Actinide-based MOFs: a middle ground in solution and solid-state structural motifs

Dolgopolova, Ekaterina A.; Rice, Allison M.; Shustova, Natalia B.

doi:10.1039/C7CC09780H

Actinide-based MOFs: a middle ground in solution and solid-state structural motifs

Journal Article · 01 January 2018 · ChemComm

DOI:https://doi.org/10.1039/C7CC09780H· OSTI ID:1470191

Dolgopolova, Ekaterina A. ^[1]; Rice, Allison M. ^[1]; ^[1]

Department of Chemistry and Biochemistry; University of South Carolina; Columbia; USA

In this review, we highlight how recent advances in the field of actinide structural chemistry of metal–organic frameworks (MOFs) could be utilized towards investigations relative to efficient nuclear waste administration, driven by the interest towards development of novel actinide-containing architectures as well as concerns regarding environmental pollution and nuclear waste storage.

Research Organization:: Energy Frontier Research Centers (EFRC) (United States). Center for Hierarchical Waste Form Materials (CHWM)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

DOE Contract Number:: SC0016574

OSTI ID:: 1470191

Journal Information:: ChemComm, Vol. 54, Issue 50; ISSN 1359-7345

Publisher:: Royal Society of Chemistry

Country of Publication:: United States

Language:: English

References (101)

