Simple quantification of zeolite acid site density by reactive gas chromatography

Abdelrahman, Omar A.; Vinter, Katherine P.; Ren, Limin; Xu, Dandan; Gorte, Raymond J.; Tsapatsis, Michael; Dauenhauer, Paul J.

doi:10.1039/c7cy01068k

Title: Simple quantification of zeolite acid site density by reactive gas chromatography

Journal Article · Sun Jan 01 00:00:00 EST 2017 · Catalysis Science and Technology

DOI:https://doi.org/10.1039/c7cy01068k· OSTI ID:1469941

Abdelrahman, Omar A. ^[1]; Vinter, Katherine P. ^[2]; Ren, Limin ^[1]; Xu, Dandan ^[1]; Gorte, Raymond J. ^[3]; Tsapatsis, Michael ^[1];

^[1]

University of Minnesota; Department of Chemical Engineering and Materials Science; Minneapolis; USA; Catalysis Center for Energy Innovation
University of Minnesota; Department of Chemical Engineering and Materials Science; Minneapolis; USA
University of Pennsylvania; Department of Chemical and Biomolecular Engineering; Philadelphia; USA; Catalysis Center for Energy Innovation

The Brønsted acid site densities of ZSM-5, BEA and single unit cell self-pillared pentasil (SPP) zeolites of varying Si/Al ratios were measured using a new technique, reactive gas chromatography (RGC), which utilizes alkylamine decomposition to selectively count Brønsted acid sites.

Cite

Export

Save

Research Organization:: Energy Frontier Research Centers (EFRC) (United States). Catalysis Center for Energy Innovation (CCEI)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

DOE Contract Number:: SC0001004

OSTI ID:: 1469941

Journal Information:: Catalysis Science and Technology, Vol. 7, Issue 17; Related Information: CCEI partners with the University of Delaware (lead); Brookhaven National Laboratory; California Institute of Technology; Columbia University; University of Delaware; Lehigh University; University of Massachusetts, Amherst; Massachusetts Institute of Technology; University of Minnesota; Pacific Northwest National Laboratory; University of Pennsylvania; Princeton University; Rutgers University; ISSN 2044-4753

Publisher:: Royal Society of Chemistry

Country of Publication:: United States

Language:: English

References (56)

