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Title: NiAu Single Atom Alloys for the Non-oxidative Dehydrogenation of Ethanol to Acetaldehyde and Hydrogen

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Publication Date:
Research Org.:
Energy Frontier Research Centers (EFRC) (United States). Integrated Mesoscale Architectures for Sustainable Catalysis (IMASC)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
DOE Contract Number:  
Resource Type:
Journal Article
Journal Name:
Topics in Catalysis
Additional Journal Information:
Journal Volume: 61; Journal Issue: 5-6; Related Information: IMASC partners with Harvard University (lead); Fritz Haber Institute; Lawrence Berkeley National Laboratory; Lawrence Livermore National Laboratory; University of Kansas; Tufts University; Journal ID: ISSN 1022-5528
Country of Publication:
United States
catalysis (heterogeneous), mesostructured materials, materials and chemistry by design, synthesis (novel materials)

Citation Formats

Giannakakis, Georgios, Trimpalis, Antonios, Shan, Junjun, Qi, Zhen, Cao, Sufeng, Liu, Jilei, Ye, Jianchao, Biener, Juergen, and Flytzani-Stephanopoulos, Maria. NiAu Single Atom Alloys for the Non-oxidative Dehydrogenation of Ethanol to Acetaldehyde and Hydrogen. United States: N. p., 2018. Web. doi:10.1007/s11244-017-0883-0.
Giannakakis, Georgios, Trimpalis, Antonios, Shan, Junjun, Qi, Zhen, Cao, Sufeng, Liu, Jilei, Ye, Jianchao, Biener, Juergen, & Flytzani-Stephanopoulos, Maria. NiAu Single Atom Alloys for the Non-oxidative Dehydrogenation of Ethanol to Acetaldehyde and Hydrogen. United States. doi:10.1007/s11244-017-0883-0.
Giannakakis, Georgios, Trimpalis, Antonios, Shan, Junjun, Qi, Zhen, Cao, Sufeng, Liu, Jilei, Ye, Jianchao, Biener, Juergen, and Flytzani-Stephanopoulos, Maria. Mon . "NiAu Single Atom Alloys for the Non-oxidative Dehydrogenation of Ethanol to Acetaldehyde and Hydrogen". United States. doi:10.1007/s11244-017-0883-0.
title = {NiAu Single Atom Alloys for the Non-oxidative Dehydrogenation of Ethanol to Acetaldehyde and Hydrogen},
author = {Giannakakis, Georgios and Trimpalis, Antonios and Shan, Junjun and Qi, Zhen and Cao, Sufeng and Liu, Jilei and Ye, Jianchao and Biener, Juergen and Flytzani-Stephanopoulos, Maria},
abstractNote = {},
doi = {10.1007/s11244-017-0883-0},
journal = {Topics in Catalysis},
issn = {1022-5528},
number = 5-6,
volume = 61,
place = {United States},
year = {2018},
month = {3}

Works referenced in this record:

Supported gold nanoparticles: in-depth catalyst characterization and application in hydrogenation and oxidation reactions
journal, February 2002

Effects of Alkali Metal Oxide Additives on Cu/SiO 2 Catalyst in the Dehydrogenation of Ethanol
journal, December 2001

  • Tu, Yao-Jen; Chen, Yu-Wen
  • Industrial & Engineering Chemistry Research, Vol. 40, Issue 25
  • DOI: 10.1021/ie010272q

Surface energy and work function of elemental metals
journal, September 1992

Heterogeneously catalysed hydrogenation using gold catalysts
journal, September 2005

Characterization of reduced α-alumina-supported nickel catalysts by spectroscopic and chemisorption measurements
journal, July 2005

Tackling CO Poisoning with Single-Atom Alloy Catalysts
journal, May 2016

  • Liu, Jilei; Lucci, Felicia R.; Yang, Ming
  • Journal of the American Chemical Society, Vol. 138, Issue 20
  • DOI: 10.1021/jacs.6b03339

Experimental and Theoretical Studies on the Reaction of H 2 with NiO:  Role of O Vacancies and Mechanism for Oxide Reduction
journal, January 2002