Network Dimensionality of Selected Uranyl(VI) Coordination Polymers and Octopus-like Uranium(IV) Clusters No authors listed Crystal Growth & Design https://doi.org/10.1021/acs.cgd.7b01165		September 2017
Solution and Solid-State Structural Chemistry of Actinide Hydrates and Their Hydrolysis and Condensation Products No authors listed Chemical Reviews https://doi.org/10.1021/cr300212f		October 2012
Functionalized Porous Aromatic Framework for Efficient Uranium Adsorption from Aqueous Solutions No authors listed ACS Applied Materials & Interfaces https://doi.org/10.1021/acsami.7b01711		March 2017
Stepwise crystallographic visualization of dynamic guest binding in a nanoporous framework No authors listed Chemical Science https://doi.org/10.1039/C7SC00267J		January 2017
Studtite, [(UO ₂ )(O ₂ )(H ₂ O) ₂ ](H ₂ O) ₂ : The first structure of a peroxide mineral No authors listed American Mineralogist https://doi.org/10.2138/am-2003-0725		July 2003
Sulfate-Rich Metal–Organic Framework for High Efficiency and Selective Removal of Barium from Nuclear Wastewater No authors listed Industrial & Engineering Chemistry Research https://doi.org/10.1021/acs.iecr.7b02887		November 2017
Synergistic Assembly of Heavy Metal Clusters and Luminescent Organic Bridging Ligands in Metal–Organic Frameworks for Highly Efficient X-ray Scintillation No authors listed Journal of the American Chemical Society https://doi.org/10.1021/ja500671h		April 2014
Adolfpateraite, K(UO2)(SO4)(OH)(H2O), a new uranyl sulphate mineral from Jachymov, Czech Republic No authors listed American Mineralogist https://doi.org/10.2138/am.2012.3976		January 2012
Centrosymmetric and chiral porous thorium organic frameworks exhibiting uncommon thorium coordination environments No authors listed Dalton Transactions https://doi.org/10.1039/C5DT03363B		January 2015
Exceptional Perrhenate/Pertechnetate Uptake and Subsequent Immobilization by a Low-Dimensional Cationic Coordination Polymer: Overcoming the Hofmeister Bias Selectivity No authors listed Environmental Science & Technology Letters https://doi.org/10.1021/acs.estlett.7b00165		May 2017
Highly Sensitive Detection of Ionizing Radiations by a Photoluminescent Uranyl Organic Framework No authors listed Angewandte Chemie International Edition https://doi.org/10.1002/anie.201700919		May 2017
Preparation, Structures, and Photocatalytic Properties of Three New Uranyl−Organic Assembly Compounds No authors listed Inorganic Chemistry https://doi.org/10.1021/ic800109y		June 2008
Direct Electrical Detection of Iodine Gas by a Novel Metal–Organic-Framework-Based Sensor No authors listed ACS Applied Materials & Interfaces https://doi.org/10.1021/acsami.7b16381		December 2017
Metal–organic frameworks for radionuclide sequestration from aqueous solution: a brief overview and outlook No authors listed Dalton Transactions https://doi.org/10.1039/C7DT03670A		January 2017
Materials for the Recovery of Uranium from Seawater No authors listed Chemical Reviews https://doi.org/10.1021/acs.chemrev.7b00355		June 2017
Iodine Gas Adsorption in Nanoporous Materials: A Combined Experiment–Modeling Study No authors listed Industrial & Engineering Chemistry Research https://doi.org/10.1021/acs.iecr.6b04189		February 2017
Capture of iodine in highly stable metal–organic frameworks: a systematic study No authors listed Chemical Communications https://doi.org/10.1039/c3cc43728k		January 2013
A New Paradigm for Anion Trapping in High Capacity and Selectivity: Crystal-to-Crystal Transformation of Cationic Materials No authors listed Journal of the American Chemical Society https://doi.org/10.1021/ja204577p		July 2011
Efficient Capture and Effective Sensing of Cr ₂ O ₇ ^2– from Water Using a Zirconium Metal–Organic Framework No authors listed Inorganic Chemistry https://doi.org/10.1021/acs.inorgchem.7b02327		November 2017
Scintillating Metal-Organic Frameworks: A New Class of Radiation Detection Materials No authors listed Advanced Materials https://doi.org/10.1002/adma.200801753		January 2009