Mechanistic studies of the catalytic dehydration of isobutyl alcohol on NaH-ZSM-5 Williams, Carol; Makarova, Marina A.; Malysheva, Ludmila V. Journal of the Chemical Society, Faraday Transactions, Vol. 86, Issue 20 https://doi.org/10.1039/ft9908603473	journal	January 1990
Design parameters for temperature-programmed desorption from a packed bed*1 Demmin, R. Journal of Catalysis, Vol. 90, Issue 1 https://doi.org/10.1016/0021-9517(84)90081-2	journal	November 1984
The Acidity of Zeolites: Concepts, Measurements and Relation to Catalysis: A Review on Experimental and Theoretical Methods for the Study of Zeolite Acidity Derouane, E. G.; Védrine, J. C.; Pinto, R. Ramos Catalysis Reviews, Vol. 55, Issue 4 https://doi.org/10.1080/01614940.2013.822266	journal	October 2013
Evaluation of specific interactions of solid surfaces by inverse gas chromatography: A new approach based on polarizability of the probes Donnet, J. B.; Park, S. J.; Balard, H. Chromatographia, Vol. 31, Issue 9-10 https://doi.org/10.1007/BF02262385	journal	May 1991
Isopropylamine adsorption for the characterization of acid sites in silica-alumina catalysts Tittensor, J. Journal of Catalysis, Vol. 138, Issue 2 https://doi.org/10.1016/0021-9517(92)90318-C	journal	December 1992
Zeolites by confined space synthesis – characterization of the acid sites in nanosized ZSM-5 by ammonia desorption and 27Al/29Si-MAS NMR spectroscopy Jacobsen, Claus J. H.; Madsen, Claus; Janssens, Ton V. W. Microporous and Mesoporous Materials, Vol. 39, Issue 1-2 https://doi.org/10.1016/S1387-1811(00)00215-8	journal	September 2000
Amine adsorption in H-ZSM-5 Parrillo, D. J.; Adamo, A. T.; Kokotailo, G. T. Applied Catalysis, Vol. 67, Issue 1 https://doi.org/10.1016/S0166-9834(00)84435-8	journal	January 1990
Calorimetric Study of Alcohol and Nitrile Adsorption Complexes in H-ZSM-5 Lee, C. -C.; Gorte, R. J.; Farneth, W. E. The Journal of Physical Chemistry B, Vol. 101, Issue 19 https://doi.org/10.1021/jp970711s	journal	May 1997
Heats of adsorption for ammonia and pyridine in H-ZSM-5: evidence for identical Brønsted-acid sites Parrillo, D. J.; Lee, C.; Gorte, R. J. Applied Catalysis A: General, Vol. 110, Issue 1 https://doi.org/10.1016/0926-860X(94)80106-1	journal	March 1994
Diels–Alder cycloaddition of 2-methylfuran and ethylene for renewable toluene Green, Sara K.; Patet, Ryan E.; Nikbin, Nima Applied Catalysis B: Environmental, Vol. 180 https://doi.org/10.1016/j.apcatb.2015.06.044	journal	January 2016
NMR Characterization of Bronsted Acid Sites in Faujasitic Zeolites with Use of Perdeuterated Trimethylphosphine Oxide Karra, Murthy D.; Sutovich, Kevin J.; Mueller, Karl T. Journal of the American Chemical Society, Vol. 124, Issue 6 https://doi.org/10.1021/ja017172w	journal	February 2002
Reaction path analysis for 1-butanol dehydration in H-ZSM-5 zeolite: Ab initio and microkinetic modeling John, Mathew; Alexopoulos, Konstantinos; Reyniers, Marie-Françoise Journal of Catalysis, Vol. 330 https://doi.org/10.1016/j.jcat.2015.07.005	journal	October 2015
Determination of Integrated Molar Extinction Coefficients for Infrared Absorption Bands of Pyridine Adsorbed on Solid Acid Catalysts Emeis, C. A. Journal of Catalysis, Vol. 141, Issue 2 https://doi.org/10.1006/jcat.1993.1145	journal	June 1993
The Strength of Brønsted Acid Sites in Microporous Aluminosilicates Jones, Andrew J.; Iglesia, Enrique ACS Catalysis, Vol. 5, Issue 10 https://doi.org/10.1021/acscatal.5b01133	journal	August 2015
Dehydration Pathways of 1-Propanol on HZSM-5 in the Presence and Absence of Water Zhi, Yuchun; Shi, Hui; Mu, Linyu Journal of the American Chemical Society, Vol. 137, Issue 50 https://doi.org/10.1021/jacs.5b09107	journal	December 2015
Solid-state NMR studies of molecular sieve catalysts Klinowski, Jacek. Chemical Reviews, Vol. 91, Issue 7 https://doi.org/10.1021/cr00007a010	journal	November 1991
Design parameters for temperature programmed desorption from porous catalysts*1 Gorte, R. Journal of Catalysis, Vol. 75, Issue 1 https://doi.org/10.1016/0021-9517(82)90131-2	journal	May 1982
Reactions on ZSM-5-type zeolite catalysts Anderson, J. Journal of Catalysis, Vol. 58, Issue 1 https://doi.org/10.1016/0021-9517(79)90250-1	journal	June 1979
Temperature-programmed desorption for the characterization of oxide catalysts Gorte, R. J. Catalysis Today, Vol. 28, Issue 4 https://doi.org/10.1016/S0920-5861(96)00249-0	journal	September 1996
