Overcoming the Interfacial Lattice Mismatch: Geometry Control of Gold-Nickel Bimetallic Heteronanostructures

Li, Guangfang Grace; Blom, Douglas A.; Pandey, Shubham; Koch, Robert J.; Misture, Scott T.; Phillpot, Simon R.; Wang, Hui

doi:10.1002/ppsc.201700361

Title: Overcoming the Interfacial Lattice Mismatch: Geometry Control of Gold-Nickel Bimetallic Heteronanostructures

Journal Article · Wed Dec 27 00:00:00 EST 2017 · Particle & Particle Systems Characterization

DOI:https://doi.org/10.1002/ppsc.201700361· OSTI ID:1470189

Li, Guangfang Grace ^[1]; Blom, Douglas A. ^[1]; Pandey, Shubham ^[2]; Koch, Robert J. ^[3]; Misture, Scott T. ^[3]; Phillpot, Simon R. ^[2];

^[1]

Univ. of South Carolina, Columbia, SC (United States)
Univ. of Florida, Gainesville, FL (United States)
Alfred Univ., NY (United States)

Seed-mediated heteroepitaxial growth provides a versatile synthetic approach to a diverse set of geometrically distinct bimetallic heteronanostructures. In bimetallic nanocrystal systems, interfacial heteroepitaxial growth typically occurs between structurally similar metals with lattice mismatch below 5%, whereas controlled epitaxial growth of bimetallic nanocrystals comprising metals with larger lattice mismatches or even dissimilar crystalline structures has long been challenging. Here in this work, the epitaxial growth of both face-centered cubic (fcc) and hexagonal close-packed (hcp) Ni on fcc Au nanocrystal seeds in polyol solvents is systematically investigated, to shed light on the complex mechanisms underpinning the intriguing geometric evolution of lattice-mismatched bimetallic nanocrystals during seed-mediated heteroepitaxial overgrowth. The success in geometry-controlled syntheses of a series of Au–Ni bimetallic heteronanostructures, such as conformal core–shell nanoparticles, asymmetric heterodimers, and multibranched core–satellite nanocrystals, represents a significant step toward the extension of nanoscale interfacial heteroepitaxy from lattice-matched bimetallic systems to the ones exhibiting large lattice mismatches and even dissimilar crystalline structures. In conclusion, the insights gained from this work serve as a central design principle that guides the development of new synthetic approaches to architecturally sophisticated and compositionally diverse multimetallic heteronanostructures.

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Research Organization:: Energy Frontier Research Centers (EFRC) (United States). Center for Hierarchical Waste Form Materials (CHWM)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0016574

OSTI ID:: 1470189

Alternate ID(s):: OSTI ID: 1414965

Journal Information:: Particle & Particle Systems Characterization, Vol. 35, Issue 5; ISSN 0934-0866

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 8 works

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36 MATERIALS SCIENCE
bimetallic nanoparticles
epitaxial growth
heteronanostructures
lattice mismatch
seed‐mediated growth

Title: Overcoming the Interfacial Lattice Mismatch: Geometry Control of Gold-Nickel Bimetallic Heteronanostructures

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