Crystalline Bilayered V 2 O 5 Nanobelts for High-Capacity Sodium-Ion Batteries journal November 2013
Sodium Storage and Transport Properties in Layered Na 2 Ti 3 O 7 for Room-Temperature Sodium-Ion Batteries journal May 2013
Nitrogen-Doping-Induced Defects of a Carbon Coating Layer Facilitate Na-Storage in Electrode Materials journal August 2014
Thermodynamics, Kinetics and Structural Evolution of ε-LiVOPO 4 over Multiple Lithium Intercalation journal February 2016
Microwave-Assisted Solvothermal Synthesis and Characterization of Various Polymorphs of LiVOPO 4 journal April 2013
Li Conductivity in Li[sub x]MPO[sub 4] (M = Mn, Fe, Co, Ni) Olivine Materials journal January 2004
A 3.8-V earth-abundant sodium battery electrode journal July 2014
Thermal Stability and Reactivity of Cathode Materials for Li-Ion Batteries journal March 2016
Molybdenum Substituted Vanadyl Phosphate ε-VOPO 4 with Enhanced Two-Electron Transfer Reversibility and Kinetics for Lithium-Ion Batteries journal April 2016
Preparation and characterization of carbon-coated NaVPO 4 F as cathode material for rechargeable sodium-ion batteries journal February 2014
Electrical Energy Storage and Intercalation Chemistry journal June 1976
KVPO5, an intersecting tunnel structure closely related to the hexagonal tungsten bronze journal June 1991
A 3.4 V Layered VOPO 4 Cathode for Na-Ion Batteries journal January 2016
Chemical and Electrochemical Lithiation of LiVOPO 4 Cathodes for Lithium-Ion Batteries journal June 2014
Carbon-Coated Na 3.32 Fe 2.34 (P 2 O 7 ) 2 Cathode Material for High-Rate and Long-Life Sodium-Ion Batteries journal March 2017
Synthesis and Crystallographic Study of Homeotypic LiVPO 4 F and LiVPO 4 O journal February 2012
β-NaVOPO 4 Obtained by a Low-Temperature Synthesis Process: A New 3.3 V Cathode for Sodium-Ion Batteries journal February 2016
Some transition metal (oxy)phosphates and vanadium oxides for lithium batteries journal January 2005
Sodium-Ion Batteries journal May 2012
P2-type Nax[Fe1/2Mn1/2]O2 made from earth-abundant elements for rechargeable Na batteries journal April 2012
Topochemical Synthesis of Sodium Metal Phosphate Olivines for Sodium-Ion Batteries journal August 2011
Rechargeable Sodium All-Solid-State Battery journal January 2017
Exploration of NaVOPO4 as a cathode for a Na-ion battery journal January 2013
KVPO 4 F and KVOPO 4 toward 4 volt-class potassium-ion batteries journal January 2017
Sodium-Ion Batteries journal June 2018
Lithium Batteries and Cathode Materials journal December 2004
Study of the Insertion/Deinsertion Mechanism of Sodium into Na0.44MnO2. journal July 2007
Molybdenum Substituted Vanadyl Phosphate ε-VOPO 4 with Enhanced Two-Electron Transfer Reversibility and Kinetics for Lithium-Ion Batteries journal July 2015

Cited By (6)

Vanadium‐Based Nanomaterials: A Promising Family for Emerging Metal‐Ion Batteries journal January 2020
Sulfur‐Grafted Hollow Carbon Spheres for Potassium‐Ion Battery Anodes journal June 2019
Metal–Organic Frameworks‐Derived Tunnel Structured Co 3 (PO 4 ) 2 @C as Cathode for New Generation High‐Performance Al‐Ion Batteries journal September 2019
Understanding Challenges of Cathode Materials for Sodium‐Ion Batteries using Synchrotron‐Based X‐Ray Absorption Spectroscopy journal July 2019
A Calcium Organic Salt/rGO composite with Low Solubility and High Conductivity as a Sustainable Anode for Sodium‐Ion Batteries journal July 2019
Emerging polyanionic and organic compounds for high energy density, non-aqueous potassium-ion batteries journal January 2020