  • Rodriguez, José A.; Hanson, Jonathan C.; Frenkel, Anatoly I.
  • Journal of the American Chemical Society, Vol. 124, Issue 2
  • DOI: 10.1021/ja0121080

Anticipating catalytic oxidation reactions on gold at high pressure (including liquid phase) from ultrahigh vacuum studies
journal, September 2008

Single-Atom Alloy Pd–Ag Catalyst for Selective Hydrogenation of Acrolein
journal, July 2015

  • Aich, Payoli; Wei, Haojuan; Basan, Bridget
  • The Journal of Physical Chemistry C, Vol. 119, Issue 32
  • DOI: 10.1021/acs.jpcc.5b01357

Steam reforming of methanol over ceria and gold-ceria nanoshapes
journal, March 2010

Preparation, Structure, and Surface Chemistry of Ni–Au Single Atom Alloys
journal, June 2016

  • Wang, Zhi-Tao; Darby, Matthew T.; Therrien, Andrew J.
  • The Journal of Physical Chemistry C, Vol. 120, Issue 25
  • DOI: 10.1021/acs.jpcc.6b03473

New insights into reaction mechanisms of ethanol steam reforming on Co–ZrO2
journal, January 2015

Selective hydrogenation of acetylene in excess ethylene using Ag- and Au–Pd/SiO2 bimetallic catalysts prepared by electroless deposition
journal, January 2014

Improved activity and stability in CO oxidation of bimetallic Au–Cu/TiO2 catalysts prepared by deposition–precipitation with urea
journal, August 2013

Characterization of unsupported copper—chromium catalysts for ethanol dehydrogenation
journal, April 1994

Active gold species on cerium oxide nanoshapes for methanol steam reforming and the water gas shift reactions
journal, January 2010

  • Yi, Nan; Si, Rui; Saltsburg, Howard
  • Energy & Environmental Science, Vol. 3, Issue 6
  • DOI: 10.1039/b924051a

Oxidative Dehydrogenation of Cyclohexane on Cobalt Oxide (Co 3 O 4 ) Nanoparticles: The Effect of Particle Size on Activity and Selectivity
journal, September 2012

  • Tyo, Eric C.; Yin, Chunrong; Di Vece, Marcel
  • ACS Catalysis, Vol. 2, Issue 11
  • DOI: 10.1021/cs300479a

Surface-Mediated Self-Coupling of Ethanol on Gold
journal, April 2009

  • Liu, Xiaoying; Xu, Bingjun; Haubrich, Jan
  • Journal of the American Chemical Society, Vol. 131, Issue 16
  • DOI: 10.1021/ja900822r

Selective hydrogenation of 1,3-butadiene on platinum–copper alloys at the single-atom limit
journal, October 2015

  • Lucci, Felicia R.; Liu, Jilei; Marcinkowski, Matthew D.
  • Nature Communications, Vol. 6, Issue 1
  • DOI: 10.1038/ncomms9550

Aerobic Oxidative Esterification of Aldehydes with Alcohols by Gold–Nickel Oxide Nanoparticle Catalysts with a Core–Shell Structure
journal, July 2013

  • Suzuki, Ken; Yamaguchi, Tatsuo; Matsushita, Ken
  • ACS Catalysis, Vol. 3, Issue 8
  • DOI: 10.1021/cs4004084

Ag Alloyed Pd Single-Atom Catalysts for Efficient Selective Hydrogenation of Acetylene to Ethylene in Excess Ethylene
journal, May 2015

Decomposition of Ethanol Over Ni-Al Catalysts: Effect of Copper Addition
journal, January 2012

Activity and stability of low-content gold–cerium oxide catalysts for the water–gas shift reaction
journal, March 2005

  • Fu, Qi; Deng, Weiling; Saltsburg, Howard
  • Applied Catalysis B: Environmental, Vol. 56, Issue 1-2, p. 57-68
  • DOI: 10.1016/j.apcatb.2004.07.015

Ag/Au Mixed Sites Promote Oxidative Coupling of Methanol on the Alloy Surface
journal, March 2014

  • Xu, Bingjun; Siler, Cassandra G. F.; Madix, Robert J.
  • Chemistry - A European Journal, Vol. 20, Issue 16
  • DOI: 10.1002/chem.201304837

