Hybrid Dion–Jacobson 2D Lead Iodide Perovskites

Mao, Lingling; Ke, Weijun; Pedesseau, Laurent; Wu, Yilei; Katan, Claudine; Even, Jacky; Wasielewski, Michael R.; Stoumpos, Constantinos C.; Kanatzidis, Mercouri G.

doi:10.1021/jacs.8b00542

Title: Hybrid Dion–Jacobson 2D Lead Iodide Perovskites

Journal Article · Wed Feb 21 00:00:00 EST 2018 · Journal of the American Chemical Society

DOI:https://doi.org/10.1021/jacs.8b00542· OSTI ID:1470389

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Northwestern Univ., Evanston, IL (United States). Dept. of Chemistry
Univ. Rennes, Rennes (France); National Centre for Scientific Research (CNRS), Rennes (France)
Northwestern Univ., Evanston, IL (United States). Dept. of Chemistry, and Argonne-Northwestern Solar Energy Research (ANSER) Center

The three-dimensional hybrid organic–inorganic perovskites have shown huge potential for use in solar cells and other optoelectronic devices. Although these materials are under intense investigation, derivative materials with lower dimensionality are emerging, offering higher tunability of physical properties and new capabilities. Here, we present two new series of hybrid two-dimensional (2D) perovskites that adopt the Dion–Jacobson (DJ) structure type, which are the first complete homologous series reported in halide perovskite chemistry. Lead iodide DJ perovskites adopt a general formula A'A_n–1PbnI₃n₊₁ (A' = 3-(aminomethyl)piperidinium (3AMP) or 4-(aminomethyl)piperidinium (4AMP), A = methylammonium (MA)). These materials have layered structures where the stacking of inorganic layers is unique as they lay exactly on top of another. With a slightly different position of the functional group in the templating cation 3AMP and 4AMP, the as-formed DJ perovskites show different optical properties, with the 3AMP series having smaller band gaps than the 4AMP series. Analysis on the crystal structures and density functional theory (DFT) calculations suggest that the origin of the systematic band gap shift is the strong but indirect influence of the organic cation on the inorganic framework. Fabrication of photovoltaic devices utilizing these materials as light absorbers reveals that (3AMP)(MA)₃Pb₄I₁₃ has the best power conversion efficiency (PCE) of 7.32%, which is much higher than that of the corresponding (4AMP)(MA)₃Pb₄I₁₃.

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Research Organization:: Energy Frontier Research Centers (EFRC) (United States). Argonne-Northwestern Solar Energy Research Center (ANSER); Univ. of California, Santa Barbara, CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22). Materials Sciences & Engineering Division

Grant/Contract Number:: SC0001059; SC0012541

OSTI ID:: 1470389

Alternate ID(s):: OSTI ID: 1599733

Journal Information:: Journal of the American Chemical Society, Vol. 140, Issue 10; Related Information: ANSER partners with Northwestern University (lead); Argonne National Laboratory; University of Chicago; University of Illinois, Urbana-Champaign; Yale University; ISSN 0002-7863

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 612 works

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Recent advances in controlling the crystallization of two-dimensional perovskites for optoelectronic device Luo, Shi-Qiang; Wang, Ji-Fei; Yang, Bin Frontiers of Physics, Vol. 14, Issue 5 https://doi.org/10.1007/s11467-019-0901-8	journal	May 2019
Inorganic and Layered Perovskites for Optoelectronic Devices Fakharuddin, Azhar; Shabbir, Umair; Qiu, Weiming Advanced Materials, Vol. 31, Issue 47 https://doi.org/10.1002/adma.201807095	journal	September 2018
Recent Studies on Bifunctional Perovskite Electrocatalysts in Oxygen Evolution, Oxygen Reduction, and Hydrogen Evolution Reactions under Alkaline Electrolyte Ramakrishnan, Prakash; Im, Hyunsik; Baek, Seong‐Ho Israel Journal of Chemistry, Vol. 59, Issue 8 https://doi.org/10.1002/ijch.201900040	journal	May 2019
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Skillfully deflecting the question: a small amount of piperazine-1,4-diium iodide radically enhances the thermal stability of CsPbI ₃ perovskite Wang, Hailiang; Xiang, Sisi; Li, Weiping Journal of Materials Chemistry C, Vol. 7, Issue 38 https://doi.org/10.1039/c9tc03576a	journal	January 2019
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14 SOLAR ENERGY
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
catalysis (homogeneous)
catalysis (heterogeneous)
solar (photovoltaic)
solar (fuels)
photosynthesis (natural and artificial)
bio-inspired
hydrogen and fuel cells
electrodes - solar
defects
charge transport
spin dynamics
membrane
materials and chemistry by design
optics
synthesis (novel materials)
36 MATERIALS SCIENCE

CCDC 1831526: Experimental Crystal Structure Determination Mao, Lingling; Ke, Weijun; Pedesseau, Laurent https://doi.org/10.5517/ccdc.csd.cc1zgvhs The current record is supplemented by this dataset	dataset	January 2018
CCDC 1831523: Experimental Crystal Structure Determination Mao, Lingling; Ke, Weijun; Pedesseau, Laurent https://doi.org/10.5517/ccdc.csd.cc1zgvdp The current record is supplemented by this dataset	dataset	January 2018
CCDC 1831522: Experimental Crystal Structure Determination Mao, Lingling; Ke, Weijun; Pedesseau, Laurent https://doi.org/10.5517/ccdc.csd.cc1zgvcn The current record is supplemented by this dataset	dataset	January 2018
CCDC 1831525: Experimental Crystal Structure Determination Mao, Lingling; Ke, Weijun; Pedesseau, Laurent https://doi.org/10.5517/ccdc.csd.cc1zgvgr The current record is supplemented by this dataset	dataset	January 2018
CCDC 1831528: Experimental Crystal Structure Determination Mao, Lingling; Ke, Weijun; Pedesseau, Laurent https://doi.org/10.5517/ccdc.csd.cc1zgvkv The current record is supplemented by this dataset	dataset	January 2018
CCDC 1831521: Experimental Crystal Structure Determination Mao, Lingling; Ke, Weijun; Pedesseau, Laurent https://doi.org/10.5517/ccdc.csd.cc1zgvbm The current record is supplemented by this dataset	dataset	January 2018
CCDC 1831524: Experimental Crystal Structure Determination Mao, Lingling; Ke, Weijun; Pedesseau, Laurent https://doi.org/10.5517/ccdc.csd.cc1zgvfq The current record is supplemented by this dataset	dataset	January 2018
CCDC 1831527: Experimental Crystal Structure Determination Mao, Lingling; Ke, Weijun; Pedesseau, Laurent https://doi.org/10.5517/ccdc.csd.cc1zgvjt The current record is supplemented by this dataset	dataset	January 2018

Title: Hybrid Dion–Jacobson 2D Lead Iodide Perovskites

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