Zirconium-Based Metal–Organic Framework for Removal of Perrhenate from Water No authors listed Inorganic Chemistry https://doi.org/10.1021/acs.inorgchem.6b01004		August 2016
Uranyl Bearing Hybrid Materials: Synthesis, Speciation, and Solid-State Structures No authors listed Chemical Reviews https://doi.org/10.1021/cr300202a		August 2012
The First Organically Templated Layered Uranium(IV) Fluorides: (H3N(CH2)3NH3)U2F10⋅2 H2O, (H3N(CH2)4NH3)U2F10⋅3 H2O, and (H3N(CH2)6NH3)U2F10⋅2 H2O No authors listed Angewandte Chemie International Edition https://doi.org/10.1002/(SICI)1521-3773(19980904)37:16<2214::AID-ANIE2214>3.0.CO;2-V		September 1998
Evaluating metal–organic frameworks for natural gas storage No authors listed Chemical Science https://doi.org/10.1039/C3SC52633J		January 2014
The crystal chemistry of uranium carboxylates No authors listed Coordination Chemistry Reviews https://doi.org/10.1016/j.ccr.2013.08.038		May 2014
Structures and luminescent properties of new uranyl-based hybrid materials No authors listed Solid State Sciences https://doi.org/10.1016/j.solidstatesciences.2011.04.004		June 2011
Metal–organic frameworks for artificial photosynthesis and photocatalysis No authors listed Chem. Soc. Rev. https://doi.org/10.1039/C4CS00103F		January 2014
Coordination polymers of uranium( iv ) terephthalates No authors listed Dalton Transactions https://doi.org/10.1039/C4DT02343A		January 2015
Design and synthesis of a chiral uranium-based microporous metal organic framework with high SHG efficiency and sequestration potential for low-valent actinides No authors listed Dalton Transactions https://doi.org/10.1039/C5DT02337H		January 2015
Carbamoylmethylphosphine Oxide-Functionalized MIL-101(Cr) as Highly Selective Uranium Adsorbent No authors listed Analytical Chemistry https://doi.org/10.1021/acs.analchem.7b00821		May 2017
Synthesis, Structures, and Properties of Uranyl Hybrids Constructed by a Variety of Mono- and Polycarboxylic Acids No authors listed Inorganic Chemistry https://doi.org/10.1021/ic4012444		October 2013
Ultrafast and Efficient Extraction of Uranium from Seawater Using an Amidoxime Appended Metal–Organic Framework No authors listed ACS Applied Materials & Interfaces https://doi.org/10.1021/acsami.7b12396		September 2017
Efficient and Selective Uptake of TcO ₄ ^– by a Cationic Metal–Organic Framework Material with Open Ag ⁺ Sites No authors listed Environmental Science & Technology https://doi.org/10.1021/acs.est.7b00339		March 2017
A Spectroscopic Study of Uranium and Molybdenum Complexation within the Pore Channels of Hybrid Mesoporous Silica: A Spectroscopic Study of Uranium and Molybdenum Complexation within the Pore Channels of Hybrid Mesoporous Silica No authors listed European Journal of Inorganic Chemistry https://doi.org/10.1002/ejic.201601085		December 2016
A Room-Temperature X-ray-Induced Photochromic Material for X-ray Detection No authors listed Angewandte Chemie https://doi.org/10.1002/ange.201108220		February 2012
Highly Sensitive and Selective Uranium Detection in Natural Water Systems Using a Luminescent Mesoporous Metal–Organic Framework Equipped with Abundant Lewis Basic Sites: A Combined Batch, X-ray Absorption Spectroscopy, and First Principles Simulation Investigation No authors listed Environmental Science & Technology https://doi.org/10.1021/acs.est.6b06305		March 2017
Thermochemical Evidence for Strong Iodine Chemisorption by ZIF-8 No authors listed Journal of the American Chemical Society https://doi.org/10.1021/ja406081r		October 2013
Structures of Metal–Organic Frameworks with Rod Secondary Building Units No authors listed Chemical Reviews https://doi.org/10.1021/acs.chemrev.6b00346		September 2016
Metal–Organic Frameworks for Separations No authors listed Chemical Reviews https://doi.org/10.1021/cr200190s		September 2011
Umbellate Distortions of the Uranyl Coordination Environment Result in a Stable and Porous Polycatenated Framework That Can Effectively Remove Cesium from Aqueous Solutions No authors listed Journal of the American Chemical Society https://doi.org/10.1021/jacs.5b02480		May 2015
