skip to main content
OSTI.GOV title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Exfoliated MoS 2 nanosheets confined in 3-D hierarchical carbon nanotube@graphene architecture with superior sodium-ion storage

Abstract

The 3D structure of the MoS 2–MWCNT@rGO composite facilitates the easy access of electrolytes and fast electron transport and accommodates the large volume change during sodiation/de-sodiation and is very promising for sodium-ion battery (SIB) anode applications.

Authors:
 [1];  [2];  [2];  [2];  [1]
  1. Department of Energy Science and Engineering; Indian Institute of Technology Bombay; Mumbai 4000 76; India
  2. Department of Materials Science and Engineering; NUANCE Center; Northwestern University; Evanston; USA
Publication Date:
Research Org.:
Energy Frontier Research Centers (EFRC) (United States). Center for Electrical Energy Storage (CEES)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1469965
DOE Contract Number:  
AC02-06CH11357
Resource Type:
Journal Article
Journal Name:
Journal of Materials Chemistry. A
Additional Journal Information:
Journal Volume: 5; Journal Issue: 1; Related Information: CEES partners with Argonne National Laboratory (lead); University of Illinois, Urbana-Champaign; Northwest University; Journal ID: ISSN 2050-7488
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English
Subject:
energy storage (including batteries and capacitors), charge transport, materials and chemistry by design, synthesis (novel materials)

Citation Formats

Sahu, Tuhin Subhra, Li, Qianqian, Wu, Jinsong, Dravid, Vinayak P., and Mitra, Sagar. Exfoliated MoS 2 nanosheets confined in 3-D hierarchical carbon nanotube@graphene architecture with superior sodium-ion storage. United States: N. p., 2017. Web. doi:10.1039/c6ta07390e.
Sahu, Tuhin Subhra, Li, Qianqian, Wu, Jinsong, Dravid, Vinayak P., & Mitra, Sagar. Exfoliated MoS 2 nanosheets confined in 3-D hierarchical carbon nanotube@graphene architecture with superior sodium-ion storage. United States. doi:10.1039/c6ta07390e.
Sahu, Tuhin Subhra, Li, Qianqian, Wu, Jinsong, Dravid, Vinayak P., and Mitra, Sagar. Sun . "Exfoliated MoS 2 nanosheets confined in 3-D hierarchical carbon nanotube@graphene architecture with superior sodium-ion storage". United States. doi:10.1039/c6ta07390e.
@article{osti_1469965,
title = {Exfoliated MoS 2 nanosheets confined in 3-D hierarchical carbon nanotube@graphene architecture with superior sodium-ion storage},
author = {Sahu, Tuhin Subhra and Li, Qianqian and Wu, Jinsong and Dravid, Vinayak P. and Mitra, Sagar},
abstractNote = {The 3D structure of the MoS2–MWCNT@rGO composite facilitates the easy access of electrolytes and fast electron transport and accommodates the large volume change during sodiation/de-sodiation and is very promising for sodium-ion battery (SIB) anode applications.},
doi = {10.1039/c6ta07390e},
journal = {Journal of Materials Chemistry. A},
issn = {2050-7488},
number = 1,
volume = 5,
place = {United States},
year = {2017},
month = {1}
}

Works referenced in this record:

Microstructural Evolution of Tin Nanoparticles during In Situ Sodium Insertion and Extraction
journal, October 2012

  • Wang, Jiang Wei; Liu, Xiao Hua; Mao, Scott X.
  • Nano Letters, Vol. 12, Issue 11
  • DOI: 10.1021/nl303305c

Synergetic Effect of Yolk–Shell Structure and Uniform Mixing of SnS–MoS 2 Nanocrystals for Improved Na-Ion Storage Capabilities
journal, October 2015

  • Choi, Seung Ho; Kang, Yun Chan
  • ACS Applied Materials & Interfaces, Vol. 7, Issue 44
  • DOI: 10.1021/acsami.5b07093

Few-Layered SnS 2 on Few-Layered Reduced Graphene Oxide as Na-Ion Battery Anode with Ultralong Cycle Life and Superior Rate Capability
journal, November 2014

  • Zhang, Yandong; Zhu, Peiyi; Huang, Liliang
  • Advanced Functional Materials, Vol. 25, Issue 3
  • DOI: 10.1002/adfm.201402833

Graphene-Based Three-Dimensional Hierarchical Sandwich-type Architecture for High-Performance Li/S Batteries
journal, September 2013

  • Chen, Renjie; Zhao, Teng; Lu, Jun
  • Nano Letters, Vol. 13, Issue 10
  • DOI: 10.1021/nl4016683

Fluorinated Ethylene Carbonate as Electrolyte Additive for Rechargeable Na Batteries
journal, October 2011

  • Komaba, Shinichi; Ishikawa, Toru; Yabuuchi, Naoaki
  • ACS Applied Materials & Interfaces, Vol. 3, Issue 11
  • DOI: 10.1021/am200973k

An Advanced MoS 2 /Carbon Anode for High-Performance Sodium-Ion Batteries
journal, September 2014