Kinetic regimes in the tandem reactions of H-BEA catalyzed formation of p-xylene from dimethylfuran Williams, C. Luke; Vinter, Katherine P.; Chang, Chun-Chih Catalysis Science & Technology, Vol. 6, Issue 1 https://doi.org/10.1039/C5CY01320H	journal	January 2016
Comprehensive IR study on acid/base properties of metal oxides Tamura, Masazumi; Shimizu, Ken-ichi; Satsuma, Atsushi Applied Catalysis A: General, Vol. 433-434 https://doi.org/10.1016/j.apcata.2012.05.008	journal	August 2012
Biomass-Derived Butadiene by Dehydra-Decyclization of Tetrahydrofuran Abdelrahman, Omar A.; Park, Dae Sung; Vinter, Katherine P. ACS Sustainable Chemistry & Engineering, Vol. 5, Issue 5 https://doi.org/10.1021/acssuschemeng.7b00745	journal	March 2017
An examination of the intrinsic activity and stability of various solid acids during the catalytic decarboxylation of γ-valerolactone Kellicutt, Aimee B.; Salary, Roozbeh; Abdelrahman, Omar Ali Catalysis Science & Technology, Vol. 4, Issue 8 https://doi.org/10.1039/c4cy00307a	journal	January 2014
An Examination of Brønsted Acid Sites in H-[Fe]ZSM-5 for Olefin Oligomerization and Adsorption Kresnawahjuesa, O. Journal of Catalysis, Vol. 210, Issue 1 https://doi.org/10.1006/jcat.2002.3657	journal	August 2002
Renewable Isoprene by Sequential Hydrogenation of Itaconic Acid and Dehydra-Decyclization of 3-Methyl-Tetrahydrofuran Abdelrahman, Omar A.; Park, Dae Sung; Vinter, Katherine P. ACS Catalysis, Vol. 7, Issue 2 https://doi.org/10.1021/acscatal.6b03335	journal	January 2017
Decoupling HZSM-5 Catalyst Activity from Deactivation during Upgrading of Pyrolysis Oil Vapors Wan, Shaolong; Waters, Christopher; Stevens, Adam ChemSusChem, Vol. 8, Issue 3 https://doi.org/10.1002/cssc.201402861	journal	December 2014
Pyridine and ammonia as probes for FTIR analysis of solid acid catalysts Barzetti, Tommy; Selli, Elena; Moscotti, Daniele Journal of the Chemical Society, Faraday Transactions, Vol. 92, Issue 8 https://doi.org/10.1039/ft9969201401	journal	January 1996
Mechanism of deamination of butylamines on protonic centers of HNaY zeolite Malysheva, L. Journal of Catalysis, Vol. 104, Issue 1 https://doi.org/10.1016/0021-9517(87)90333-2	journal	March 1987
Adsorption and reaction properties of SnBEA, ZrBEA and H-BEA for the formation of p-xylene from DMF and ethylene Yu, Jingye; Zhu, Shiyu; Dauenhauer, Paul J. Catalysis Science & Technology, Vol. 6, Issue 14 https://doi.org/10.1039/C6CY00501B	journal	January 2016
Experimental criterion for the absence of artifacts in the measurement of rates of heterogeneous catalytic reactions Madon, Rostam J.; Boudart, Michel Industrial & Engineering Chemistry Fundamentals, Vol. 21, Issue 4, p. 438-447 https://doi.org/10.1021/i100008a022	journal	November 1982
A diagnostic test of the kinetic regime in a packed bed reactor Koros, R. M.; Nowak, E. J. Chemical Engineering Science, Vol. 22, Issue 3 https://doi.org/10.1016/0009-2509(67)80134-9	journal	March 1967
Acidity and accessibility studies of desilicated ZSM-5 zeolites in terms of their effectiveness as catalysts in acid-catalyzed cracking processes Tarach, Karolina A.; Góra-Marek, Kinga; Martinez-Triguero, Joaquin Catalysis Science & Technology, Vol. 7, Issue 4 https://doi.org/10.1039/C6CY02609E	journal	January 2017
Quantitative carbon detector for enhanced detection of molecules in foods, pharmaceuticals, cosmetics, flavors, and fuels Beach, Connor A.; Krumm, Christoph; Spanjers, Charles S. The Analyst, Vol. 141, Issue 5 https://doi.org/10.1039/C5AN02552D	journal	January 2016
Gas phase catalysis by zeolites Stöcker, Michael Microporous and Mesoporous Materials, Vol. 82, Issue 3 https://doi.org/10.1016/j.micromeso.2005.01.039	journal	August 2005
Acid strength and solvation in catalysis by MFI zeolites and effects of the identity, concentration and location of framework heteroatoms Jones, Andrew J.; Carr, Robert T.; Zones, Stacey I. Journal of Catalysis, Vol. 312 https://doi.org/10.1016/j.jcat.2014.01.007	journal	April 2014
A study of the surface structure of decationized Y zeolite by quantitative infrared spectroscopy Hughes, Thomas Robert; White, Harry M. The Journal of Physical Chemistry, Vol. 71, Issue 7 https://doi.org/10.1021/j100866a035	journal	June 1967
Phosphorus 31 NMR study of trialkylphosphine probes adsorbed on silica-alumina Baltusis, Laima; Frye, James S.; Maciel, Gary E. Journal of the American Chemical Society, Vol. 109, Issue 1 https://doi.org/10.1021/ja00235a006	journal	January 1987