Metal–Organic Framework Materials as Chemical Sensors No authors listed Chemical Reviews https://doi.org/10.1021/cr200324t		September 2011
Metal–Organic-Framework-Type 1D-Channel Open Network of a Tetravalent Uranium Trimesate No authors listed Inorganic Chemistry https://doi.org/10.1021/ic2021963		December 2011
Multifaceted Modularity: A Key for Stepwise Building of Hierarchical Complexity in Actinide Metal–Organic Frameworks No authors listed Journal of the American Chemical Society https://doi.org/10.1021/jacs.7b09496		November 2017
Heterogeneous photoredox synthesis of N-hydroxy-oxazolidinones catalysed by metal–organic frameworks No authors listed Catalysis Science & Technology https://doi.org/10.1039/C6CY00054A		January 2016
A Revised and Expanded Structure Hierarchy of Natural and Synthetic Hexavalent Uranium Compounds No authors listed The Canadian Mineralogist https://doi.org/10.3749/canmin.1500078		January 2016
Stability of metal–organic frameworks under gamma irradiation No authors listed Chemical Communications https://doi.org/10.1039/C6CC06878B		January 2016
Removal of TcO ₄ ⁻ ions from solution: materials and future outlook No authors listed Chemical Society Reviews https://doi.org/10.1039/C5CS00330J		January 2016
Crystal Engineering with the Uranyl Cation I. Aliphatic Carboxylate Coordination Polymers: Synthesis, Crystal Structures, and Fluorescent Properties No authors listed Crystal Growth & Design https://doi.org/10.1021/cg060329h		October 2006
A mesoporous cationic thorium-organic framework that rapidly traps anionic persistent organic pollutants No authors listed Nature Communications https://doi.org/10.1038/s41467-017-01208-w		November 2017
Competitive I ₂ Sorption by Cu-BTC from Humid Gas Streams No authors listed Chemistry of Materials https://doi.org/10.1021/cm401762g		June 2013
Six-Fold Coordinated Uranyl Cations in Extended Coordination Polymers No authors listed Crystal Growth & Design https://doi.org/10.1021/cg300853f		August 2012
[(Th ₂ F ₅ )(NC ₇ H ₅ O ₄ ) ₂ (H ₂ O)][NO ₃ ]: An Actinide−Organic Open Framework No authors listed Journal of the American Chemical Society https://doi.org/10.1021/ja036832p		October 2003
Construction of Three-Dimensional Uranyl-Organic Frameworks with Benzenetricarboxylate Ligands No authors listed European Journal of Inorganic Chemistry https://doi.org/10.1002/ejic.201000298		June 2010
Functionalized metal organic frameworks for effective capture of radioactive organic iodides No authors listed Faraday Discussions https://doi.org/10.1039/C7FD00013H		January 2017
Identifying the Recognition Site for Selective Trapping of ⁹⁹ TcO ₄ ^– in a Hydrolytically Stable and Radiation Resistant Cationic Metal–Organic Framework No authors listed Journal of the American Chemical Society https://doi.org/10.1021/jacs.7b08632		October 2017
Syntheses and Structures of a Series of Uranyl Phosphonates and Sulfonates: An Insight into Their Correlations and Discrepancies No authors listed Inorganic Chemistry https://doi.org/10.1021/ic302847g		February 2013
Functionalized magnetic mesoporous silica nanoparticles for U removal from low and high pH groundwater No authors listed Journal of Hazardous Materials https://doi.org/10.1016/j.jhazmat.2016.05.093		November 2016
Polynuclear uranium(IV) compounds with (μ3-oxo)U3 or (μ4-oxo)U4 cores and compartmental Schiff base ligands No authors listed Polyhedron https://doi.org/10.1016/j.poly.2005.10.015		May 2006
Syntheses, Structures, Luminescence, and Photocatalytic Properties of a Series of Uranyl Coordination Polymers No authors listed Crystal Growth & Design https://doi.org/10.1021/cg501118b		October 2014
Highly porous and stable metal–organic frameworks for uranium extraction No authors listed Chemical Science https://doi.org/10.1039/c3sc50230a		January 2013
Lanthanides and actinides: Annual survey of their organometallic chemistry covering the year 2016 No authors listed Coordination Chemistry Reviews https://doi.org/10.1016/j.ccr.2017.02.001		May 2017
Clusters of Actinides with Oxide, Peroxide, or Hydroxide Bridges No authors listed Chemical Reviews https://doi.org/10.1021/cr300159x		October 2012