Water co-catalyzed selective dehydrogenation of methanol to formaldehyde and hydrogen
journal, August 2016

Molecular-Scale Perspective of Water-Catalyzed Methanol Dehydrogenation to Formaldehyde
journal, June 2013

  • Boucher, Matthew B.; Marcinkowski, Matthew D.; Liriano, Melissa L.
  • ACS Nano, Vol. 7, Issue 7
  • DOI: 10.1021/nn402055k

Nanoporous Metals with Structural Hierarchy: A Review
journal, August 2017

  • Juarez, Theresa; Biener, Juergen; Weissmüller, Jörg
  • Advanced Engineering Materials, Vol. 19, Issue 12
  • DOI: 10.1002/adem.201700389

The selective oxidation of ethylene glycol and 1,2-propanediol on Au, Pd, and Au–Pd bimetallic catalysts
journal, November 2013

  • Griffin, Michael B.; Rodriguez, Abraham A.; Montemore, Matthew M.
  • Journal of Catalysis, Vol. 307
  • DOI: 10.1016/j.jcat.2013.07.012

Selective oxidation of ethanol to acetaldehyde by Au−Ir catalysts
journal, September 2013

Synergy and Anti-Synergy between Palladium and Gold in Nanoparticles Dispersed on a Reducible Support
journal, September 2016

Performance of Cu-Alloyed Pd Single-Atom Catalyst for Semihydrogenation of Acetylene under Simulated Front-End Conditions
journal, January 2017

Coalescence Behavior of Gold Nanoparticles
journal, March 2009

CO-Induced Diffusion of Ni Atoms to the Surface of Ni–Au Clusters on TiO 2 (110)
journal, May 2011

  • Tenney, Samuel A.; He, Wei; Roberts, Christopher C.
  • The Journal of Physical Chemistry C, Vol. 115, Issue 22
  • DOI: 10.1021/jp2014258

Bimetallic Au–Pd catalysts for selective hydrogenation of butadiene: Influence of the preparation method on catalytic properties
journal, January 2013

Selective hydrogenation of butadiene over TiO 2 supported copper, gold and gold–copper catalysts prepared by deposition–precipitation
journal, January 2014

  • Delannoy, Laurent; Thrimurthulu, Gode; Reddy, Padigapati S.
  • Phys. Chem. Chem. Phys., Vol. 16, Issue 48
  • DOI: 10.1039/c4cp02141j

XPS study of silver, nickel and bimetallic silver–nickel nanoparticles prepared by seed-mediated growth
journal, September 2012

Isolated Metal Atom Geometries as a Strategy for Selective Heterogeneous Hydrogenations
journal, March 2012

  • Kyriakou, Georgios; Boucher, Matthew B.; Jewell, April D.
  • Science, Vol. 335, Issue 6073
  • DOI: 10.1126/science.1215864

Oxygen reduction reaction on electrodeposited PtAu alloy catalysts in the presence of phosphoric acid
journal, April 2015

Structure sensitivity of methanol decomposition on Ni/SiO2 catalysts
journal, November 2011

  • Mihaylov, Mihail; Tsoncheva, Tanya; Hadjiivanov, Konstantin
  • Journal of Materials Science, Vol. 46, Issue 22
  • DOI: 10.1007/s10853-011-5437-4

Ethanol dehydrogenation to ethyl acetate by using copper and copper chromite catalysts
journal, January 2012

Why gold is the noblest of all the metals
journal, July 1995

Reaction-Relevant Gold Structures in the Low Temperature Water-Gas Shift Reaction on Au-CeO 2
journal, August 2008

  • Deng, Weiling; Frenkel, Anatoly I.; Si, Rui
  • The Journal of Physical Chemistry C, Vol. 112, Issue 33
  • DOI: 10.1021/jp800075y

Alloy formation in the Au{111}/Ni system – An investigation with scanning tunnelling microscopy and medium energy ion scattering
journal, February 2009

ZnO-modified zirconia as gold catalyst support for the low-temperature methanol steam reforming reaction
journal, July 2014

Nanoporous Gold Catalysts for Selective Gas-Phase Oxidative Coupling of Methanol at Low Temperature
journal, January 2010

Monodispersed and nanostructrured Ni/SiO2 catalyst and its activity for non oxidative methane activation
journal, April 2011