The assessment of Brönsted acidity concentration in HY zeolites by propan-2-ol dehydration and other methods Rudham, Robert; Spiers, Andrew I.; Winstanley, Alastair W. Zeolites, Vol. 11, Issue 8 https://doi.org/10.1016/S0144-2449(05)80068-5	journal	November 1991
Genesis of Brønsted Acid Sites during Dehydration of 2-Butanol on Tungsten Oxide Catalysts Baertsch, Chelsey D.; Komala, Kenny T.; Chua, Yong-Hwee Journal of Catalysis, Vol. 205, Issue 1 https://doi.org/10.1006/jcat.2001.3426	journal	January 2002
Characterization of H,Na-Y Using Amine Desorption Biaglow, A. I.; Parrillo, D. J.; Gorte, R. J. Journal of Catalysis, Vol. 144, Issue 1 https://doi.org/10.1006/jcat.1993.1323	journal	November 1993
Selective ketonization of acetic acid over HZSM-5: The importance of acyl species and the influence of water Gumidyala, Abhishek; Sooknoi, Tawan; Crossley, Steven Journal of Catalysis, Vol. 340 https://doi.org/10.1016/j.jcat.2016.04.017	journal	August 2016
Synthesis of Self-Pillared Zeolite Nanosheets by Repetitive Branching Zhang, Xueyi; Liu, Dongxia; Xu, Dandan Science, Vol. 336, Issue 6089 https://doi.org/10.1126/science.1221111	journal	June 2012
Zn-Promoted H-ZSM-5 for Endothermic Reforming of n -Hexane at High Pressures Yeh, Yu-Hao; Zhu, Shiyu; Staiber, Patrick Industrial & Engineering Chemistry Research, Vol. 55, Issue 14 https://doi.org/10.1021/acs.iecr.6b00639	journal	March 2016
Introduction into the characterisation of porous materials by inverse gas chromatography Thielmann, Frank Journal of Chromatography A, Vol. 1037, Issue 1-2 https://doi.org/10.1016/j.chroma.2004.03.060	journal	May 2004
An Adsorption Study of CH ₄ on ZSM-5, MOR, and ZSM-12 Zeolites Zhang, Yiwei; Yu, JingYe; Yeh, Yu-Hao The Journal of Physical Chemistry C, Vol. 119, Issue 52 https://doi.org/10.1021/acs.jpcc.5b09571	journal	December 2015
Methods for Characterizing Zeolite Acidity Farneth, W. E.; Gorte, R. J. Chemical Reviews, Vol. 95, Issue 3 https://doi.org/10.1021/cr00035a007	journal	May 1995
An infrared study of pyridine adsorbed on acidic solids. Characterization of surface acidity Parry, E. Journal of Catalysis, Vol. 2, Issue 5 https://doi.org/10.1016/0021-9517(63)90102-7	journal	October 1963
Microkinetic analysis of ring opening and decarboxylation of γ-valerolactone over silica alumina Bond, Jesse Q.; Jungong, Christian S.; Chatzidimitriou, Anargyros Journal of Catalysis, Vol. 344 https://doi.org/10.1016/j.jcat.2016.10.021	journal	December 2016
Quantitative carbon detector (QCD) for calibration-free, high-resolution characterization of complex mixtures Maduskar, Saurabh; Teixeira, Andrew R.; Paulsen, Alex D. Lab on a Chip, Vol. 15, Issue 2 https://doi.org/10.1039/C4LC01180E	journal	January 2015
A comparison of CaO, beta, and a dealuminated Y by ammonia TPD and by temperature programmed 2-propylamine cracking Juskelis, M. Journal of Catalysis, Vol. 138, Issue 1 https://doi.org/10.1016/0021-9517(92)90032-D	journal	November 1992
Comparison between the surface acidity of solid catalysts determined by TPD and FTIR analysis of pre-adsorbed pyridine Selli, E.; Forni, L. Microporous and Mesoporous Materials, Vol. 31, Issue 1-2 https://doi.org/10.1016/S1387-1811(99)00063-3	journal	October 1999
Development of a heterogeneous catalytic cracking reactor utilizing online mass spectrometry analysis Benson, Tracy J.; Holmes, William E.; White, Mark G. Journal of Chromatography A, Vol. 1172, Issue 2 https://doi.org/10.1016/j.chroma.2007.09.061	journal	November 2007
Ultra-selective cycloaddition of dimethylfuran for renewable p-xylene with H-BEA Chang, Chun-Chih; Green, Sara K.; Williams, C. Luke Green Chem., Vol. 16, Issue 2 https://doi.org/10.1039/C3GC40740C	journal	January 2014
Kinetic processes during sorption and diffusion of aromatic molecules on medium pore zeolites studied by time resolved IR spectroscopy Tanaka, H.; Zheng, S.; Jentys, A. Studies in Surface Science and Catalysis https://doi.org/10.1016/S0167-2991(02)80332-9	book	January 2002
On the effectiveness of tailored mesoporous MFI zeolites for biomass catalytic fast pyrolysis Gamliel, David P.; Cho, Hong Je; Fan, Wei Applied Catalysis A: General, Vol. 522 https://doi.org/10.1016/j.apcata.2016.04.026	journal	July 2016
Br⊘nsted Acid Sites in Zeolites Characterized by Multinuclear Solid-State NMR Spectroscopy Hunger, Michael Catalysis Reviews, Vol. 39, Issue 4 https://doi.org/10.1080/01614949708007100	journal	November 1997