Water-Stable Metal–Organic Frameworks for Fast and High Dichromate Trapping via Single-Crystal-to-Single-Crystal Ion Exchange No authors listed Chemistry of Materials https://doi.org/10.1021/cm503767r		December 2014
Direct Observation of Confined I ⁻ ⋅⋅⋅I ₂ ⋅⋅⋅I ⁻ Interactions in a Metal-Organic Framework: Iodine Capture and Sensing No authors listed Chemistry - A European Journal https://doi.org/10.1002/chem.201702087		May 2017
Reactions of UCl4 withtBu-Calix[4, 5, and 6]arenes: The First “Non-Uranyl” Calixarene Complexes of Uranium No authors listed European Journal of Inorganic Chemistry https://doi.org/10.1002/1099-0682(200008)2000:8<1733::AID-EJIC1733>3.0.CO;2-L		August 2000
Stability of Peroxide-Containing Uranyl Minerals No authors listed Science https://doi.org/10.1126/science.1090259		November 2003
Radiation effects in crystalline ceramics for the immobilization of high-level nuclear waste and plutonium No authors listed Journal of Materials Research https://doi.org/10.1557/JMR.1998.0205		June 1998
U6+ Minerals and Inorganic Compounds: Insights into an Expanded Structural Hierarchy of Crystal Structures No authors listed The Canadian Mineralogist https://doi.org/10.2113/gscanmin.43.6.1839		December 2005
Sequestration and Remobilization of Radioiodine ( ¹²⁹ I) by Soil Organic Matter and Possible Consequences of the Remedial Action at Savannah River Site No authors listed Environmental Science & Technology https://doi.org/10.1021/es201343d		December 2011
Trapping Guests within a Nanoporous Metal–Organic Framework through Pressure-Induced Amorphization No authors listed Journal of the American Chemical Society https://doi.org/10.1021/ja2085096		November 2011
Immobilisation of radioactive waste in glasses, glass composite materials and ceramics No authors listed Advances in Applied Ceramics https://doi.org/10.1179/174367606X81669		February 2006
Extraction of Lanthanide and Actinide Ions from Aqueous Mixtures Using a Carboxylic Acid-Functionalized Porous Aromatic Framework No authors listed ACS Central Science https://doi.org/10.1021/acscentsci.6b00066		April 2016
Radioactive Iodine Capture in Silver-Containing Mordenites through Nanoscale Silver Iodide Formation No authors listed Journal of the American Chemical Society https://doi.org/10.1021/ja103110y		July 2010
Extended Structures and Physicochemical Properties of Uranyl–Organic Compounds No authors listed Accounts of Chemical Research https://doi.org/10.1021/ar200042t		July 2011
Postsynthesis Modification of a Metallosalen-Containing Metal–Organic Framework for Selective Th(IV)/Ln(III) Separation No authors listed Inorganic Chemistry https://doi.org/10.1021/acs.inorgchem.7b01835		September 2017
Capture of organic iodides from nuclear waste by metal-organic framework-based molecular traps No authors listed Nature Communications https://doi.org/10.1038/s41467-017-00526-3		September 2017
A Water-Stable Cationic Metal-Organic Framework as a Dual Adsorbent of Oxoanion Pollutants No authors listed Angewandte Chemie International Edition https://doi.org/10.1002/anie.201600185		February 2016
Crystal Engineering with the Uranyl Cation II. Mixed Aliphatic Carboxylate/Aromatic Pyridyl Coordination Polymers: Synthesis, Crystal Structures, and Sensitized Luminescence No authors listed Crystal Growth & Design https://doi.org/10.1021/cg060330g		October 2006
Hydrothermal Crystallization of Uranyl Coordination Polymers Involving an Imidazolium Dicarboxylate Ligand: Effect of pH on the Nuclearity of Uranyl-Centered Subunits No authors listed Inorganic Chemistry https://doi.org/10.1021/acs.inorgchem.6b01232		August 2016
Bottom-up construction of a superstructure in a porous uranium-organic crystal No authors listed Science https://doi.org/10.1126/science.aam7851		April 2017
Thorium Terephthalates Coordination Polymers Synthesized in Solvothermal DMF/H ₂ O System No authors listed Inorganic Chemistry https://doi.org/10.1021/ic502725y		February 2015
Synthesis of Coordination Polymers of Tetravalent Actinides (Uranium and Neptunium) with a Phthalate or Mellitate Ligand in an Aqueous Medium No authors listed Inorganic Chemistry https://doi.org/10.1021/acs.inorgchem.6b02962		February 2017