Effective Liquid-Phase Exfoliation and Sodium Ion Battery Application of MoS 2 Nanosheets
journal, May 2014

  • Bang, Gyeong Sook; Nam, Kwan Woo; Kim, Jong Yun
  • ACS Applied Materials & Interfaces, Vol. 6, Issue 10
  • DOI: 10.1021/am4060222

Anomalous Lattice Vibrations of Single- and Few-Layer MoS 2
journal, March 2010

  • Lee, Changgu; Yan, Hugen; Brus, Louis E.
  • ACS Nano, Vol. 4, Issue 5
  • DOI: 10.1021/nn1003937

The role of graphene for electrochemical energy storage
journal, December 2014

  • Raccichini, Rinaldo; Varzi, Alberto; Passerini, Stefano
  • Nature Materials, Vol. 14, Issue 3
  • DOI: 10.1038/nmat4170

Carbon Nanosheet Frameworks Derived from Peat Moss as High Performance Sodium Ion Battery Anodes
journal, November 2013

  • Ding, Jia; Wang, Huanlei; Li, Zhi
  • ACS Nano, Vol. 7, Issue 12
  • DOI: 10.1021/nn404640c

Synthesis of Water Soluble Graphene
journal, June 2008

  • Si, Yongchao; Samulski, Edward T.
  • Nano Letters, Vol. 8, Issue 6
  • DOI: 10.1021/nl080604h

Self-assembly of hierarchical MoSx/CNT nanocomposites (2<x<3): towards high performance anode materials for lithium ion batteries
journal, July 2013

  • Shi, Yumeng; Wang, Ye; Wong, Jen It
  • Scientific Reports, Vol. 3, Issue 1
  • DOI: 10.1038/srep02169

High Capacity Anode Materials for Rechargeable Sodium-Ion Batteries
journal, January 2000

  • Stevens, D. A.; Dahn, J. R.
  • Journal of The Electrochemical Society, Vol. 147, Issue 4
  • DOI: 10.1149/1.1393348

A graphene-like MoS 2 /graphene nanocomposite as a highperformance anode for lithium ion batteries
journal, January 2014

  • Liu, Yongchang; Zhao, Yanping; Jiao, Lifang
  • J. Mater. Chem. A, Vol. 2, Issue 32
  • DOI: 10.1039/C4TA01644K

Na-ion batteries, recent advances and present challenges to become low cost energy storage systems
journal, January 2012

  • Palomares, Verónica; Serras, Paula; Villaluenga, Irune
  • Energy & Environmental Science, Vol. 5, Issue 3
  • DOI: 10.1039/c2ee02781j

In Situ Observation of the Electrochemical Lithiation of a Single SnO2 Nanowire Electrode
journal, December 2010


Dimensional Effects of MoS 2 Nanoplates Embedded in Carbon Nanofibers for Bifunctional Li and Na Insertion and Conversion Reactions
journal, September 2016

  • Jung, Ji-Won; Ryu, Won-Hee; Yu, Sunmoon
  • ACS Applied Materials & Interfaces, Vol. 8, Issue 40
  • DOI: 10.1021/acsami.6b08267

Graphene Oxide Sheets Chemically Cross-Linked by Polyallylamine
journal, August 2009

  • Park, Sungjin; Dikin, Dmitriy A.; Nguyen, SonBinh T.
  • The Journal of Physical Chemistry C, Vol. 113, Issue 36
  • DOI: 10.1021/jp907613s

Defect-Rich MoS 2 Ultrathin Nanosheets with Additional Active Edge Sites for Enhanced Electrocatalytic Hydrogen Evolution
journal, August 2013


Origin of additional capacities in metal oxide lithium-ion battery electrodes
journal, November 2013

  • Hu, Yan-Yan; Liu, Zigeng; Nam, Kyung-Wan
  • Nature Materials, Vol. 12, Issue 12
  • DOI: 10.1038/nmat3784

CTAB-assisted synthesis of single-layer MoS 2 –graphene composites as anode materials of Li-ion batteries
journal, January 2013

  • Wang, Zhen; Chen, Tao; Chen, Weixiang
  • J. Mater. Chem. A, Vol. 1, Issue 6
  • DOI: 10.1039/C2TA00598K

Nanomaterials for Rechargeable Lithium Batteries
journal, April 2008

  • Bruce, Peter G.; Scrosati, Bruno; Tarascon, Jean-Marie
  • Angewandte Chemie International Edition, Vol. 47, Issue 16, p. 2930-2946
  • DOI: 10.1002/anie.200702505

Sodium-Ion Batteries
journal, May 2012

  • Slater, Michael D.; Kim, Donghan; Lee, Eungje
  • Advanced Functional Materials, Vol. 23, Issue 8, p. 947-958
  • DOI: 10.1002/adfm.201200691

α-MoO3: A high performance anode material for sodium-ion batteries
journal, June 2013


Graphene: The New Two-Dimensional Nanomaterial
journal, October 2009

  • Rao, C. N. R.; Sood, A. K.; Subrahmanyam, K. S.
  • Angewandte Chemie International Edition, Vol. 48, Issue 42, p. 7752-7777
  • DOI: 10.1002/anie.200901678