Similar Records

H-D Exchange of Simple Aromatics as a Measure of Brønsted-Acid Site Strengths in Solids

Journal Article · Tue Sep 25 00:00:00 EDT 2018 · Catalysis Letters · OSTI ID:1469941

Wang, Cong; Li, Sha; Mao, Xinyu; +2 more

Dehydrogenation of Propane and n-Butane Catalyzed by Isolated PtZn₄ Sites Supported on Self-Pillared Zeolite Pentasil Nanosheets

Journal Article · Wed Aug 31 00:00:00 EDT 2022 · ACS Catalysis · OSTI ID:1469941

Qi, Liang; Zhang, Yanfei; Babucci, Melike; +11 more

Adsorption of furan, hexanoic acid, and alkanes in a hierarchical zeolite at reaction conditions: Insights from molecular simulations

Journal Article · Fri Nov 27 00:00:00 EST 2020 · Journal of Computational Science · OSTI ID:1469941

Josephson, Tyler R.; Dauenhauer, Paul J.; Tsapatsis, Michael; +1 more

Related Subjects

catalysis (homogeneous)
catalysis (heterogeneous)
biofuels (including algae and biomass)
bio-inspired
hydrogen and fuel cells
materials and chemistry by design
synthesis (novel materials)
synthesis (self-assembly)
synthesis (scalable processing)

Title: Simple quantification of zeolite acid site density by reactive gas chromatography

Citation Formats

References (56)

Similar Records

Related Subjects