Orthowalpurgite (UO2)Bi4O4(AsO4)2-2H2O, a new mineral from the Black Forest, Germany [Orthowalpurgite (UO2)Bi4O4(AsO4)2-2H2O, a new mineral from the Black Forest, Germany] No authors listed European Journal of Mineralogy https://doi.org/10.1127/ejm/7/6/1313		December 1995
Silver-mordenite for radiologic gas capture from complex streams: Dual catalytic CH3I decomposition and I confinement No authors listed Microporous and Mesoporous Materials https://doi.org/10.1016/j.micromeso.2014.04.041		December 2014
Mesoporous stilbene-based lanthanide metal organic frameworks: synthesis, photoluminescence and radioluminescence characteristics No authors listed Dalton Transactions https://doi.org/10.1039/C6DT03755K		January 2017
Dynamic sorption properties of Metal-Organic Frameworks for the capture of methyl iodide No authors listed Microporous and Mesoporous Materials https://doi.org/10.1016/j.micromeso.2017.10.018		March 2018
Mixed Formate-Dicarboxylate Coordination Polymers with Tetravalent Uranium: Occurrence of Tetranuclear {U ₄ O ₄ } and Hexanuclear {U ₆ O ₄ (OH) ₄ } Motifs No authors listed Crystal Growth & Design https://doi.org/10.1021/cg400643g		June 2013
Grand Challenges and Future Opportunities for Metal–Organic Frameworks No authors listed ACS Central Science https://doi.org/10.1021/acscentsci.7b00197		June 2017
3-Fold-Interpenetrated Uranium–Organic Frameworks: New Strategy for Rationally Constructing Three-Dimensional Uranyl Organic Materials No authors listed Inorganic Chemistry https://doi.org/10.1021/ic202577z		February 2012
Capture of Volatile Iodine, a Gaseous Fission Product, by Zeolitic Imidazolate Framework-8 No authors listed Journal of the American Chemical Society https://doi.org/10.1021/ja204757x		August 2011
In silico screening of metal organic framework for iodine capture and storage No authors listed Chemical Physics Letters https://doi.org/10.1016/j.cplett.2014.07.008		August 2014
Melt processed single phase hollandite waste forms for nuclear waste immobilization: Ba1.0Cs0.3A2.3Ti5.7O16; A=Cr, Fe, Al No authors listed Journal of Alloys and Compounds https://doi.org/10.1016/j.jallcom.2013.09.087		January 2014
The first organically templated thorium compounds, [C ₄ N ₂ H ₁₂ ] _0.5 [ThF ₅ ] and [C ₅ N ₂ H ₁₄ ][ThF ₆ ]·0.5H ₂ O No authors listed Chem. Commun. https://doi.org/10.1039/B206749H		January 2002
Materials Science of High-Level Nuclear Waste Immobilization No authors listed MRS Bulletin https://doi.org/10.1557/mrs2009.12		January 2009
The Postsynthetic Renaissance in Porous Solids No authors listed Journal of the American Chemical Society https://doi.org/10.1021/jacs.6b11259		February 2017
Extending the Use of Highly Porous and Functionalized MOFs to Th(IV) Capture No authors listed ACS Applied Materials & Interfaces https://doi.org/10.1021/acsami.7b04192		July 2017
Metal–organic framework photophysics: Optoelectronic devices, photoswitches, sensors, and photocatalysts No authors listed MRS Bulletin https://doi.org/10.1557/mrs.2016.246		November 2016
Surprising coordination for low-valent actinides resembling uranyl( vi ) in thorium( iv ) organic hybrid layered and framework structures based on a graphene-like (6,3) sheet topology No authors listed Dalton Transactions https://doi.org/10.1039/C5DT04183J		January 2016
Iodine Confinement into Metal–Organic Frameworks (MOFs): Low-Temperature Sintering Glasses To Form Novel Glass Composite Material (GCM) Alternative Waste Forms No authors listed Industrial & Engineering Chemistry Research https://doi.org/10.1021/ie200248g		May 2011
TOF-2: A Large 1D Channel Thorium Organic Framework No authors listed Journal of the American Chemical Society https://doi.org/10.1021/ja800395q		March 2008
Capture of Iodine Species in MIL-53(Al), MIL-120(Al), and HKUST-1(Cu) Periodic DFT and Ab-Initio Molecular Dynamics Studies No authors listed The Journal of Physical Chemistry C https://doi.org/10.1021/acs.jpcc.7b08903		November 2017

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