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Water facilitates oxygen migration on gold surfaces

Journal Article · · Physical Chemistry Chemical Physics. PCCP (Print)
DOI:https://doi.org/10.1039/C7CP06451A· OSTI ID:1470014
 [1];  [1];  [1];  [1];  [1];  [2];  [3];  [4]
  1. Department of Chemistry and Chemical Biology, Harvard University; Cambridge; USA
  2. Department of Physics, Harvard University, Cambridge; USA; John A. Paulson School of Engineering and Applied Sciences, Harvard University, Cambridge; USA
  3. John A. Paulson School of Engineering and Applied Sciences, Harvard University, Cambridge; USA
  4. Department of Chemistry and Chemical Biology, Harvard University; Cambridge; USA; John A. Paulson School of Engineering and Applied Sciences, Harvard University, Cambridge; USA

Oxygen exchange between surface oxygen atom and isotopic labeled water vapor through transient hydroxyl pairs on Au(110) surface.

Research Organization:
Energy Frontier Research Centers (EFRC) (United States). Integrated Mesoscale Architectures for Sustainable Catalysis (IMASC)
Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
DOE Contract Number:
SC0012573
OSTI ID:
1470014
Journal Information:
Physical Chemistry Chemical Physics. PCCP (Print), Vol. 20, Issue 4; Related Information: IMASC partners with Harvard University (lead); Fritz Haber Institute; Lawrence Berkeley National Laboratory; Lawrence Livermore National Laboratory; University of Kansas; Tufts University; ISSN 1463-9076
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English

References (60)

Highly Fluorescent, Water-Soluble, Size-Tunable Gold Quantum Dots journal August 2004
Oxygen-induced reconstruction of the Pd(110) surface: an STM study journal April 1995
Generalized Gradient Approximation Made Simple journal October 1996
Efficient CO Oxidation at Low Temperature on Au(111) journal October 2006
The Effect of Adsorbed Water in CO Oxidation on Au/TiO 2 (110) journal December 2010
Propene Adsorption on Clean and Oxygen-Covered Au(111) and Au(100) Surfaces journal September 2000
The oxidation of methanol on a silver (110) catalyst journal September 1978
Projector augmented-wave method journal December 1994
Adsorption of oxygen on Pt(111) journal December 1982
Transient hydroxyl formation from water on oxygen-covered Au(111) journal August 2008
The adsorption of H2O on clean and oxygen-covered pd(100): Formation and reaction of OH groups journal October 1984
Theoretical Study of O-Assisted Selective Coupling of Methanol on Au(111) journal February 2011
From ultrasoft pseudopotentials to the projector augmented-wave method journal January 1999
Direct visualization of quasi-ordered oxygen chain structures on Au(110)-(1 × 2) journal August 2016
Heterogeneous Gold-Based Catalysis for Green Chemistry:  Low-Temperature CO Oxidation and Propene Oxidation journal June 2007
Propene epoxidation with oxygen over gold clusters: Role of basic salts and hydroxides of alkalis journal September 2012
Through the labyrinth of surface reaction mechanism: a personal account, 1964–1992 journal January 1994
Accurate Molecular Van Der Waals Interactions from Ground-State Electron Density and Free-Atom Reference Data journal February 2009
A climbing image nudged elastic band method for finding saddle points and minimum energy paths journal December 2000
Selective Propene Epoxidation on Immobilized Au 6-10 Clusters: The Effect of Hydrogen and Water on Activity and Selectivity journal February 2009
Low temperature CO oxidation on Au(111) and the role of adsorbed water journal June 2007
Imaging Water Dissociation on TiO 2 (110):  Evidence for Inequivalent Geminate OH Groups journal November 2006
Oxygen chemisorption on Au-(1×2) II. Spectroscopic and reactive thermal desorption measurements journal February 2003
Role of Water in CO Oxidation on Gold Catalysts journal August 2014
Monitoring surface reactions with scanning tunneling microscopy: CO oxidation on p(2 × 1)-O pre-covered Cu(110) at 400 K journal November 1994
The reaction of carbon dioxide with an oxygen precovered Ag(110) surface journal December 1995
Spectroscopic Observation of Dual Catalytic Sites During Oxidation of CO on a Au/TiO2 Catalyst journal August 2011
Corrosion Resistance of Superhydrophobic Layered Double Hydroxide Films on Aluminum journal March 2008
The desorption of propylene oxide from oxygen atom and hydroxyl covered Ag(110) journal May 1998
Reaction pathways in the oxydehydrogenation of ammonia at Cu(110) surfaces journal March 1993
The role of water in the epoxidation over gold–titania catalysts journal January 2005
The oxidation of carbon monoxide on the Au(110) surface journal January 1987
Efficiency of ab-initio total energy calculations for metals and semiconductors using a plane-wave basis set journal July 1996
Oxygen chemisorption on Au()-(1×2) I. Thermal desorption measurements journal February 2003
Initial stages of oxidation of Cu(111) journal March 2007
Chainlike Au−O Structures on Au(110)-(1 × r ) Surfaces Calculated from First Principles journal March 2009
A New Type of Strong Metal–Support Interaction and the Production of H 2 through the Transformation of Water on Pt/CeO 2 (111) and Pt/CeO x /TiO 2 (110) Catalysts journal May 2012
Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set journal October 1996
Hydrogen Spillover Enhanced Hydroxyl Formation and Catalytic Activity Toward CO Oxidation at the Metal/Oxide Interface journal February 2015
Water adsorption and the wetting of metal surfaces journal September 2009
Methanol oxidation on Cu(110) journal August 1994
The selective oxidation of CH3OH to H2CO on a copper(110) catalyst journal June 1978
Structural and morphological changes accompanying the reaction of ammonia with Ag()–p(2×1)-O: an STM study journal March 2002
Hydroxyls-induced oxygen activation on “inert” Au nanoparticles for low-temperature CO oxidation journal January 2011
The adsorption of water on clean and oxygen covered Cu(110) journal August 1982
Water-Enhanced Low-Temperature CO Oxidation and Isotope Effects on Atomic Oxygen-Covered Au(111) journal May 2008
Vital Role of Moisture in the Catalytic Activity of Supported Gold Nanoparticles journal April 2004
Origin of the Overpotential for Oxygen Reduction at a Fuel-Cell Cathode journal November 2004
The water dissociation reaction on clean and oxidized iron (110) journal February 1982
The adsorption and reaction of H2O on clean and oxygen covered Ag(110) journal October 1981
Reactivity of the Gold/Water Interface During Selective Oxidation Catalysis journal September 2010
Solvation and ionization of hydroxyl groups in water–ice layers on silver (110) journal April 1999
First-principles investigations of the structure and stability of oxygen adsorption and surface oxide formation at Au(111) journal August 2007
Water Activated by Atomic Oxygen on Au(111) to Oxidize CO at Low Temperatures journal May 2006
Desorption rate isotherms in flash desorption analysis journal June 1977
c ( 2 × 2 ) Water-Hydroxyl Layer on Cu(110): A Wetting Layer Stabilized by Bjerrum Defects journal January 2011
Intermediates Arising from the Water–Gas Shift Reaction over Cu Surfaces: From UHV to Near Atmospheric Pressures journal March 2015
SIMS and TDS study of the reaction of water and oxygen on Pt(111) journal November 1982
Cleavage of N-H bonds by active oxygen on Ag(110): I. Ammonia journal October 1989
Infrared studies of propene and propene oxide adsorption on nanoparticulate Au/TiO2 journal October 2016