Production of Hydrogen from Ethanol: Review of Reaction Mechanism and Catalyst Deactivation
journal, April 2012

  • Mattos, Lisiane V.; Jacobs, Gary; Davis, Burtron H.
  • Chemical Reviews, Vol. 112, Issue 7
  • DOI: 10.1021/cr2000114

Aerobic oxidation of aqueous ethanol using heterogeneous gold catalysts: Efficient routes to acetic acid and ethyl acetate
journal, October 2007

Transition-Metal Single Atoms in a Graphene Shell as Active Centers for Highly Efficient Artificial Photosynthesis
journal, December 2017

Acido-basicity of lanthana/alumina catalysts and their activity in ethanol conversion
journal, January 2017

Shape-Controlled Synthesis of Gold and Silver Nanoparticles
journal, December 2002

Palladium–gold single atom alloy catalysts for liquid phase selective hydrogenation of 1-hexyne
journal, January 2017

  • Liu, Jilei; Shan, Junjun; Lucci, Felicia R.
  • Catalysis Science & Technology, Vol. 7, Issue 19
  • DOI: 10.1039/C7CY00794A

Active Nonmetallic Au and Pt Species on Ceria-Based Water-Gas Shift Catalysts
journal, August 2003

Single atom alloy surface analogs in Pd0.18Cu15 nanoparticles for selective hydrogenation reactions
journal, January 2013

  • Boucher, Matthew B.; Zugic, Branko; Cladaras, George
  • Physical Chemistry Chemical Physics, Vol. 15, Issue 29
  • DOI: 10.1039/c3cp51538a

Selective non-oxidative dehydrogenation of ethanol to acetaldehyde and hydrogen on highly dilute NiCu alloys
journal, May 2017

‘Shape effects’ in metal oxide supported nanoscale gold catalysts
journal, January 2011

  • Boucher, Matthew B.; Goergen, Simone; Yi, Nan
  • Physical Chemistry Chemical Physics, Vol. 13, Issue 7
  • DOI: 10.1039/c0cp02009e

Design of a Surface Alloy Catalyst for Steam Reforming
journal, March 1998

Ethanol dehydrogenation by gold catalysts: The effect of the gold particle size and the presence of oxygen
journal, June 2009

Hydrogen production from formic acid decomposition at room temperature using a Ag–Pd core–shell nanocatalyst
journal, April 2011

  • Tedsree, Karaked; Li, Tong; Jones, Simon
  • Nature Nanotechnology, Vol. 6, Issue 5
  • DOI: 10.1038/nnano.2011.42

Structure and stability of nickel/nickel oxide core–shell nanoparticles
journal, April 2011

Mechanistic Aspects of the Ethanol Steam Reforming Reaction for Hydrogen Production on Pt, Ni, and PtNi Catalysts Supported on γ-Al 2 O 3
journal, March 2010

  • Sanchez-Sanchez, Maria Cruz; Navarro Yerga, Rufino M.; Kondarides, Dimitris I.
  • The Journal of Physical Chemistry A, Vol. 114, Issue 11
  • DOI: 10.1021/jp906531x

Characterization of the Oxidation States of Supported Gold Species by IR Spectroscopy of Adsorbed CO
journal, June 2007

  • Mihaylov, M.; Knözinger, H.; Hadjiivanov, K.
  • Chemie Ingenieur Technik, Vol. 79, Issue 6
  • DOI: 10.1002/cite.200700029

Gold catalysis in chemical processing
journal, February 2002

Silica-Supported Au-Ag Catalysts for the Selective Hydrogenation of Butadiene
journal, June 2017

  • Masoud, Nazila; Delannoy, Laurent; Calers, Christophe
  • ChemCatChem, Vol. 9, Issue 12
  • DOI: 10.1002/cctc.201700127

Controlling Hydrogen Activation, Spillover, and Desorption with Pd–Au Single-Atom Alloys
journal, January 2016

  • Lucci, Felicia R.; Darby, Matthew T.; Mattera, Michael F. G.
  • The Journal of Physical Chemistry Letters, Vol. 7, Issue 3
  • DOI: 10.1021/acs.jpclett.5b02400