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Enhanced charge carrier mobility and lifetime suppress hysteresis and improve efficiency in planar perovskite solar cells

Journal Article · · Energy & Environmental Science
DOI:https://doi.org/10.1039/C7EE02901B· OSTI ID:1470543
 [1];  [2];  [2];  [3];  [4];  [5];  [2];  [6];  [6];  [5];  [2];  [7];  [2];  [8]
  1. École Polytechnique Fédérale de Lausanne; Station 6; CH-1015-Lausanne; Switzerland; Benemérita Universidad Autónoma de Puebla. CIDS
  2. École Polytechnique Fédérale de Lausanne; Station 6; CH-1015-Lausanne; Switzerland
  3. Benemérita Universidad Autónoma de Puebla. CIDS; Av. San Claudio y 18 Sur; Col. San Manuel; Ciudad Universitaria; CP 72570
  4. Instituto de Energías Renovables; Universidad Nacional Autónoma de México; Temixco; Mexico
  5. Massachusetts Institute of Technology; Cambridge; USA
  6. Wesleyan University; Middletown; USA
  7. Young Investigator Group Active Materials and Interfaces for Stable Perovskite Solar Cells; Helmholtz-Zentrum Berlin für Materialien und Energie; Kekuléstrasse 5; 12489 Berlin; Germany
  8. École Polytechnique Fédérale de Lausanne; Station 6; CH-1015-Lausanne; Switzerland; Massachusetts Institute of Technology

Planar perovskite solar cells yield efficiency of over 20%.

Research Organization:
Energy Frontier Research Centers (EFRC) (United States). Center for Excitonics (CE)
Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
DOE Contract Number:
SC0001088
OSTI ID:
1470543
Journal Information:
Energy & Environmental Science, Vol. 11, Issue 1; Related Information: CE partners with Massachusetts Institute of Technology (lead); Brookhaven National Laboratory; Harvard University; ISSN 1754-5692
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English

References (44)

Chemical Management for Colorful, Efficient, and Stable Inorganic–Organic Hybrid Nanostructured Solar Cells March 2013
Stabilizing Perovskite Structures by Tuning Tolerance Factor: Formation of Formamidinium and Cesium Lead Iodide Solid-State Alloys December 2015
Hysteresis and transient behavior in current–voltage measurements of hybrid-perovskite absorber solar cells January 2014
Room-Temperature Formation of Highly Crystalline Multication Perovskites for Efficient, Low-Cost Solar Cells January 2017
Chemical Distribution of Multiple Cation (Rb + , Cs + , MA + , and FA + ) Perovskite Materials by Photoelectron Spectroscopy April 2017
23.6%-efficient monolithic perovskite/silicon tandem solar cells with improved stability February 2017
High-Efficiency Perovskite Solar Cells Based on the Black Polymorph of HC(NH 2 ) 2 PbI 3 June 2014
Efficient, high yield perovskite photovoltaic devices grown by interdiffusion of solution-processed precursor stacking layers January 2014
Inverted Current-Voltage Hysteresis in Mixed Perovskite Solar Cells: Polarization, Energy Barriers, and Defect Recombination July 2016
Sequential deposition as a route to high-performance perovskite-sensitized solar cells July 2013
Organometallic Halide Perovskites: Sharp Optical Absorption Edge and Its Relation to Photovoltaic Performance March 2014
Iodide management in formamidinium-lead-halide–based perovskite layers for efficient solar cells June 2017
Organometal Halide Perovskites as Visible-Light Sensitizers for Photovoltaic Cells May 2009
Cesium-doped methylammonium lead iodide perovskite light absorber for hybrid solar cells July 2014
Chlorobenzene vapor assistant annealing method for fabricating high quality perovskite films July 2016
Structural engineering using rubidium iodide as a dopant under excess lead iodide conditions for high efficiency and stable perovskites December 2016
Grain boundary dominated ion migration in polycrystalline organic–inorganic halide perovskite films January 2016
Understanding the rate-dependent J–V hysteresis, slow time component, and aging in CH 3 NH 3 PbI 3 perovskite solar cells: the role of a compensated electric field January 2015
The rapid evolution of highly efficient perovskite solar cells January 2017
Excitons versus free charges in organo-lead tri-halide perovskites April 2014
Cesium-containing triple cation perovskite solar cells: improved stability, reproducibility and high efficiency January 2016
Formamidinium lead trihalide: a broadly tunable perovskite for efficient planar heterojunction solar cells January 2014
Electron-Hole Diffusion Lengths Exceeding 1 Micrometer in an Organometal Trihalide Perovskite Absorber October 2013
Long-Range Balanced Electron- and Hole-Transport Lengths in Organic-Inorganic CH3NH3PbI3 October 2013
A vacuum flash–assisted solution process for high-efficiency large-area perovskite solar cells June 2016
Enhancing Efficiency of Perovskite Solar Cells via N-doped Graphene: Crystal Modification and Surface Passivation August 2016
Picosecond carrier recombination dynamics in chalcogen-hyperdoped silicon August 2014
Efficient Hybrid Solar Cells Based on Meso-Superstructured Organometal Halide Perovskites October 2012
Ionic Liquid Control Crystal Growth to Enhance Planar Perovskite Solar Cells Efficiency July 2016
Solar cell efficiency tables (version 49): Solar cell efficiency tables (version 49) November 2016
Efficient and stable solution-processed planar perovskite solar cells via contact passivation February 2017
Incorporation of rubidium cations into perovskite solar cells improves photovoltaic performance September 2016
Mixed-Organic-Cation Perovskite Photovoltaics for Enhanced Solar-Light Harvesting February 2014
Lead-free solid-state organic–inorganic halide perovskite solar cells May 2014
Compositional engineering of perovskite materials for high-performance solar cells January 2015
Monolithic perovskite/silicon-heterojunction tandem solar cells processed at low temperature January 2016
Entropic stabilization of mixed A-cation ABX 3 metal halide perovskites for high performance perovskite solar cells January 2016
Formamidinium and Cesium Hybridization for Photo- and Moisture-Stable Perovskite Solar Cell September 2015
Highly efficient and stable planar perovskite solar cells by solution-processed tin oxide January 2016
High-efficiency solution-processed perovskite solar cells with millimeter-scale grains January 2015
Lead Iodide Perovskite Sensitized All-Solid-State Submicron Thin Film Mesoscopic Solar Cell with Efficiency Exceeding 9% August 2012
Unbroken Perovskite: Interplay of Morphology, Electro-optical Properties, and Ionic Movement April 2016
Perovskites: The Emergence of a New Era for Low-Cost, High-Efficiency Solar Cells October 2013
Highly efficient planar perovskite solar cells through band alignment engineering January 2015