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Title: A Spontaneous Structural Transition of {U 24 Pp 12 } Clusters Triggered by Alkali Counterion Replacement in Dilute Solution

Journal Article · · Chemistry - A European Journal
 [1];  [2];  [3];  [1];  [1];  [4]; ORCiD logo [1]
  1. Department of Polymer Science, University of Akron, Akron OH 44325 USA
  2. Department of Chemistry and Biochemistry, University of Notre Dame, Notre Dame IN 46556 USA
  3. Department of Civil and Environmental Engineering and Earth Science, University of Notre Dame, Notre Dame IN 46556 USA
  4. Department of Chemistry and Biochemistry, University of Notre Dame, Notre Dame IN 46556 USA; Department of Civil and Environmental Engineering and Earth Science, University of Notre Dame, Notre Dame IN 46556 USA

Research Organization:
Energy Frontier Research Centers (EFRC) (United States). Materials Science of Actinides (MSA)
Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
DOE Contract Number:
SC0001089
OSTI ID:
1470426
Journal Information:
Chemistry - A European Journal, Vol. 23, Issue 33; Related Information: MSA partners with University of Notre Dame (lead); University of California, Davis; Florida State University; George Washington University; University of Michigan; University of Minnesota; Oak Ridge National Laboratory; Oregon state University; Rensselaer Polytechnic Institute; Savannah River National Laboratory; ISSN 0947-6539
Publisher:
ChemPubSoc Europe
Country of Publication:
United States
Language:
English

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Solution 31 P NMR Study of the Acid-Catalyzed Formation of a Highly Charged {U 24 Pp 12 } Nanocluster, [(UO 2 ) 24 (O 2 ) 24 (P 2 O 7 ) 12 ] 48– , and Its Structural Characterization in the Solid State Using Single-Crystal Neutron Diffraction journal June 2016
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