Exfoliated-SnS 2 restacked on graphene as a high-capacity, high-rate, and long-cycle life anode for sodium ion batteries
journal, January 2015

  • Liu, Yongchang; Kang, Hongyan; Jiao, Lifang
  • Nanoscale, Vol. 7, Issue 4
  • DOI: 10.1039/C4NR05106H

Exfoliated MoS2 Sheets and Reduced Graphene Oxide-An Excellent and Fast Anode for Sodium-ion Battery
journal, July 2015

  • Sahu, Tuhin Subhra; Mitra, Sagar
  • Scientific Reports, Vol. 5, Issue 1
  • DOI: 10.1038/srep12571

Patternable Large-Scale Molybdenium Disulfide Atomic Layers Grown by Gold-Assisted Chemical Vapor Deposition
journal, January 2014


Large Area Films of Alternating Graphene–Carbon Nanotube Layers Processed in Water
journal, November 2013

  • Tristán-López, Ferdinando; Morelos-Gómez, Aaron; Vega-Díaz, Sofía Magdalena
  • ACS Nano, Vol. 7, Issue 12
  • DOI: 10.1021/nn404022m

Excellent electrochemical performance of tin monosulphide (SnS) as a sodium-ion battery anode
journal, January 2014

  • Dutta, Prasit Kumar; Sen, Uttam Kumar; Mitra, Sagar
  • RSC Adv., Vol. 4, Issue 81
  • DOI: 10.1039/C4RA05851H

Growth of Ultrathin MoS 2 Nanosheets with Expanded Spacing of (002) Plane on Carbon Nanotubes for High-Performance Sodium-Ion Battery Anodes
journal, December 2014

  • Zhang, Shen; Yu, Xianbo; Yu, Hailong
  • ACS Applied Materials & Interfaces, Vol. 6, Issue 24
  • DOI: 10.1021/am5061036

Design and tailoring of a hierarchical graphene-carbon nanotube architecture for supercapacitors
journal, January 2011

  • Yang, Shin-Yi; Chang, Kuo-Hsin; Tien, Hsi-Wen
  • J. Mater. Chem., Vol. 21, Issue 7
  • DOI: 10.1039/C0JM03199B

Sodium Ion Insertion in Hollow Carbon Nanowires for Battery Applications
journal, June 2012

  • Cao, Yuliang; Xiao, Lifen; Sushko, Maria L.
  • Nano Letters, Vol. 12, Issue 7
  • DOI: 10.1021/nl3016957

MoS 2 /Graphene Composite Anodes with Enhanced Performance for Sodium-Ion Batteries: The Role of the Two-Dimensional Heterointerface
journal, January 2015

  • Xie, Xiuqiang; Ao, Zhimin; Su, Dawei
  • Advanced Functional Materials, Vol. 25, Issue 9
  • DOI: 10.1002/adfm.201404078

Laser-Thinning of MoS 2 : On Demand Generation of a Single-Layer Semiconductor
journal, May 2012

  • Castellanos-Gomez, A.; Barkelid, M.; Goossens, A. M.
  • Nano Letters, Vol. 12, Issue 6
  • DOI: 10.1021/nl301164v

Electrode Materials for Rechargeable Sodium-Ion Batteries: Potential Alternatives to Current Lithium-Ion Batteries
journal, May 2012

  • Kim, Sung-Wook; Seo, Dong-Hwa; Ma, Xiaohua
  • Advanced Energy Materials, Vol. 2, Issue 7, p. 710-721
  • DOI: 10.1002/aenm.201200026

Two-Dimensional Tin Disulfide Nanosheets for Enhanced Sodium Storage
journal, October 2015


Mesoscale Imperfections in MoS 2 Atomic Layers Grown by a Vapor Transport Technique
journal, July 2014

  • Liu, Yingnan; Ghosh, Rudresh; Wu, Di
  • Nano Letters, Vol. 14, Issue 8
  • DOI: 10.1021/nl501782e

The Mechanisms of Lithium and Sodium Insertion in Carbon Materials
journal, January 2001

  • Stevens, D. A.; Dahn, J. R.
  • Journal of The Electrochemical Society, Vol. 148, Issue 8
  • DOI: 10.1149/1.1379565

SnO2@graphene nanocomposites as anode materials for Na-ion batteries with superior electrochemical performance
journal, January 2013

  • Su, Dawei; Ahn, Hyo-Jun; Wang, Guoxiu
  • Chemical Communications, Vol. 49, Issue 30
  • DOI: 10.1039/c3cc40448j

Research Development on Sodium-Ion Batteries
journal, October 2014

  • Yabuuchi, Naoaki; Kubota, Kei; Dahbi, Mouad
  • Chemical Reviews, Vol. 114, Issue 23
  • DOI: 10.1021/cr500192f

FeSe 2 Microspheres as a High-Performance Anode Material for Na-Ion Batteries
journal, April 2015


Atomic-Scale Probing of the Dynamics of Sodium Transport and Intercalation-Induced Phase Transformations in MoS 2
journal, September 2015