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Title: Surface Electrolyte Interphase Control on Magnetite, Fe3O4, Electrodes: Impact on Electrochemistry

Abstract

ABSTRACT In battery systems, a solid electrolyte interphase (SEI) is formed through electrolyte reaction on an electrode surface. The formation of SEI can have both positive and negative effects on electrochemistry. The initial formation of the layer protects the electrode from further reactivity, which can improve both shelf and cycle life. However, if the layer continues to form, it can impede charge transfer, which increases cell resistance and limits cycle life. The role of SEI is particularly important when studying conversion electrodes, since phase transformations which unveil new electroactive surfaces during reduction/oxidation can facilitate electrolyte decomposition. This manuscript highlights recent developments in the understanding and control of SEI formation for magnetite (Fe 3O 4) conversion electrodes through electrolyte and electrode modification.

Authors:
; ; ; ; ;
Publication Date:
Research Org.:
Energy Frontier Research Centers (EFRC) (United States). Center for Mesoscale Transport Properties (m2M)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1470272
DOE Contract Number:  
SC0012673
Resource Type:
Journal Article
Journal Name:
MRS Advances
Additional Journal Information:
Journal Volume: 3; Journal Issue: 11; Related Information: m2M partners with Stony Brook University (lead); Brookhaven National Laboratory; Columbia University; Georgia Institute of Technology; Oak Ridge National Laboratory; Rensselaer Polytechnic Institute; University of California, Berkeley; University of North Carolina at Chapel Hill; Journal ID: ISSN 2059-8521
Publisher:
Materials Research Society (MRS)
Country of Publication:
United States
Language:
English
Subject:
energy storage (including batteries and capacitors), charge transport, mesostructured materials

Citation Formats

Housel, Lisa M., Abraham, Alyson, Renderos, Genesis D., Takeuchi, Kenneth J., Takeuchi, Esther S., and Marschilok, Amy C. Surface Electrolyte Interphase Control on Magnetite, Fe3O4, Electrodes: Impact on Electrochemistry. United States: N. p., 2018. Web. doi:10.1557/adv.2018.294.
Housel, Lisa M., Abraham, Alyson, Renderos, Genesis D., Takeuchi, Kenneth J., Takeuchi, Esther S., & Marschilok, Amy C. Surface Electrolyte Interphase Control on Magnetite, Fe3O4, Electrodes: Impact on Electrochemistry. United States. doi:10.1557/adv.2018.294.
Housel, Lisa M., Abraham, Alyson, Renderos, Genesis D., Takeuchi, Kenneth J., Takeuchi, Esther S., and Marschilok, Amy C. Mon . "Surface Electrolyte Interphase Control on Magnetite, Fe3O4, Electrodes: Impact on Electrochemistry". United States. doi:10.1557/adv.2018.294.
@article{osti_1470272,
title = {Surface Electrolyte Interphase Control on Magnetite, Fe3O4, Electrodes: Impact on Electrochemistry},
author = {Housel, Lisa M. and Abraham, Alyson and Renderos, Genesis D. and Takeuchi, Kenneth J. and Takeuchi, Esther S. and Marschilok, Amy C.},
abstractNote = {ABSTRACT In battery systems, a solid electrolyte interphase (SEI) is formed through electrolyte reaction on an electrode surface. The formation of SEI can have both positive and negative effects on electrochemistry. The initial formation of the layer protects the electrode from further reactivity, which can improve both shelf and cycle life. However, if the layer continues to form, it can impede charge transfer, which increases cell resistance and limits cycle life. The role of SEI is particularly important when studying conversion electrodes, since phase transformations which unveil new electroactive surfaces during reduction/oxidation can facilitate electrolyte decomposition. This manuscript highlights recent developments in the understanding and control of SEI formation for magnetite (Fe3O4) conversion electrodes through electrolyte and electrode modification.},
doi = {10.1557/adv.2018.294},
journal = {MRS Advances},
issn = {2059-8521},
number = 11,
volume = 3,
place = {United States},
year = {2018},
month = {1}
}

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